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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 13 (1897), S. 16-18 
    ISSN: 0863-1778
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Kinetics experiments have determined the reaction network in the hydrodesulfurization of dibenzothiophene catalyzed by sulfided CoO-MoO3/γ-Al2O3 at 573°K and 102 atm. The predominant reaction is a direct sulfur extrusion, giving biphenyl and hydrogen sulfide; the biphenyl is subsequently hydrogenated slowly to give cyclohexylbenzene and then bicyclohexyl. Dibenzothiophene also undergoes a primary hydrogenation reaction preceding sulfur removal, but it is about one thousand times slower than the sulfur extrusion reaction.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0044-8249
    Keywords: Eisenverbindungen ; Gemischtvalente Verbindungen ; Magnetische Eigenschaften ; Mößbauer-Spektroskopie ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 645 (1961), S. 101-114 
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Das Toluolsulfonat des exo-Camphenilols wird 600mal so rasch solvolysiert wie das des endo-Camphenilols. Das Verhältnis kexo: kendo ist wesentlich kleiner als bei den Fenchol-, aber größer als bei den Norborneol-Isomeren. Das exo-Isomere paßt mit seiner Geschwindigkeit in die Reihe der trans-2-substituierten Cyclopentanole, obwohl es die Brücke cis-ständig zum Hydroxyl trägt; dies wird mit der Verzerrung des Fünfringes erklärt. Das endo-Campheniloltoluolsulfonat reagiert am langsamsten von allen bisher untersuchten Toluolsulfonaten sekundärer Alkohole. Das Isopinocampheol steht mit der Alkoholysegeschwindigkeit seines unbeständigen Toluolsulfonats zwischen exo-Camphenilol und exo-Fenchol sowie in der Nähe der cis-2-substituierten Cyclohexanole mit großem Nachbarsubstituenten. Ihm ist danach die extreme cis-Konfiguration zuzuerteilen. Die besondere hohe Solvolysegeschwindigkeit wird mit einer Deformation des Sechsrings in Zusammenhang gebracht, die als eine Folge der Wechselwirkung zwischen dem veresterten Hydroxyl und der gem. Dimethylgruppe angesehen wird.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 36 (1997), S. 152-155 
    ISSN: 0570-0833
    Keywords: iron ; magnetic properties ; mixedvalent compounds ; Mössbauer spectroscopy ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Publication Date: 2019-07-12
    Description: No abstract available
    Keywords: Earth Resources and Remote Sensing
    Type: GSFC-E-DAA-TN33613
    Format: application/pdf
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  • 8
    Publication Date: 2019-07-13
    Description: As technology has improved, operators have sought to use cubesats, as well as smallsats more generally, to perform increasingly more ambitious and sophisticated functions. Despite this, practical concerns associated with cubesat infant mortality, conjunctions, limited maneuverability, and debris generation have been relatively muted because most cubesats have been launched to lower orbits that limit both their orbital lifetime and consequences should a collision occur. NASA ARC has developed a concept for a highly-automated and distributed space traffic management (STM) architecture, drawing on similar work done to provide traffic management for small unmanned aerial systems (UAS) operating at low altitudes. The system proposes a strategy to accommodate growing space traffic volume safely, as well as pave the way for a transition of civil STM authority to a civilian governmental entity. The architecture envisions an open-access software platform architecture of data and service suppliers, consumers, and regulators, connected via a set of application programming interfaces (APIs). The platform would build on, rather than replicate existing integration and coordination efforts within the space situational awareness ecosystem, using existing standards for data message formats from organizations like the Consultative Committee for Space Data Systems and wrapping, rather than replacing existing integrations. We will present an initial STM architecture in this presentation, with a few examples showing how stakeholders can interact structurally, but flexibly, within this architecture.
    Keywords: Air Transportation and Safety
    Type: ARC-E-DAA-TN59948 , Small Satellite Conference; Aug 04, 2018 - Aug 09, 2018; Logan, UT; United States
    Format: application/pdf
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  • 9
    Publication Date: 2019-07-13
    Description: NASA is developing the Unmanned Aircraft System Traffic Management research platform to safely integrate small unmanned aircraft operations in large-scale at low-altitudes. As a part of this effort, small unmanned aircraft system off-nominal operational situations data collection process has been developed to take lessons learned and to reinforce operational compliance. In this paper, descriptions of variables used for digital data collection and an online report form for collection of observational data from the operators (contextual data) are provided. They are used to collect off-nominal data from the Unmanned Aircraft System Traffic Management National Campaign in 2017. The digital data show that 2 out of 118 campaign operations (1.7%) encountered loss of navigation. Since the campaign aircraft used Global Positioning System for navigation, it is likely that unobstructed view of the sky at the campaign locations contributed to this small number. Also, 4 out of 47 operations (8.5%) encountered loss of communications. A relatively short distance between ground control system and aircraft, ranging from 2300 feet to 4200 feet, likely contributed to this small number. There was no data to identify the loss of communications condition, aircraft received signal strength, for the remaining 71 operations suggesting that some operators may not be monitoring unmanned aircraft communications system performance or monitoring it with different parameters. For the contextual data, due to the low number of total reports during the campaign, no significant trends emerged. This is an initial attempt to collect contextual data from small unmanned aircraft operators about off-nominal situations, and changes will be made to the future data collection to improve the amount and quality of the information.
    Keywords: Air Transportation and Safety
    Type: ARC-E-DAA-TN57430 , Aviation Forum 2018; Jun 25, 2018 - Jun 29, 2018; Atlanta, GA; United States
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  • 10
    Publication Date: 2019-08-14
    Description: We confirm the applicability of using small satellite formation flight for multi-angular earth observation to retrieve global, narrow band, narrow field-of-view albedo. The value of formation flight is assessed using a coupled systems engineering and science evaluation model, driven by Model Based Systems Engineering and Observing System Simulation Experiments. Albedo errors are calculated against bi-directional reflectance data obtained from NASA airborne campaigns made by the Cloud Absorption Radiometer for the seven major surface types, binned using MODIS' land cover map - water, forest, cropland, grassland, snow, desert and cities. A full tradespace of architectures with three to eight satellites, maintainable orbits and imaging modes (collective payload pointing strategies) are assessed. For an arbitrary 4-sat formation, changing the reference, nadir-pointing satellite dynamically reduces the average albedo error to 0.003, from 0.006 found in the static reference case. Tracking pre-selected waypoints with all the satellites reduces the average error further to 0.001, allows better polar imaging and continued operations even with a broken formation. An albedo error of 0.001 translates to 1.36 W/sq m or 0.4% in Earth's outgoing radiation error. Estimation errors are found to be independent of the satellites' altitude and inclination, if the nadir-looking is changed dynamically. The formation satellites are restricted to differ in only right ascension of planes and mean anomalies within slotted bounds. Three satellites in some specific formations show average albedo errors of less than 2% with respect to airborne, ground data and seven satellites in any slotted formation outperform the monolithic error of 3.6%. In fact, the maximum possible albedo error, purely based on angular sampling, of 12% for monoliths is outperformed by a five-satellite formation in any slotted arrangement and an eight satellite formation can bring that error down four fold to 3%. More than 70% ground spot overlap between the satellites is possible with 0.5deg of pointing accuracy, 2 Km of GPS accuracy and commands uplinked once a day. The formations can be maintained at less than 1 m/s of monthly (Delta)V per satellite.
    Keywords: Earth Resources and Remote Sensing
    Type: GSFC-E-DAA-TN32486 , Acta Astronautica (ISSN 0094-5765); o 126; 77-97
    Format: text
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