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  • 551.9  (1)
  • geochronology  (1)
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  • 1
    Publikationsdatum: 2023-10-24
    Beschreibung: 〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉In a reconnaissance study, we investigated the potential of γ‐ray induced production of 〈sup〉38〈/sup〉Ar〈sub〉K〈/sub〉 from 〈sup〉39〈/sup〉K for geochronological applications. For this purpose, various age monitors commonly in use for the established 〈sup〉40〈/sup〉Ar/〈sup〉39〈/sup〉Ar‐method were co‐irradiated for 60 h at 17.6 MeV maximum energy in the ELBE facility, Dresden‐Rossendorf, Germany. Because the available energy was low, total production of 〈sup〉38〈/sup〉Ar〈sub〉K〈/sub〉 was depressed, leading to low 〈italic toggle="no"〉J〈/italic〉〈sub〉38〈/sub〉‐values of (2.1–4.1) × 10〈sup〉‐6〈/sup〉 and hence resulted in only minor 〈sup〉38〈/sup〉Ar excess when compared with atmospheric 〈sup〉38〈/sup〉Ar〈sub〉/〈/sub〉〈sup〉36〈/sup〉Ar ratios. In spite of these restrictions, ages of younger monitors could be reproduced within error, whereas older age reference materials showed discrepancies due to the low production rate. We observed Ca‐derived contributions on 〈sup〉36〈/sup〉Ar in analysed CaF〈sub〉2〈/sub〉 reference materials, and calculated a limit for Ca‐interference on 〈sup〉38〈/sup〉Ar〈sub〉Ca〈/sub〉 of (〈sup〉38〈/sup〉Ar/〈sup〉36〈/sup〉Ar)〈sub〉Ca〈/sub〉 = 0.07 ± 0.03 (1〈italic toggle="no"〉s〈/italic〉). In addition, we investigated a potential recoil redistribution of 〈sup〉38〈/sup〉Ar by stepwise heating experiments, but could not quantify this further because of concurring processes. More work at higher photon energies is necessary to resolve other open issues, in particular the potential of utilising 〈sup〉40〈/sup〉Ar/〈sup〉37〈/sup〉Ar ratios for age determination and the possibility of 〈sup〉42〈/sup〉Ar production from 〈sup〉44〈/sup〉Ca, which would allow correction for Ca‐interference reactions on other Ar isotopes. This would be a pre‐requisite for dating extra‐terrestrial rocks.〈/p〉
    Beschreibung: Klaus‐Tschira‐Stiftung gGmbH
    Schlagwort(e): ddc:550.724 ; geochronology ; γ‐irradiation ; 40Ar/39Ar dating ; age spectra ; isochrons
    Sprache: Englisch
    Materialart: doc-type:article
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2021-07-21
    Beschreibung: The lunar meteorite Dhofar 1436 is dominated by solar wind type noble gases. Solar argon is equilibrated with “parentless” 40Ar commonly known as lunar orphan argon. Ar‐Ar isochron analyses determined the lunar trapped 40Ar/36Ar ratio to 2.51 ± 0.04, yielding a corrected plateau age of 4.1 ± 0.1 Ga, consistent with the lunar Late Heavy Bombardment period. Lunar trapped and radiogenic argon components are all released at high temperatures (1200–1400 °C). Surprisingly, solar noble gases and lunar trapped argon can largely be released by crushing. Initial crushing steps mainly release elementally fractionated solar wind gases, while in advanced crushing steps, cosmogenic components dominate. Cosmogenic noble gases indicate irradiation at the lunar surface; they are less fractionated than solar wind species. We favor a scenario in which both solar and a large fraction of cosmogenic gases were acquired before the 4.1 Ga event, which caused shock metamorphism and formation of the regolith breccia. Sintering and agglutination along grain boundaries resulted in mobilization of solar wind, reimplanted, radiogenic, and cosmogenic noble gases, and resulted in their partial homogenization, fractionation, and retrapping in voids and/or defects accessible by crushing. An alternative scenario would be complete reset of the K‐Ar system 4.1 Ga ago accompanied by loss of all previously accumulated solar and cosmogenic noble gases. Later, the precursor of Dhofar 1436 became lunar regolith and accumulated solar and cosmogenic noble gases and reimplanted 40Ar before its final formation of the polymict impact breccia. The C abundance of the step‐combusted Dhofar 1436 is 555.3 ppm, with δ13C of −28‰ to +11‰. Nitrogen contents released by crushing and combustion are 3.2 ppm and 20.8 ppm, respectively. The lightest nitrogen composition (δ15N = −79‰) is likely due to release from voids of shock metamorphic phases and is rather a result of the mobilization of nitrogen components that accumulated prior to the 4.1 Ga event.
    Beschreibung: Klaus Tschira Stiftung http://dx.doi.org/10.13039/501100007316
    Schlagwort(e): 523.51 ; 551.9 ; 549.112 ; lunar meteorite Dhofar 1436 ; impact melt breccia ; argon isotope data ; noble gas measurements
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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