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  • 1
    Electronic Resource
    Electronic Resource
    Clathrate and Inclusion Compounds. Part 12. Vibrational and NMR Spectroscopic Studies of Carboxylic Acid Guests in Dianin's Compound (1997)
    Springer
    Journal of inclusion phenomena and macrocyclic chemistry 27 (1997), S. 179-190 
    Details
    ISSN: 1573-1111
    Keywords: IR spectroscopy ; Raman spectroscopy ; 13C-MAS NMR spectroscopy ; Dianin's compound ; clathrates ; carboxylic acids ; alcohols
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Infrared, Raman and solid state 13C-NMR spectra have been recorded for a range of clathrates of Dianin's compound containing straight chain aliphatic carboxylic acids (formic - octanoic) as guests. The IR, Raman and NMR spectra can be satisfactorily interpreted in terms of dimer (formic and acetic) and monomer (propionic - octanoic) occupation of the cavities. The clathrates containing straight chain alcohol guests (methanol - octanol) have also been prepared to aid in the interpretation of the NMR data.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1007958323076
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  • 2
    Electronic Resource
    Electronic Resource
    Clathrate and inclusion compounds. Part 11 [1]. A pre-resonance Raman study of the β-quinol/SO2 clathrate (1991)
    Springer
    Journal of inclusion phenomena and macrocyclic chemistry 11 (1991), S. 389-396 
    Details
    ISSN: 1573-1111
    Keywords: Clathrate ; quinol/SO2 clathrate ; Raman spectroscopy ; pre-resonance Raman effect
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A pre-resonance Raman study of the yellow β-quinol/SO2 clathrate has been carried out using 609.8, 586.8, 514.5, 488.0 and 457.9 run excitation. Pre-resonance enhancement is observed for the guest vl (Al) band at 1147 cm−1 and the host band at 1257 cm−1. These observations are consistent with a charge transfer interaction arising from the LUMO of S02 (S 3pz) and the HOMO of quinol, which consists mainly of the ring π electrons.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01041416
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  • 3
    Electronic Resource
    Electronic Resource
    Clathrate and Inclusion Compounds. Part 13 [1]. Vibrational and NMR Spectroscopic Studies of Carboxylic Acid Guests in Urea (1998)
    Springer
    Journal of inclusion phenomena and macrocyclic chemistry 31 (1998), S. 99-107 
    Details
    ISSN: 1573-1111
    Keywords: IR spectroscopy ; Raman spectroscopy ; 13C MAS NMR spectroscopy ; clathrates ; inclusion compounds ; carboxylic acids ; urea ; thiourea
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Infrared, Raman and solid state13C NMR spectra have been recorded for arange of inclusion compounds of urea containingstraight chain aliphatic carboxylic acids(butyric – decanoic) as guests. Inclusioncompounds are not formed with formic, acetic andpropionic acids. Thiourea does not forminclusion compounds with any of the C1 to C10acids. The vibrational and NMR data support theconclusion that the acids are present ashydrogen bonded dimers in the channels of thehost. The alkyl chain 13C chemical shiftvalues are very different from those of acidguests in the cavities formed in Dianin'scompound. These suggest that the alkyl chainsare present in the all-trans conformation,although weak bands observed in the spectrum ofthe decanoic acid inclusion compound lend somesupport to suggestions based on MM calculationsthat other conformations might be present.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1007917532412
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  • 4
    Electronic Resource
    Electronic Resource
    Comparison of the Size Distribution of Boron Powders as Measured by Malvern Diffractometer and Coulter Counter (1988)
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 5 (1988), S. 116-121 
    Details
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Aspects of measuring the particle size distribution and median diameters of fine boron powders have been investigated. It has been demonstrated that high concentrations, typically 20 w/o, of wetting agent are necessary in a predispersion stage, especially if the material has a wide range of particle size. Measurements were made with both Coulter counting and a light scattering technique from which it has been demonstrated that for particles of median diameter in the range 10-30 μm, the latter oversizes with respect to the former by as much as 30%.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ppsc.19880050303
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  • 5
    Electronic Resource
    Electronic Resource
    Biospecific adsorption of lysozyme onto monoclonal antibody ligand immobilized on nonporous silica particles (1989)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 34 (1989), S. 467-477 
    Details
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is very important to understand the equilibrium and dynamic characteristics of biospecific adsorption (affinity chromatography) for both scientific and application purposes. Experimental equilibrium and dynamic column data are presented on the adsorption of lysozyme onto antibody immobilized on nonporous silica particles. The Langmuir model is found to represent the equilibrium experimental data satisfactorily, and the equilibrium association constants and heats of adsorption have been estimated for two systems with different ligand densities. The effects of nonspecific interactions are more pronounced in the system with low-density ligand. The dynamic interaction kinetic parameters are estimated by matching the predictions of a fixed-bed model with the experimental breakthrough curves. The agreement between theory and experiment is good for the initial phases of breakthrough, where the mechanism of biospecific adsorption is dominant. In the later phase (saturation neighborhood) of breakthrough, the effects of nonspecific interactions appear to be greater in the low-density ligand system. The kinetics of the nonspecific interactions were estimated from the data of the later phase of breakthrough and were found to be considerably slower than those attributed to biospecific adsorption.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260340406
