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  • Articles  (8)
  • General Chemistry  (4)
  • time-resolved spectroscopy  (2)
  • AC- and DC-susceptibility
  • CHEMISTRY
  • GEOPHYSICS
  • NUCLEAR ENGINEERING
  • Physics
  • 1
    Electronic Resource
    Electronic Resource
    New fluorescent labels for time-resolved detection of biomolecules (1993)
    Springer
    Journal of fluorescence 3 (1993), S. 131-139 
    Details
    ISSN: 1573-4994
    Keywords: Fluorescence ; multiplex dyes ; photochemistry ; time-resolved spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract New dyes with characteristic fluorescence lifetimes have been developed for bioanalytical applications. Based upon the concept of “multiplex dyes,” we have designed rhodamine dyes with nearly identical absorption and emission spectral characteristics but different fluorescence lifetimes. Extending this principle to applications with laser diodes, new rhodamines with functional groups for covalent coupling of analytes have been developed. The new labels exhibit absortion and fluorescence beyond 600 nm and have a high quantum efficiency, even in aqueous buffer systems.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00862730
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  • 2
    Electronic Resource
    Electronic Resource
    New fluorescent dyes in the red region for biodiagnostics (1995)
    Springer
    Journal of fluorescence 5 (1995), S. 247-261 
    Details
    ISSN: 1573-4994
    Keywords: Fluorescence ; photochemistry ; rhodamine dyes ; time-resolved spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The increased sensitivity together with the advent of low-cost optical sources and detectors in the visible-near IR region has led us to current efforts to develop new efficient fluorescent labels for biodiagnostics with absorption and emission beyond 600 nm. In view of the general fluorescence decrease with increasing emission wavelength, we investigated the possibility to shift the absorption of rhodamine dyes toward the region 620–670 nm. The hydrophobic nature of all known long-wavelength dyes results in the tendency to form intra- and intermolecular aggregates in hydrophilic solvents, especially in aqueous environment. Due to the aggregation with biological materials, fluorescence quenching of the dyes is often observed. New strategies for prevention of these processes are considered.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00723896
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  • 3
    Electronic Resource
    Electronic Resource
    Grazer Hochschulen. Chemisches Colloquium am 22. Mai 1944 (1944)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 57 (1944), S. 126-126 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19440571706
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  • 4
    Electronic Resource
    Electronic Resource
    Über die Methylalkoholvergiftung (1910)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 23 (1910), S. 351-355 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19100230805
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  • 5
    Electronic Resource
    Electronic Resource
    Spherulite boundary strengthening concept for toughening polypropylene (1998)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 2047-2056 
    Details
    ISSN: 0887-6266
    Keywords: polypropylene ; spherulite ; cocrystallization ; lamellae ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: During spherulitic crystallization of polymers, there is a tendency for low molecular weight and other less crystallizable entities to be rejected from the body of the spherulites. This rejection process causes a segregation of these species to those areas where spherulites impinge. As a result of this segregation, lamellar and spherulite boundaries have a tendency to become weak, often resulting in premature mechanical failure. The objective of this work, anthropomorphically speaking, is to develop a melt miscible blend system in which a propylene copolymer “fools” a polypropylene homopolymer into rejecting the copolymer to the spherulite boundaries as an impurity. However, once the copolymer arrives at these boundaries, the copolymer subsequently connects adjacent spherulites through cocrystallization of the propylene copolymer segments. It was found that addition of either a random ethylene-propylene copolymer or an isotactic-atactic block copolymer was able to yield the desired effect. Cocrystallization was confirmed by calorimetry, and segregation of copolymer and subsequent reinforcement at the spherulite boundaries was directly observed microscopically. Using this approach, toughness was increased with little loss in stiffness. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 2047-2056, 1998
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Ein alternativer Weg zur Darstellung von Bi2Sr2CaCu2Ox, YBa2Cu3O7-δ, und YBa2Cu3-xMxO7-δ (M = Ni, Ag und x ≤ 33 Mol%)Professor Rudolf Hoppe zum 70. Geburtstage gewidmet (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 616 (1992), S. 186-190 
    Details
    ISSN: 0044-2313
    Keywords: Preparation of quaternary copper oxides ; high Tc superconductors ; characterization by X-ray powder methods ; AC- and DC-susceptibility ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: An Alternative Method for Preparation of Bi2Sr2CaCu3Ox, YBa2Cu3O7-δ, and YBa2Cu3-xMxO7-δ (M = Ni, Ag and x ≤ 33 Mol%)Oxidation of quenched melts of metals in a well defined argon/oxygen atmosphere has been found as an alternative method to prepare hight purity samples of Bi2Sr2CaCu2Ox without Pb-stabilization. A special equipment for the oxidation of powder samples will be described. By our new method it is also possible to prepare YBa2Cu3O7-δ and derivatives of this compound, where Cu is substituted by high amounts of Ni or Ag.
    Notes: Es wird eine alternative Präparationsmethode beschrieben, die es ermöglicht, durch Oxidation abgeschreckter Metallschmelzen in einer Sauerstoff-Argon-Strömungsapparatur sehr saubere, nicht Pb-stabilisierte Bi2Sr2CaCu2Ox-Präparate herzustellen. Dieser Weg ist auch für die Darstellung von YBa2Cu3O7-δ und Substitutionsderivaten dieser Verbindung mit hohen Konzentrationen an Ni oder Ag geeignet.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926161030
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  • 7
    Electronic Resource
    Electronic Resource
    IV. Bericht über die Ausstellung in der Technischen Hochschule (1900)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 13 (1900), S. 1103-1108 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19000134404
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  • 8
    Electronic Resource
    Electronic Resource
    Technology of the Microbiological Preparation of Organic Substances (1966)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 5 (1966), S. 653-662 
    Details
    ISSN: 0570-0833
    Keywords: Biotechnology ; Fermentation ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The preparation of organic substances with the aid of the enzyme systems of micoorganisms has become competitive as a result of recent progress in the technology of fermentation. The relatively high cost of apparatus and the lower production capacity of microbiological plants in relation to the plants used in purely chemical processes are offset in many cases by the advantages of biological methods (reactions at conventionally inactive positions in the molecule, stereospecific substitutions, coupling of several reactions, mild reaction conditions, possible use of waste products).
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196606531
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