Publication Date:
2019-06-27
Description:
The Raman spectra of gaseous propane-d0 and -d3 have been recorded between 50 and 3500 cm. Considerable torsional data are reported and used to characterize the torsional potential function based on a semirigid model. The average 'effective' V3 for the propanes is found to be 1139 plus or minus 10/cm. The sine-sine coupling term is similar in magnitude but opposite in sign to the cosine-cosine coupling term in propane-d0.
Keywords:
ATOMIC AND MOLECULAR PHYSICS
Type:
Journal of Chemical Physics; 66; Apr. 1
Format:
text
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