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  • 1
    ISSN: 1434-6079
    Keywords: 36.40. + d ; 35.20. Wg ; 79.20.Ds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We have investigated the structures and properties of alkali halide cluster ions produced by laser vaporization of solid samples. In many alkali halide cluster ions, we observe the appearances of bulk-like characteristics even at sub-nanometer sizes:fcc crystalline structures (including surface terraces), ionic binding, and a susceptibility to common bulk defects such as F and H color-centers. To understand the origins of cluster structures, we have made calculations of ground state energetics, high-temperature molecular dynamics, and the electronic structure of clusters having excess electrons.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 20 (1991), S. 461-463 
    ISSN: 1434-6079
    Keywords: 36.40. + d ; 35.20.Wg ; 79.20.Ds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We have studied the formation of clusters of alkali halides during laser vaporization. Measurements of the abundances of cluster ions produced by several different source configurations indicate that clusters are ejected directly from the source sample and do not necessarily grow from an atomic or molecular vapor. Using samples consisting of mixed alkali halide powders, we have found that unalloyed clusters are easily produced in a source that prevents growth from occurring after the clusters leave the sample surface. Melting the sample or encouraging growth after vaporization lead to the production of alloyed cluster species. We also obtain information about the relative binding energies for substituted halogen ions bound to alkali halide clusters.
    Type of Medium: Electronic Resource
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