ISSN:
1573-0662
Keywords:
Bromo-fluoro-methanes
;
UV absorption cross-sections
;
photodissociation coefficients
;
temperature dependence
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Geosciences
Notes:
Abstract Ultraviolet absorption cross-sections of trifluoro-bromo-methane (CF3Br-Halon 1301), difluoro-dibromo-methane (CF2Br2-Halon 1202) and of difluoro-bromo-chloro-methane (CF2BrCl-Halon 1211) are measured in the wavelength interval 172–304 nm for temperatures ranging from 210 to 295 K with uncertainties of between 2 and 4%. They are compared with previous measurements available at room temperature. Temperature effects are discussed and parametrical formulae are proposed to compute the absorption cross-sections for wavelengths and temperatures useful in atmospheric modelling calculations. Photodissociation coefficients are presented and their temperature dependence is discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00053815
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