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  • Dissolved inorganic carbon  (2)
  • 83-504B; AA; Alkalinity, total; Ammonia; Autoanalyzer; Barium; Boron; Caesium; Calcium; Calculated, see reference(s); Chlorinity; Chromatographic; Colorimetry; Comment; Deep Sea Drilling Project; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP; Flame atomic absorption spectrometry (FAAS); Glomar Challenger; Hydrogen sulfide; ICP-OES, Inductively coupled plasma - optical emission spectrometry; Identification; Leg83; Magnesium; Mass spectrometry; Nitrate and Nitrite; Nitrite; Oxygen; pH; Potassium; Rubidium; Salinity; see reference(s); Silicon; Sodium; Strontium; Strontium-87/Strontium-86 ratio; Strontium-87/Strontium-86 ratio, error; Sulfate; Titration; Titration, Winkler; Δ14C; Δ14C, standard deviation; δ18O; δ34S  (1)
  • Deep Sea Drilling Project; DSDP  (1)
  • Kinetics  (1)
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  • 1
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    PANGAEA
    In:  Supplement to: Mottl, Michael J; Druffel, Ellen R M; Hart, Stanley R; Lawrence, James R; Saltzman, Eric S (1985): Chemistry of hot waters sampled from basaltic basement in Hole 504B, Deep Sea Drilling Project Leg 83, Costa Rica Rift. In: Anderson, RN; Honnorez, J; Becker, K; et al. (eds.), Initial Reports of the Deep Sea Drilling Project, Washington (U.S. Govt. Printing Office), 83, 315-328, https://doi.org/10.2973/dsdp.proc.83.115.1985
    Publikationsdatum: 2023-12-11
    Beschreibung: Seawater that has been altered by reaction with basaltic basement has been sampled from Deep Sea Drilling Project Hole 504B, located on 5.9-m.y.-old crust on the southern flank of the Costa Rica Rift. Fourteen water samples have been collected on Legs 69, 70, and 83, both before and after renewed drilling on the latter two legs, at temperatures from 69 to 133°C and pressures from 390 to 425 bars. The water sampled prior to renewed drilling on Leg 83 had occupied the hole for nearly 2 yr. since it was last flushed with surface seawater at the end of Leg 70. Despite some contamination by seawater during sampling, the composition of two of these waters has been determined by using nitrate as a tag for the contaminant. Both the 80 and 115°C waters have seawater chlorinity, but have lost considerable Mg, Na, K, sulfate, and 02, and have gained Ca, alkalinity, Si, NH3 and H2S. The loss of sulfate is due to anhydrite precipitation, as indicated by the d34S value of the remaining dissolved sulfate. The 87Sr/86Sr ratio has been lowered to 0.7086 for the 80°C water and 0.7078 for the 115°C water, whereas the Sr concentration is nearly unchanged. The changes in major element composition relative to seawater are also larger for the 115°C water, indicating that the basement formation water at this site probably varies in composition with depth. Based on their direction relative to seawater, the compositional changes for the 80 and 115°C waters do not complement the changes inferred for the altered rocks from Hole 504B, suggesting that the bulk composition of the altered rocks, like their mineralogy, is largely unrelated to the present thermal and alteration regime in the hole. The exact nature of the reacted seawaters cannot be determined yet, however. During its 2 yr. residence in the hole, the surface seawater remaining at the end of Leg 70 would have reacted with the wall rocks and exchanged with their interstitial formation waters by diffusion and possibly convection. How far these processes have proceeded is not yet certain, although calculations suggest that diffusion alone could have largely exchanged the surface seawater for interstitial water. The d18O of the samples is indistinguishable from seawater, however, and the d14C of the 80°C sample is similar to that of ocean bottom water. Although the interpretation of these species is ambiguous, that of tritium should not be. Tritium analyses, which are in progress, should clarify the nature of the reacted seawaters obtained from the hole.
    Schlagwort(e): Deep Sea Drilling Project; DSDP
    Materialart: Dataset
    Format: application/zip, 2 datasets
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2024-05-22
    Schlagwort(e): 83-504B; AA; Alkalinity, total; Ammonia; Autoanalyzer; Barium; Boron; Caesium; Calcium; Calculated, see reference(s); Chlorinity; Chromatographic; Colorimetry; Comment; Deep Sea Drilling Project; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP; Flame atomic absorption spectrometry (FAAS); Glomar Challenger; Hydrogen sulfide; ICP-OES, Inductively coupled plasma - optical emission spectrometry; Identification; Leg83; Magnesium; Mass spectrometry; Nitrate and Nitrite; Nitrite; Oxygen; pH; Potassium; Rubidium; Salinity; see reference(s); Silicon; Sodium; Strontium; Strontium-87/Strontium-86 ratio; Strontium-87/Strontium-86 ratio, error; Sulfate; Titration; Titration, Winkler; Δ14C; Δ14C, standard deviation; δ18O; δ34S
    Materialart: Dataset
    Format: text/tab-separated-values, 458 data points
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2022-10-26
    Beschreibung: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Druffel, E. R. M., Griffin, S., Wang, N., Garcia, N. G., McNichol, A. P., Key, R. M., & Walker, B. D. Dissolved organic radiocarbon in the central Pacific Ocean. Geophysical Research Letters, 46(10), (2019):5396-5403, doi:10.1029/2019GL083149.
