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  • Surface physics, nanoscale physics, low-dimensional systems  (3)
  • Physics  (2)
  • 79.20.Fv  (1)
  • 1
    ISSN: 1434-6036
    Schlagwort(e): 71.10.+x ; 71.28.+d ; 79.20.Fv
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Due to their sensitivity to electron-correlation effects,CVV Auger-electron (AES) and appearance-potential spectroscopy (APS) can provide useful information on the electronic structure of solids. Correlations among the valence-band electrons (VV correlations) as well as correlations between the valence-band and the core electrons (CV correlations) are responsible for a variety of effects. StrongVV correlations are well known to give rise to sharp satellites in the spectra, which are related to localized two-hole (electron) final states. On the other hand, the screening of the core-hole potential in the initial state for AES, the sudden response of the valence-band electrons after the destruction of the core hole, and, for APS, the scattering of the valence-band electrons at the core hole are all consequences ofCV correlations. Up to now, however, little is known about the combined influence of both types of correlations on the spectra. We present a new theoretical approach that refers to the general case of a model system with arbitrary band-filling and arbitrary strengths ofVV as well asCV correlations. Remaining restrictions and simplifications concerning the degeneracy of the valence band, the transition matrix elements, etc. can be improved systematically. Of course, this generality can only be achieved at the expense of inevitable approximations in the theoretical formulation. The AES and APS intensities are given by properly defined three-particle Green functions, which are determined by use of a diagrammatic vertex-correction method that is based on the three-particle ladder approximation, which is the main idea of our approach. It is a direct generalization of the two-particle ladder approximation, which in the past has been applied for the calculation of two-particle Green functions that are related to the AES and APS intensities, ifCV correlations can be neglected.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 13 (1975), S. 1119-1131 
    ISSN: 0360-6376
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Studies of olefin copolymers by inverse gas chromatography show that the method is suitable for determining the crystallinity of compositions where a linear extrapolation of density determinations is not applicable. Satisfactory estimates of crystallinity were obtained on ethylene copolymers with carbon monoxide and vinyl acetate and on an emulsifiable polyethylene wax. Studies were also made in which the columns were packed with physical mixtures of GC support and polyolefin powders, either obtained direct or ground from film samples. It was shown that good estimates of crystallinity could be obtained if suitable allowance is made for variance in peak retention time with flow rate, due to the relatively slow rate of diffusion of the probe molecule in polymer particles of large diameter (〉100 μm). If smaller particles are used it is usually unnecessary to correct for flow rate effects. This extends the usefulness of the “molecular probe” technique to any polyolefin sample which can be ground to a fine particle size and eliminates the need for solution coating of the column packing.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 14 (1976), S. 1073-1081 
    ISSN: 0360-6376
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The glass transition temperatures of polypropylene, poly-1-butene, polyisobutylene, and an ethylene-propylene (EP) copolymer have been determined by inverse gas chromatography. The results are consistent with those determined by other procedures. When applied to low-, medium- and high-density polyethylene, values of -35, -25, and -18°C, respectively, were obtained. Because of the fact that the chromatographic technique involves essentially a sensitive detection of free volume in a polymer, it is suggested that these values represent Tg if it is defined as an iso-free volume state of the amorphous phase of the polyethylene.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2011-12-15
    Beschreibung: Author(s): T. Allmers, M. Donath, J. Braun, J. Minár, and H. Ebert [Phys. Rev. B 84, 245426] Published Wed Dec 14, 2011
    Schlagwort(e): Surface physics, nanoscale physics, low-dimensional systems
    Print ISSN: 1098-0121
    Digitale ISSN: 1095-3795
    Thema: Physik
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Publikationsdatum: 2013-11-08
    Beschreibung: Author(s): J. Braun, J. Minár, S. Mankovsky, V. N. Strocov, N. B. Brookes, L. Plucinski, C. M. Schneider, C. S. Fadley, and H. Ebert We present a theory of temperature-dependent photoemission which accurately describes phonon effects in soft and hard x-ray angle-resolved photoemission. Our approach is based on a fully relativistic one-step theory of photoemission that quantitatively reproduces the effects of phonon-assisted trans... [Phys. Rev. B 88, 205409] Published Thu Nov 07, 2013
    Schlagwort(e): Surface physics, nanoscale physics, low-dimensional systems
    Print ISSN: 1098-0121
    Digitale ISSN: 1095-3795
    Thema: Physik
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Publikationsdatum: 2016-11-10
    Beschreibung: Author(s): H. J. Elmers, R. Wallauer, M. Liebmann, J. Kellner, M. Morgenstern, R. N. Wang, J. E. Boschker, R. Calarco, J. Sánchez-Barriga, O. Rader, D. Kutnyakhov, S. V. Chernov, K. Medjanik, C. Tusche, M. Ellguth, H. Volfova, St. Borek, J. Braun, J. Minár, H. Ebert, and G. Schönhense In regular semiconductors each electronic state is occupied by spin-up and spin-down electrons. It is well known that inversion symmetry breaking at a surface may lift this degeneracy by spin-orbit coupling (the Rashba effect). As already proposed by Rashba, bulk inversion symmetry breaking may cause a similar degeneracy lifting of bulk states. Ferroelectric materials provide such an inversion symmetry breaking. Thin ferroelectric α -GeTe(111) films grown on Si(111) show a stable ferroelectric polarization with a polarization vector perpendicular to the surface that can be switched by an electric field into a metastable state with opposite polarization. Spin-resolved time-of-flight momentum microscopy reveals a Rashba-type spin splitting of the valence band caused by the inner electric field. Due to orbital polarization, the outer Rashba branch has a larger polarization than the inner branch. The corresponding net spin polarization provides new functionalities in spintronic devices, e.g. it may strongly affect the conversion process of spin into current via the spin-galvanic effect. [Phys. Rev. B 94, 201403(R)] Published Wed Nov 09, 2016
    Schlagwort(e): Surface physics, nanoscale physics, low-dimensional systems
    Print ISSN: 1098-0121
    Digitale ISSN: 1095-3795
    Thema: Physik
    Standort Signatur Erwartet Verfügbarkeit
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