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  • 1
    Publication Date: 2021-10-06
    Description: Cliff failure is a fundamental process shaping many coastlines worldwide. Improved insight into direct links between cliff failure and forcing mechanisms requires precise information on the timing of individual failures, which is difficult to obtain with conventional observation methods for longer stretches of coastline. Here we use seismic records and auxiliary data spanning 25 months to precisely identify and locate 81 failure events along the 8.6-km-long chalk cliff coast of Jasmund, on Germany's largest island, Rügen. The subminute precision of event timing allows the linkage of individual failures to triggers over a wide range of relevant time scales. We show that during the monitoring interval, marine processes were negligible as a trigger of cliff failure, although still being important for the removal of resulting deposits. Instead, cliff failure was associated with terrestrial controls on rock moisture. Most failures occurred when water caused a state transition of the cliff forming chalk, from solid to liquid. Water content was modulated by (i) subsurface flow toward the cliff, (ii) rain onto the cliff, and (iii) condensation of atmospheric moisture, leading to clustered failures preferentially during the night. Seasonal water availability, controlled by plant activity, imposed an annual cycle of cliff failure, and wetter and drier than average years imposed a month-long legacy effect on cliff failure dynamics. Similar terrestrial control mechanisms may also be relevant for other coastal chalk cliffs, in addition to already investigated marine triggers.
    Keywords: 551.307 ; cliff coast ; mass wasting ; cliff failure ; environmental seismology ; trigger analysis ; natural hazard
    Language: English
    Type: map
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 3 (1989), S. 289-292 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The observation of sharp limits to the chain lengths of alkyl cations derived by low energy collision-induced dissociation of isotopically labelled trimethyltetradecylammonium cations, as well as the selectively limited scrambling of its isotope label, has prompted the proposal of a new mechanistic model for alkyl cation fragmentation. The model invokes protonated cyclopropane intermediates which may reopen to branched structures, or fragment (if suitably substituted) to form smaller alkyl cations and neutral olefins. The model accounts completely for the absence of daughter ions with fewer than three or more than six carbon atoms, while its semi-quantitative application provides a reasonable match to the observed isotope scrambling.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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