ALBERT

Description: We report results of experiments to measure the H isotope composition of organic acids and alcohols. These experiments make use of a pyroprobe interfaced with a GC and high temperature extraction furnace to make quantitative H isotope measurements. This work compliments our previous work that focused on the extraction and analysis of C isotopes from the same compounds [1]. Together with our carbon isotope analyses our experiments serve as a "proof of concept" for making C and H isotope measurements on more complex mixtures of organic compounds on mineral surfaces in abiotic hydrocarbon formation processes at elevated temperatures and pressures. Our motivation for undertaking this work stems from observations of methane detected within the Martian atmosphere [2-5], coupled with evidence showing extensive water-rock interaction during Mars history [6-8]. Methane production on Mars could be the result of synthesis by mineral surface-catalyzed reduction of CO2 and/or CO by Fischer-Tropsch Type (FTT) reactions during serpentization [9,10]. Others have conducted experimental studies to show that FTT reactions are plausible mechanisms for low-molecular weight hydrocarbon formation in hydrothermal systems at mid-ocean ridges [11-13]. Our H isotope measurements utilize an analytical technique combining Pyrolysis-Gas Chromatograph-Mass Spectrometry-High Temperature Conversion-Isotope Ratio Mass Spectrometry (Py-GC-MS-TC-IRMS). This technique is designed to carry a split of the pyrolyzed GC-separated product to a Thermo DSQII quadrupole mass spectrometer as a means of making qualitative and semi-quantitative compositional measurements of separated organic compounds, therefore both chemical and isotopic measurements can be carried out simultaneously on the same sample.

Description: The paper presents a review of the volatiles found within interplanetary dust particles. These particles have been shown to represent primitive material from early in the solar system's formation and also may contain records of stellar processes. The organogenic elements (i.e., H, C, N, O, and S) are among the most abundant elements in our solar system, and their abundances, distributions, and isotopic compositions in early solar system materials permit workers to better understand the processes operating early in the evolutionary history of solar system materials. Interplanetary dust particles have a range of elemental compositions, but generally they have been shown to be similar to carbonaceous chondrites, the solar photosphere, Comet Halley's chondritic cores, and matrix materials of chondritic chondrites. Recovery and analysis of interplanetary dust particles have opened new opportunities for analysis of primitive materials, although interplanetary dust particles represent major challenges to the analyst because of their small size.