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  • 1
    ISSN: 1432-0630
    Keywords: 68.22 ; 78.47 ; 78.70
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Thin films consisting of 3 or 4 Sb and Ge alternating layers are irradiated with single nanosecond laser pulses (12 ns, 193 nm). Real time reflectivity (RTR) measurements are performed during irradiation, and Rutherford backscattering spectrometry (RBS) is used to obtain the concentration depth profiles before and after irradiation. Interdiffusion of the elements takes place at the layer interfaces within the liquid phase. The reflectivity transients allow to determine the laser energy thresholds both to induce and to saturate the process being both thresholds dependent on the multilayer configuration. It is found that the energy threshold to initiate the process is lower when Sb is at the surface while the saturation is reached at lower energy densities in those configurations with thinner layers.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 8 (1997), S. 235-241 
    ISSN: 1573-4846
    Keywords: polymer ; spectroscopy ; modifying agent
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Two chemical routes were employed to prepare Si-Ti polymers, using acetylacetone (acacH) and acetic acid (HOAc) as modifying agents. The homogeneous and transparent sols were studied at different aging times. The characterization techniques were 29Si NMR, FTIR, UV-Vis and TGA. When HOAc was used, the oligomeric species in the first stages of polymerization were assigned by 29Si NMR. The Ti–O–Si bond vibration was detected by FTIR in the 950–960 cm–1 region. UV-Vis spectroscopy showed bands of acac bonded to Ti at 300 nm and 365 nm, and OAc– bonded to Ti was found at 320 nm. The TGA study allowed the establishment of the xerogel formulas.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 8 (1997), S. 235-241 
    ISSN: 1573-4846
    Keywords: polymer ; spectroscopy ; modifying agent
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Two chemical routes were employed to prepare Si−Ti polymers, using acetylacetone (acacH) and acetic acid (HOAc) as modifying agents. The homogeneous and transparent sols were studied at different aging times. The characterization techniques were29Si NMR, FTIR, UV-Vis and TGA. When HOAc was used, the oligomeric species in the first stages of polymerization were assigned by29 Si NMR. The Ti−O−Si bond vibration was detected by FTIR in the 950–960 cm−1 region. UV-Vis spectroscopy showed bands of acac bonded to Ti at 300 nm and 365 nm, and OAc− bonded to Ti was found at 320 nm. The TGA study allowed the establishment of the xerogel formulas.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
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