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  • ASTROPHYSICS  (16)
  • Analytical Chemistry and Spectroscopy  (6)
  • 11
    Publication Date: 2019-07-13
    Description: Detection of the 205 micrometer fine structure line of N II in the nearby starburst galaxy M82 is reported. The intensity wihin a 54 sec Full width at Half Maximum (FWHM) beam is (7.1 +/- 1.2) x 10(exp -19) W cm(exp -2). The ratio of the intensity of the recently detected 122 micrometer line to that of the 2.5 micrometer lines is = (4.2) (sup =1.6) (sub -1.2), significantly larger than the corresponding Galactic value of 1.6 +/- 0.3, reflecting higher electron densities within the central 850 pc of M82 in comparison to the Cosmic Background Explorer (COBE) Galactic average. The 2.5 micrometer line profile is consistent with other far-infrared fine-structure line profiles observed in M82. The observations are interpreted in the context of a two-component model of the ionized medium in M82. We find that a component of density as low as approximately 50 cm(exp -3) can comprise up to 70% of the total mass of warm ionized gas within the beam. The balance of the ionized mass is comprised of a component of density approximately greater than 100 cm(exp -3). A model is explored in which the dneser ionized medium constitute the boundaries of neutral surfaces which border the expanding hot plasma from the nuclear region.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 2 - Letters (ISSN 0004-637X); 427; 1; p. L17-L20
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  • 12
    Publication Date: 2019-07-12
    Description: A high-resolution interferometric map of the CO emission on the eastern spiral arm of M83 is presented. The detected emission originates in about five unresolved components located parallel but about 300 pc downstream from the dust lane which lies along the inner edge of the spiral arm. All the CO components in the map but one are located within 130 pc of an H II region and may represent emission from locally heated gas. The lack of CO emission on the dust lane indicates that the dense molecular gas does not pile up here in M83. Remarkable differences between the molecular gas distributions in M83 and the spiral arms or M51, where CO emission peaks on the dust lane, is attributed to the difference in the strength of their density waves. The observations of M83 are consistent with the model of Elmegreen in which diffuse gas is compressed at the shock front, producing the dust lane at the inner edge of the spiral arm while dense giant molecular clouds pass through the front and form a broad distribution on the arm.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 381; 130-136
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  • 13
    Publication Date: 2019-07-12
    Description: The southwestern bar-spiral arm transition zone in M83 is been studied in CO, H-alpha, H I, red light, and the radio continuum. A massive molecular gas complex in the heart of the transition zone is composed or two principal components which have the morphology and kinematics expected from orbit crowding, where gas on highly elliptical orbits form the bar region converges with gas on more circular orbits from the spiral arm region. Three mechanisms for the origin of the orbit crowding are investigated, and it is proposed that the crowding is due primarily to density wave streaming motions caused by the bar and spiral arms. The inner CO component is partially coincident with a region of highly polarized radio continuum emission which precedes the H-alpha spiral arm by 15-25 arcsec, indicating that it lies on or just downstream from a shock front. This suggests that the bar gas approaching the transition zone is shocked and explains the ridge of dense gas seen upstream from the spiral arm.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 381; 118-129
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  • 14
    Publication Date: 2019-07-13
    Description: We have used the NRAO 12 m telescope to map the inner 10 kpc of NGC 2445, the ring galaxy in Arp 143, in CO-12(J = 1-0). Emission is peaked near the ring galaxy nucleus, but we find evidence for an additional asymmetric and extended CO component. This extended CO distribution is consistent with an approximately 8 kpc diameter crescent-shaped ring of molecular gas, similar to the one seen in H I, accounting for approximately half of the total CO flux. Assuming this distribution, we derive a total H2 mass for NGC 2445 of 0.4-2.4 x 10(exp 10) solar mass, depending on whether a Galactic or low-metallicity Large Magellanic Cloud (LMC) conversion factor is used, and an H2/H I mass ratio between 0.9 and 5. The ring is experiencing low rates of massive star formation despite very high gas column densities. We find that the gas surface density exceeds the critical threshold for star formation throughout the ring, even without a possible contribution from a significant molecular component. The absence of vigorous star formation is most simply understood in terms of its youth (approximately 30 Myr): massive stars have not had time to form in large numbers. Our results support the interpretation that NGC 2445 is a nascent ring galaxy, seen prior to its ring starburst phase.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 2 - Letters (ISSN 0004-637X); 438; 2; p. L79-L82
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  • 15
    Publication Date: 2019-07-12
    Description: The forbidden F II profiles at 18 and 26 micron from SN 1987A have been measured with a resolution of about 400 km/s. The central portion of each profile is well-fitted by a Gaussian with a FWHM of 2900 and 2500 km/s, respectively. The centroid velocity is redshifted relative to the LSR by 450 + or - 200 km/s at 18 microns and by 680 + or - 200 km/s at 26 microns. The integrated line fluxes alone imply a maximum expansion velocity of about 2000 km/s and a minimum expansion velocity much less than the maximum. A significant fraction of the iron has mixed with the overlying hydrogen regions. There is a high-velocity emission feature at about +3500 km/s relative to the main emission peak which contains about 3 percent of the total iron mass and has T about 2600 K. The measured 26 micron line flux corresponds to a total singly ionized iron mass of 0.026 solar. The line fluxes and profiles are inconsistent with a physically thin shell of gas and show that there is a wide range of expansion velocities for the iron.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 360; 257-266