    Beschreibung: We report marine dissolved organic carbon (DOC) concentrations, and DOC ∆14C and δ13C values in seawater collected from the central Pacific. Surface ∆14C values are low in equatorial and polar regions where upwelling occurs and high in subtropical regions dominated by downwelling. A core feature of these data is that 14C aging of DOC (682 ± 86 14C years) and dissolved inorganic carbon (643 ± 40 14C years) in Antarctic Bottom Water between 54.0°S and 53.5°N are similar. These estimates of aging are minimum values due to mixing with deep waters. We also observe minimum ∆14C values (−550‰ to −570‰) between the depths of 2,000 and 3,500 m in the North Pacific, though the source of the low values cannot be determined at this time.
    Beschreibung: We thank Jennifer Walker, Xiaomei Xu, and Dachun Zhang for their help with the stable carbon isotope measurements; John Southon and staff of the Keck Carbon Cycle AMS Laboratory for their assistance and advice; the support of chief scientists Samantha Siedlecki, Molly Baringer, Alison Macdonald, and Sabine Mecking; the guidance of Jim Swift and Dennis Hansell for shared ship time; and Sarah Bercovici for collecting water on the GoA cruise. We appreciate the comments of Christian Lewis and Niels Hauksson on this manuscript. This work was supported by NSF (OCE‐141458941 to E. R. M. D. and OCE‐0824864, OCE‐1558654, and Cooperative Agreement OCE1239667 to R. M. K. and A. P. M.), the Fred Kavli Foundation, the Keck Carbon Cycle AMS Laboratory, and the NSF/NOAA‐funded GO‐SHIP Program. This research was undertaken, in part, thanks to funding from the Canada Research Chairs program (to B. D. W.) and an American Chemical Society Petroleum Research Fund New Directions grant (55430‐ND2 to E. R. M. D. and B. D. W.). Data from the P16N cruises are available in Table S2 in the Supporting Information and at the Repeat Hydrography Data Center at the CCHDO website (http://cdiac.esd.ornl.gov/oceans/index.html) using the expo codes 3RO20150329, 3RO20150410, and 3RO20150525. There are no real or perceived financial conflicts of interests for any author.
    Beschreibung: 2019-11-02
    Schlagwort(e): Dissolved organic carbon ; Radiocarbon ; Pacific Ocean ; Dissolved inorganic carbon ; Deep ocean circulation ; AABW
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2022-10-26
    Beschreibung: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 48(10), (2021): e2021GL092904, https://doi.org/10.1029/2021GL092904.
    Beschreibung: We report marine dissolved organic carbon (DOC) concentrations, and DOC Δ14C and δ13C values in seawater collected from the Southern Ocean and eastern Pacific GOSHIP cruise P18 in 2016/2017. The aging of 14C in DOC in circumpolar deep water northward from 69°S to 20°N was similar to that measured in dissolved inorganic carbon in the same samples, indicating that the transport of deep waters northward is the primary control of 14C in DIC and DOC. Low DOC ∆14C and δ13C measurements between 1,200 and 3,400 m depth may be evidence of a source of DOC produced in nearby hydrothermal ridge systems (East Pacific Rise).
    Beschreibung: This work was supported by NSF (OCE-1458941 and OCE-1951073 to Ellen R. M. Druffel), Fred Kavli Foundation, Keck Carbon Cycle AMS Laboratory, NSF/NOAA funded GO-SHIP Program, Canada Research Chairs program (to Brett D. Walker) and American Chemical Society Petroleum Research Fund New Directions (55,430-ND2 to Ellen R. M. Druffel and Brett D. Walker).
    Beschreibung: 2021-11-24
    Schlagwort(e): 13C ; Carbon cycle ; Circumpolar deep water ; Dissolved inorganic carbon ; Dissolved organic carbon ; Radiocarbon
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
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    American Geophysical Union
    Publikationsdatum: 2022-05-26
    Beschreibung: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 39 (2012): L18602, doi:10.1029/2012GL052974.
    Beschreibung: Marine dissolved organic carbon (DOC) is the largest reservoir of reduced carbon in seawater and persists up to 4,000–6,000 conventional radiocarbon (14C) years on average. Photochemical degradation has been suggested as a geochemical sink for these long-lived molecules, yet there have been no studies relating photochemical lability to the 14C-ages of surface DOC. We observed apparent second order (2°) kinetics with respect to DOC and a strong trend from Δ14C-enriched to depleted values during exhaustive photomineralization of surface marine DOC with high energy UV light. Geochemically, these results suggest that surface DOC is an isotopically-heterogeneous mixture of molecules for which photochemical lability and 14C ages are correlated. Photochemical mineralization may therefore be an important control on the persistence of 14C-depleted DOC in the ocean.
    Beschreibung: This study was supported under NSF grant OCE-0961980 to E. R. M. Druffel.
    Beschreibung: 2013-03-20
    Schlagwort(e): DOC ; Kinetics ; Photochemistry ; Radiocarbon
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Format: application/msword
    Format: text/plain
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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