ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    facet.materialart.
    Unknown
    Unlocking P(V): Reagents for chiral phosphorothioate synthesis (2018)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2018-09-21
    Description: Phosphorothioate nucleotides have emerged as powerful pharmacological substitutes of their native phosphodiester analogs with important translational applications in antisense oligonucleotide (ASO) therapeutics and cyclic dinucleotide (CDN) synthesis. Stereocontrolled installation of this chiral motif has long been hampered by the systemic use of phosphorus(III) [P(III)]–based reagent systems as the sole practical means of oligonucleotide assembly. A fundamentally different approach is described herein: the invention of a P(V)-based reagent platform for programmable, traceless, diastereoselective phosphorus-sulfur incorporation. The power of this reagent system is demonstrated through the robust and stereocontrolled synthesis of various nucleotidic architectures, including ASOs and CDNs, via an efficient, inexpensive, and operationally simple protocol.
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
    Published by American Association for the Advancement of Science (AAAS)
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER CURRENT
  • 2
    Electronic Resource
    Electronic Resource
    Correlations between gas permeation and free-volume hole properties probed by positron annihilation spectroscopy (1995)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 2365-2371 
    Details
    ISSN: 0887-6266
    Keywords: positron annihilation ; positronium ; free volume ; hole ; gas permeation ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Free-volume hole sizes, fractions, and distributions in a series of polycarbonate-based polymers are measured by using positron annihilation lifetime (PAL) spectroscopy. Correlations between the obtained free-volume hole properties and gas diffusion coefficients are observed. © 1995 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1995.090331708
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    The effect of high pressure on the mechanical behavior of short fiber composites (1984)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 24 (1984), S. 844-850 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Three types of pressure dependent deformation processes have been observed for the short glass fiber reinforced composites of poly(vinyl chloride) (PVC). A unique deformation behavior, observed for the first time, features a sharp drop in stress followed by shear yielding in the matrix. Competitive pressure dependent failure processes in the composites are strongly affected by “debonding” at the fiber-matrix interface. A new general pressure dependent yield criterion for PVC and its composites was elucidated.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760241103
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 4
    Electronic Resource
    Electronic Resource
    Acoustic emission during irreversible deformation in short fiber reinforced poly(vinyl chloride) composites (1986)
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 7 (1986), S. 26-35 
    Details
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Acoustic emission (AE) during irreversible deformation in short glass fiber reinforced poly(vinyl chloride) (PVC) composites was studied using a piezoelectric crystal transducer. Compared to the well-coupled composites, many more AE events were observed during tensile deformation in the poorly-coupled composites, presumably due to failure at the fiber-matrix interface. No fiber fracture was detected in the tensile tests for either well-coupled or poorly-coupled composites. Irreversibility of acoustic emission was observed in repeated tensile loading experiments. Unlike PVC, the short fiber composites fractured during stress relaxation at 1 percent elongation. Studies of acoustic emission behavior during stress relaxation indicated that interfacial debonding is a time-dependent process. Relaxation fracture time was strongly increased by chemical coupling at the interface.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pc.750070107
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 5
    facet.materialart.
    Unknown
    A semiclassical study of laser-induced atomic fluorescence from Na2, K2 and NaK (1982)
    In:  Other Sources
    Details
    Publication Date: 2019-06-28
    Description: A semiclassical treatment of laser-induced atomic fluorescence for the alkali-dimer systems Na2, K2 and NaK is presented. The variation of the fluorescence intensity with the frequency of the exciting laser photon is studied and a comparison of theoretical results with a set of experimental data is presented.
    Keywords: ATOMIC AND MOLECULAR PHYSICS
    Type: AD-A127849 , AFOSR-TR-83-0358 , Molecular Physics; 47; 5, 19; 1982
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 6
    facet.materialart.
    Unknown
    A quantum-mechanical method for calculating level widths and shifts, applicable to type I unimolecular predissociation (1978)
    In:  Other Sources
    Details
    Publication Date: 2019-06-27
    Keywords: ATOMIC AND MOLECULAR PHYSICS
    Type: Molecular Physics; 36; 6, 19; 1978
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 7
    facet.materialart.
    Unknown
    Theory of molecular rate processes in the presence of intense laser radiation (1979)
    In:  Other Sources
    Details
    Publication Date: 2019-06-27
    Description: The present paper deals with the influence of intense laser radiation on gas-phase molecular rate processes. Representations of the radiation field, the particle system, and the interaction involving these two entities are discussed from a general rather than abstract point of view. The theoretical methods applied are outlined, and the formalism employed is illustrated by application to a variety of specific processes. Quantum mechanical and semiclassical treatments of representative atom-atom and atom-diatom collision processes in the presence of a field are examined, and examples of bound-continuum processes and heterogeneous catalysis are discussed within the framework of both quantum-mechanical and semiclassical theories.
    Keywords: ATOMIC AND MOLECULAR PHYSICS
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 8
    facet.materialart.
    Unknown
    Laser-enhanced dynamics in molecular rate processes (1978)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: The present discussion deals with some theoretical aspects associated with the description of molecular rate processes in the presence of intense laser radiation, where the radiation actually interacts with the molecular dynamics. Whereas for weak and even moderately intense radiation, the absorption and stimulated emission of photons by a molecular system can be described by perturbative methods, for intense radiation, perturbation theory is usually not adequate. Limiting the analysis to the gas phase, an attempt is made to describe nonperturbative approaches applicable to the description of such processes (in the presence of intense laser radiation) as electronic energy transfer in molecular (in particular atom-atom) collisions; collision-induced ionization and emission; and unimolecular dissociation.
    Keywords: ATOMIC AND MOLECULAR PHYSICS
    Type: Radiation energy conversion in space; Conference; Jan 26, 1978 - Jan 28, 1978; Moffett Field, CA
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
  • 9
    facet.materialart.
    Unknown
    Semiclassical theory of unimolecular dissociation induced by a laser field (1978)
    In:  Other Sources
    Details
    Publication Date: 2019-06-27
    Description: A semiclassical nonperturbative theory of direct photodissociation in a laser field is developed in which photon absorption and dissociation are treated in a unified fashion. This is achieved by visualizing nuclear dynamics as a representative particle moving on electronic-field surfaces. Methods are described for calculating dissociation rates and probabilities by Monte Carlo selection of initial conditions and integration of classical trajectories on these surfaces. This unified theory reduces to the golden rule expression in the weak-field and short-time limits, and predicts nonlinear behavior, i.e., breakdown of the golden rule expression in intense fields. Field strengths above which lowest-order perturbation theory fails to work have been estimated for some systems. Useful physical insights provided by the electronic-field representation have been illustrated. Intense field effects are discussed which are amenable to experimental observation. The semiclassical methods used here are also applicable to multiple-surface dynamics in fieldfree unimolecular and bimolecular reactions.
    Keywords: ATOMIC AND MOLECULAR PHYSICS
    Type: AD-A056671 , AFOSR-78-1042TR , Journal of Chemical Physics; 68; Apr. 1
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    NASA TECHNICAL REPORTS
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...