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  • TEM  (2)
  • modelling  (2)
  • 65F25  (1)
  • 65G05  (1)
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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    BIT 34 (1994), S. 1-24 
    ISSN: 1572-9125
    Schlagwort(e): 65F25 ; 65G05 ; 65F05 ; 65F20 ; augmented systems ; QR factorization ; least squares ; minimum norm solution ; seminormal equations ; numerical stability ; Gram-Schmidt
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Mathematik
    Notizen: Abstract We consider solvingx+Ay=b andA T x=c for givenb, c andm ×n A of rankn. This is called the augmented system formulation (ASF) of two standard optimization problems, which include as special cases the minimum 2-norm of a linear underdetermined system (b=0) and the linear least squares problem (c=0), as well as more general problems. We examine the numerical stability of methods (for the ASF) based on the QR factorization ofA, whether by Householder transformations, Givens rotations, or the modified Gram-Schmidt (MGS) algorithm, and consider methods which useQ andR, or onlyR. We discuss the meaning of stability of algorithms for the ASF in terms of stability of algorithms for the underlying optimization problems. We prove the backward stability of several methods for the ASF which useQ andR, inclusing a new one based on MGS, and also show under what circumstances they may be regarded as strongly stable. We show why previous methods usingQ from MGS were not backward stable, but illustrate that some of these methods may be “acceptable-error stable”. We point out that the numerical accuracy of methods that do not useQ does not depend to any significant extent on which of of the above three QR factorizations is used. We then show that the standard methods which do not useQ are not backward stable or even acceptable-error stable for the general ASF problem, and discuss how iterative refinement can be used to counteract these deficiencies.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    ISSN: 1573-2932
    Schlagwort(e): desorption ; ferrihydrite ; modelling ; phosphate ; TEM ; transformation ; wastewater
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The presence of phosphate retards the transformation of ferrihydrite into crystalline products. Increasing phosphate from 0 to 1 mole % results in an order of magnitude decrease in the rate of transformation of ferrihydrite at pH 12. Levels of phosphate of ∼1 mol % suppress the formation of goethite (α-FeO(OH)) and result in the formation of a product consisting of η-Fe2O3. Higher levels of phosphate result in the ferrihydrite remaining amorphous, even after several hundred hours. Phosphate prevents formation of goethite by hindering the dissolution of ferrihydrite rather than by interfering with nucleation and growth of goethite in solution. The transformation rate of pure ferrihydrite is also strongly inhibited in the presence of dissolved phosphate. This is due to surface complexation. The transformation rate was measured at temperatures of 60 °C and 70 °C. The rate of transformation was found to be described by either (i) a solid-state reaction equation for powdered compacts or (ii) a zero-order reaction controlled by desorption. The transformation of the ferrihydrite matrix was accompanied by the loss of the phosphate trace component. X-ray diffraction indicates that no solid solution involving phosphate substitution into η-Fe2O3 is formed. Transmission electron microphotographs of the original precipitates containing phosphate confirm the presence of the phosphate and demonstrate its involvement in linking together extremely small particles of ferrihydrite.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    ISSN: 1573-2932
    Schlagwort(e): desorption ; ferrihydrite ; modelling ; phosphate ; TEM ; transformation ; wastewater
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract The presence of phosphate retards the transformation of ferrihydrite into crystalline products. Increasing phosphate from 0 to 1 mole % results in an order of magnitude decrease in the rate of transformation of ferrihydrite at pH 12. Levels of phosphate of ∼1 mol % suppress the formation of goethite (α-FeO(OH)) and result in the formation of a product consisting ofη-Fe2O3. Higher levels of phosphate result in the ferrihydrite remaining amorphous, even after several hundred hours. Phosphate prevents formation of goethite by hindering the dissolution of ferrihydrite rather than by interfering with nucleation and growth of goethite in solution. The transformation rate of pure ferrihydrite is also strongly inhibited in the presence of dissolved phosphate. This is due to surface complexation. The transformation rate was measured at temperatures of 60 °C and 70 °C. The rate of transformation was found to be described by either (i) a solid-state reaction equation for powdered compacts or (ii) a zero-order reaction controlled by desorption. The transformation of the ferrihydrite matrix was accompanied by the loss of the phosphate trace component. X-ray diffraction indicates that no solid solution involving phosphate substitution intoη-Fe2O3 is formed. Transmission electron microphotographs of the original precipitates containing phosphate confirm the presence of the phosphate and demonstrate its involvement in linking together extremely small particles of ferrihydrite.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
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