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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 59 (1994), S. 463-467 
    ISSN: 1432-0630
    Keywords: 79.60.Bm ; 61.16.Ch ; 61.46.+w ; 73.20.Hb
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The fascination of research with nanometersized objects in contact with a macroscopic surface will be illustrated by two examples: mass-selected supported transition-metal clusters and C60 molecules on metallic single-crystal substrates. The preparation, mass-selection and deposition of the small particles will be described in some detail. The main experimental techniques involved in the characterization of their electronic and structural properties are photoelectron spectroscopy and scanning tunneling methods. For the transition-metal clusters the evolution of the valence band with cluster size reveals a trend to metal formation. When the tip of a Scanning Tunneling Microscope (STM) is placed above individual C60 molecules intense light emission is observed. The diameter of this emission spot is approximately 4 Å. This observation indicates the possibility of an optical spectroscopic analysis on the scale of individual molecules.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1434-6079
    Keywords: 79.60.Cn ; 73.20.Hb ; 79.20.Rf
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We report on a photoemission study (XPS, UPS) of the evolution of the electronic structure with cluster size of Nin, Pdn, Ptn(n=1–15) mass-selected clusters deposited in submonolayer quantities on a Ag(110) single crystal surface. The monodispersed clusters display individual discrete electronic structure features of the Ni3d, Pd4d and Pt5d emission. With increasing cluster size the increasing splitting between the bonding-like and antibonding-like d-states reflects the molecular interaction. The shift of the center of gravity of the d-state spectrum towards the Fermi energy and its concomittant broadening indicate the trend to transition-metal formation.
    Type of Medium: Electronic Resource
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