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  • 68,35.Fx  (1)
  • 82.65.Jv  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 53 (1991), S. 369-376 
    ISSN: 1432-0630
    Keywords: 68.55.−a ; 68,35.Fx ; 61.16.Fk
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The growth of Pt(111) by Pt vapour deposition is studied by He diffraction as a function of substrate temperature and deposition rate. At a deposition rate of about 2.5×10−2 monolayers/second several growth modes are observed: layer-by-layer (2D-) growth at 450 K≲T s≲800 K, multilayer (3D-) growth at 340 K≲T s≲450 K and reentrant layer-by-layer (2D-) growth at T s≲340 K. The observed growth modes and in particular the reentrant 2D-growth are shown to be characteristic of growing Pt(111) under clean conditions, i.e. not influenced by contaminants. The influence of the intra- and interlayer mass transport on the growth mode is discussed in the light of experimental and simulation results. The 3D-growth mode is attributed to the existence of an activation barrier which suppresses the descent of adatoms from the top of the growing adatom islands onto the lower terraces. The barrier can be overcome by thermal adatoms at T s≳450 K enabling interlayer mass transport which leads to 2D-growth. The reentrant 2D-growth occurs due to a break down of this barrier for small, irregularly shaped islands.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0630
    Keywords: 82.65.Jv ; 61.16Di
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The adsorption and reactions of ethylene adsorbed in UHV on Pt(111) have been studied as a function of temperature by STM. The STM images taken at 160K show an ordered structure of adsorbed ethylene. Annealing to 300 K produces ethylidyne (C-CH3) irreversibly, as has been demonstrated by a wide variety of surface science techniques. The ethylidyne on Pt(111) is not visible to the STM at room temperature. Cooling the sample allows direct observation of the ethylidyne ordered structure by STM. Annealing above 430 K results in further dehydrogenation, eventually leaving only carbon on the surface. The decomposition products appear as small clusters which are localized and uniformly distributed over the surface. Further annealing to temperatures 〉800 K results in the growth of graphite islands on the Pt(111) surface. The annealed graphite islands exhibit several supersturctures with lattice parameters of up to 22 Å, which are thought to result from the higher order commensurability with the Pt(111) substrate at different relative rotations.
    Type of Medium: Electronic Resource
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