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  • 1
    ISSN: 1432-0630
    Keywords: 66.30 ; 68.20
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The kinetics of shaping of periodic surface profiles under the action of surface selfdiffusion were calculated for the special case of anisotropic surface energy. The orientation-dependent surface energy was allowed to contain a local minimum of very high curvature (cusp). The orientation of this cusp was equal to the macroscopic orientation of the crystal surface. The periodic surface profiles exhibited in all cases extended, nearly flat regions centered at the cusp orientation. This type of faceting which causes the profile to be trapezoidal in shape agrees well with experimentally observed profiles on (111) and (100) Ni single crystal surfaces. A procedure is outlined by which the orientation-dependent surface energy along a certain azimuth and the surface self-diffusion coefficient can be extracted from the decay kinetics of faceted periodic surface profiles. This procedure demands the accurate experimental assessment of profile shapes and amplitudes.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 41 (1986), S. 137-143 
    ISSN: 1432-0630
    Keywords: 68.20 ; 66.30
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The decay of periodic surface profiles by surface self-diffusion is simulated by numerically solving the phenomenological equations for this process. The crystalline nature of the surface is taken into account by introducing an anisotropic surface free energy,γ(θ). Depending on the degree of anisotropy ofγ(θ), the decay kinetics and the shapes of the profiles are largely different. A comparison with measurements of profile decay on Pt(l10) single crystal surfaces shows that the anisotropy inγ(θ) along the [1¯10] azimuth should be about 2–3%, while that along the [001] azimuth is expected near 8%. In the latter case large amplitude profiles exhibit (111) faceting and slow decay kinetics which are non-exponential. The rate of surface self-diffusion on Pt(110) is anisotropic with the [1¯10] direction being faster than the [001] direction.
    Type of Medium: Electronic Resource
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