ISSN:
1434-193X
Keywords:
Allyl alcohols
;
Organocerium reagents
;
Alkenes
;
Addition reactions
;
Cerium
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
---Alkylcerium reagents add to the multiple bonds of allyl and propargyl alcohols in good yields and under mild conditions. The double bond can be reduced with lithium aluminum hydride in the presence of cerium trichloride. The regiochemistry of the attack depends on electronic factors.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
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