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  • 63.20  (1)
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    Electronic Resource
    Electronic Resource
    The thermal motion of gold atoms in metal cluster compounds as determined by Mössbauer and specific heat (1989)
    Springer
    The European physical journal 12 (1989), S. 193-197 
    Details
    ISSN: 1434-6079
    Keywords: 33.40 ; 63.20 ; 65.40
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract 197Au Mössbauer effect spectroscopy and specific heat measurements have been performed as a function of temperature on three gold polynuclear cluster compounds, [Au9(PPh3)8](NO3)3, Au11(PPh3)7(SCN)3, and Au55(PPh3)12Cl6. The Mössbauer data yield information on the vibrational motions of the various distinguishable Au sites, as well as on the motion of the clusters as a whole. The Mössbauer and the specific heat data are successfully described by a superposition of inter- and intra-cluster vibrations. The latter are determined by calculating numerically the normal modes of vibration of the metal cores.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01426936
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