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  • 16
    Publication Date: 2019-08-27
    Description: We have measured day 640-645 line and continuum spectra of (Ni II) 6.6 micrometer (Ne II) 12.8 micrometer (line emission was not detected), and (Fe II) 17.9 and 26.0 micrometer from SN 1987A. The high velocity feature at v(sub HVF) approximately 3900 km/sec found in both of our day 410 (Fe II) spectra is again detected in the day 640 (Ni II) spectrum, although the signal-to-noise of the day 640 (Fe II) spectra is insufficient to show this feature. The continuum fluxes provide clear evidence for the formation of dust between day 410 and day 640 and are best fitted by a graybody spectrum with a temperature of 342 +/- 17 K at day 640 and a surface area corresponding to a minimum dust velocity v(sub dust) = 1910 +/- 170 km/sec. Optically thin dust emissivity laws proportional to lambda(exp -1) or lambda(exp -2) are inconsistent with the data. Either the dust grains are large (radius a much greater than 4 micrometer and radiate like individual blackbodies, or else they are located in clumps optically thick in the 6-26 micrometer range. The (Ni II) 6.6 micrometer line flux yields a minimum Ni(+) mass of 5.8 +/- 1.6 x 10(exp -4) solar mass and a Ni/Fe abundance ratio of 0.06 +/- 0.02, equal to the solar value. The ratio of the two (Fe II) line profiles implies a gas temperature 2600 +/- 700 K, a drop of 1800 +/- 800 K from our day 410 measurement. The (Fe II) 26.0 micrometer line flux has decreased by a factor of 2 and the day 640 (Ni II) profile is blueshifted by -440 +/- 270 km/sec, relative to observations before day 500. We show that the decrease in the (Fe II) flux and the blueshift are not produced by a decrease in electron scattering optical depth, electron density, or temperature, but rather are probably due to obscuration by the same dust which produces the infrared continuum. This supports the interpretation that the dust spectrum is produced by optically thick clumps. We discuss possible explanations for the discrepancy between the mass of Fe(+) detected and the total iron mass required to power the light curve. The decrease in the (Fe II) fluxes relative to the decrease required to account for the blueshifts of optical lines from non-iron-group elements and the similarity between v(sub dust) and the Ni(+) expansion velocity imply a spatial association between the dust clumps and the iron-group elements. In addition, the larger blueshift observed for the near and far-infrared, heavy metal transitions relative to non-iron-group lines suggests that the iron-group elements are somewhat segregated from lighter elements such as the Mg(sup 0) and O(sup 0) responsible for shorter wavelength lines. We speculate that FeS may be an important constituent of the dust. A comparison of our line profiles with radiative transfer models shows that while power law and exponential density distributions yield reasonable fits to the data, polytrope distributions provided significantly worse agreement. The best fits require a substantial fraction of the iron to be undetectable, and are consistent with maximum expansion velocities of v(sub max) approximately 3000 km/sec.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 427; 2; p. 874-888
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  • 17
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 8 (1994), S. 544-548 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The enhanced performance of electro-osmotically driven high performance liquid chromatography (HPLC) using reversed-phase packed capillaries has been evaluated for coupling to mass spectrometers, as an alternative to both conventional pressure-driven elution, and to micellar electrokinetic capillary chromatography for the separation of neutral analytes. An off-line comparison of electro-osmotically driven versus pressure driven chromatography for the separation of an aromatic mixture shows the superiority of the method over conventional HPLC. Coupling of the technique with continuous-flow fast-atom bombardment for the analysis of a steroid mixture is described.
    Additional Material: 8 Ill.
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  • 18
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 2 (1969), S. 547-548 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Deuterium labelling has been utilised to elucidate the mechanism by which a molecule of water is eliminated from a heterocyclic nitro compound under electron-impact.
    Additional Material: 2 Tab.
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  • 19
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 9 (1980), S. 304-307 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The Raman spectra of bovine pancreatic α-chymotrypsin and trypsin were determined from 7% aqueous solutions and lyophilized solids containing residual sulfate ion. A large amount of β-pleated-sheet structure is present in both molecules, as shown by the contour of the amide III region, but trypsin contains substantially more α-helical conformation than does chymotrypsin. There is evidence of some change in structure of both molecules in solution as compared with the solids. The tyrosines are all or nearly all weakly hydrogen bonded in both enzymes, and the binding of sulfate ion is also weak in the lyophilized solids.
    Additional Material: 3 Ill.
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  • 20
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 11 (1981), S. 315-319 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Reduction of one disulfide bond in bovine pancreatic ribonuclease A, which leaves the enzyme with nearly unimpaired biological activity, makes barely perceptible changes in the aqueous Raman spectrum. Reduction of all four disulfide bonds, which inactivates the enzyme, produces serious conformational changes. The spectrum shows a substantial decrease in α-helical content and conversion of all tyrosines to a weakly hydrogen-bonded form. Cleavage of the peptide chain by cyanogen bromide at the three sites of methionine residues (13, 29-30 and 79) makes little alteration in the α-helical content but reduces the proportion of the β-pleated sheet. This structural change is attributed mainly to the chain breaking at residue 79, which occurs in the center of the β-network.
    Additional Material: 3 Ill.
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