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  • Organic Chemistry  (5)
  • SPACE COMMUNICATIONS, SPACECRAFT COMMUNICATIONS, COMMAND AND TRACKING  (2)
  • 61.40  (1)
  • 1
    ISSN: 1432-0630
    Keywords: 61.80 ; 61.40
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Fast heavy ions produce stable defects in most dielectrica. As examples mica, Polyethylenterephtalat and Polystyrol were irradiated with Ar, Ni, Kr, Xe and U ions in an energy range from 0.5 up to 20 MeV/u. The resulting defects were investigated by neutron and x-ray small-angle scattering. The ion beam supplied by the UNILAC accelerator at GSI Darmstadt is characterized by its small emittance, the well defined mass, charge and energy of the ions and their stochastical distribution in the phase space. In scattering experiments the system of scattering centers created by these ions causes a scattered intensity distribution which strongly depends on the orientation of the sample with respect to the unscattered neutron or x-ray beam. This dependence is investigated and explained. By a mathematical model — describing form, size, and density of the average ion track — the measured intensity distribution is simulated. Based on the model, computer procedures are written, simulating the scattering experiment by varying the most important experimental and instrumental parameters and calculating the expected theoretical intensity distribution on the detector. The parameter values of this model — the maximum density difference in the track, length of the defect, and radial dimension — are determined by least square fits to the measured data. A simple description of the dependence of these parameters on the ion energy can be given in relation to the energy loss of the primary ion. It is not only possible now to predict an expected track, to calculate its volume and the number of missing atoms, but moreover to check theories of the track formation.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 339 (1997), S. 708-713 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The influence of the chemical structure of rigid star-shaped multipodes composed of an adamantane central core and short rigid branches on the glass formation and crystallisation is analysed. It was found that esters of 1,3,5,7-adamantanetetracarboxylic acid with various phenols (3a-c) and esters of 1,3,5,7-tetrahydroxyadamantane with various benzoic acid derivatives (4a-c) display both crystalline and glassy states with high glass transition temperatures and melting temperatures. These quantities strongly depend on the restriction of the rotational motions about the ester groups connecting the core and the branches.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 38 (1955), S. 1178-1185 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Δ14,16-20-Keto-diene der Steroid-Reihe (vgl.I) gehen bekanntlich bei der katalytischen Hydrierung in gesättigte Verbindungen über, die im Unterschied zu den natürlichen Vertretern dieser Körperklasse sowohl an C—14 als auch an C—17 die entgegengesetzte Konfiguration (14β; 17α) aufweisen. Im Gegensatz dazu liefern dieselben Verbindungen (vgl.I) bei der chemischen Reduktion unter selektiver Absättigung der 16,17-Doppelbindung Δ14-Pregnen-Derivate mit normaler Konfiguration an C—17. Diese letzteren lassen sich in bekannter Weise in die entsprechenden natürlichen Vertreter überführen. Im Zusammenhang mit diesen Untersuchungen wurde ein neues ungesättigtes Gestagen, das 14-Dehydro-progesteron, bereitet.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 49 (1966), S. 1903-1907 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A fluorogenic renin substrate, N-CBO-L-prolyl-L-phenylalanyl-L-histidyl-L-leucyl-L-leucyl-L-valyl-L-tyrosyl-L-seryl-β-naphthylamide, has been synthesized. Upon incubation at pH 5,6 with renin and an excess of the auxiliary enzyme aminopeptidase M, it gives rise to β-naphthylamine at a rate related to the quantity of renin.
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  • 5
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The experiments described in reaction schemes 1-12 indicate that sulfide contraction via alkylative coupling (see scheme p. 729) is a potentially general method for the synthesis of secondary vinylogous amides and enolizable β-dicarbonyl compounds.
    Additional Material: 2 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 36 (1953), S. 1908-1918 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die experimentelle Verknüpfung der Polyporensäure A, eines Inhaltstoffes des Pilzes Polyporus betulinus Fr., mit dem Lanostadienol beschrieben. Dadurch ist es möglich geworden, die vollständige Konstitutionsformel II für die Polyporensäure A aufzustellen. Diese Verbindung stellt somit ein weiteres Glied einer Gruppe von Steroiden mit 31 Kohlenstoffatomen dar.
    Additional Material: 1 Ill.
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  • 7
    Publication Date: 2011-08-17
    Description: The DSN implementation of a system for measuring UT1 and polar motion using very long baseline interferometry (VLBI) is currently being tested. The VLBI experiments are being conducted on a weekly basis on each of two intercontinental baselines. During a 17 day period in September 1979, data were obtained for seven consecutive experiments using an early version of that system. Those experiments were used to refine the estimation procedure to be used in the operational system and to provide a preliminary assessment of the performance of the system.
    Keywords: SPACE COMMUNICATIONS, SPACECRAFT COMMUNICATIONS, COMMAND AND TRACKING
    Type: The Telecommun. and Data Acquisition Rept.; p 15-20
    Format: text
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  • 8
    Publication Date: 2014-09-12
    Description: Very Long Baseline Interferometry (VLBI) in the DSN provides support for spacecraft navigation, Earth orientation measurements, and synchronization of network time and frequency standards. An improved method for calibrating instrumental phase shifts has recently been implemented as a computer program in the Block 1 system. The new calibration program, called PRECAL, performs calibrations over intervals as small as 0.4 seconds and greatly reduces the amount of computer processing required to perform phase calibration.
    Keywords: SPACE COMMUNICATIONS, SPACECRAFT COMMUNICATIONS, COMMAND AND TRACKING
    Type: The Telecommun. and Data Acquisition Rept.; p 54-62
    Format: text
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