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  • 6
    Electronic Resource
    Electronic Resource
    Turbulence phenomena at free surfaces (1972)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 169-173 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gas absorption by eddies at the free surface of a strongly turbulent liquid is interpreted quantitatively in terms of the Levich approach. The mass transfer coefficient is calculated to vary as Re to a relatively high power (1.3 to 1.5).Experiments on free turbulent jets of liquids in gas are in general accord with this theory. For turbulent films of liquids flowing over large roughness elements in “wake-interference” flow, the turbulence is anomalously efective in promoting gas absorption.Traces of surface-active agents suppress the surface renewal. This is analyzed theoretically: the results compare favorably with gas-absorption for stirred cells and flow experiments over smooth plates. For “wake-interference” flow over rough plates, the reduction in the rate of gas absorption by surface-active material is more pronounced than predicted for ordinary turbulence. But even in the presence of a surface-active agent, the roughness still gives an advantage in mass transfer rates as compared with smooth plates.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690180131
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  • 7
    Electronic Resource
    Electronic Resource
    Turbulence and surface renewal at the clean surface of a stirred vessel (1984)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 502-504 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690300327
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  • 8
    Electronic Resource
    Electronic Resource
    A new stabilizing index to correlate foam height (1975)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 599-600 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690210327
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  • 9
    Electronic Resource
    Electronic Resource
    Measurement of the surface ages of water jets (1978)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 24 (1978), S. 524-530 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental values of the surface velocities vs of water jets have been obtained by high speed flash cine photography of talc particles on the surfaces of both laminar and turbulent jets. Values of the surface ages as defined variously by Defay and Hommelen (1958), Hansen (1964), and Harper (1973) have been obtained from our data for both pure water and for dilute solutions of surface active agents.We find, by comparison with published entry length corrections for gas absorption, that x/vs gives the most reasonable age of the surface at any distance x along a jet of pure water.If a surface active agent is present in the water, the amount of adsorption of a few millimeters downstream from the nozzle is of the order ten times greater than calculated for laminar jets and five to six times greater than calculated for turbulent jets at Ren = 18 800. This we ascribe to liquid circulation in the jet adjacent to the nozzle, caused by the Marangoni surface flow, which also reduces vs significantly.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690240318
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  • 10
    Electronic Resource
    Electronic Resource
    Osteoclastic resorption of calcium phosphates is potentiated in postosteogenic culture conditions (1994)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 28 (1994), S. 105-112 
    Details
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Cell-mediated resorption of densely sintered hydroxyapatite (HA1250), tricalcium phosphate (TCP), and 600° or 900°C calcined hydroxyapatite (HA600 and HA900, respectively), was investigated by using two culture systems. The first was an osteoclastic cell culture, and the second was a two-stage culture that was composed of a bonelike tissue formation on the substrata in the first stage and its subsequent resorption by osteoclasts in the second stage. Neither of the materials showed resorption or surface alterations in the osteoclastic cell culture, except for some limited phagocytotic activity on HA600 and HA900. In the two-stage culture, production of mineralized extracellular matrix was only observed on HA1250 and TCP, and its subsequent resorption by osteoclastlike cells was evident. Small and occasionally larger tartrate-resistant acid phosphatase positive cells produced 20-150 μm diameter resorption pits in both the mineralized extracellular matrix on HA1250 and TCP and TCP and the surfaces of HA600 and HA900. Resorption of the mineralized extracellular matrix on TCP also resulted in degradation of the underlying ceramic surface, mainly initiating from intergrain boundaries, whereas the surface of HA1250 remained unaltered. The results of this study clearly demonstrate that osteoclastic resorption of calcium phosphates is potentiated in postosteogenic culture conditions. A possible role for bone matrix constituents in cell-mediated resorption is hypothesized, whereas the occurrence of resorption seems to be mainly governed by the combined effects of material characteristics such as grain size and crystal structure. © 1994 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jbm.820280114
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