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  • 1
    Publication Date: 2021-03-29
    Description: The effect of iron content and iron nanolites on Raman spectra of hydrous geologically-relevant glasses is presented. Current procedures to estimate the water content using Raman spectra were tested to explore potential effects of iron content, its oxidation state, and nanolites on models' reliability. A chemical interval spanning from basalt to rhyolite, including alkali- and iron-rich compositions, with water content up to 5.6 wt% was investigated using two spectrometers. When considering nanolite-free samples, the area of the band at 3550 cm−1 linearly correlates with the sample water content regardless of chemical composition. Using this approach, data were reproduced with a root-mean-square error (RMSE) of ~ 0.15 wt%. Depending on the sample chemistry, water content, and acquisition conditions the laser-induced sample oxidation led to underestimating the water content up to ~ 90% with a long acquisition time (26 min). Normalising the water band region to the silicate band region minimises such a limitation. The area ratio between these bands linearly correlates with the water content and the use of different baseline procedures does not remove the dependence of such a correlation by the iron content and its oxidation state. With this procedure, data were reproduced with a RMSE of ~ 0.16 wt%. For both approaches, the presence of iron nanolites may result in underestimating the water content.
    Keywords: Raman spectroscopy Glasses Water Iron Nanolites ; 551
    Language: English
    Type: article , publishedVersion
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  • 2
    Publication Date: 2020-02-24
    Description: Plinian-type eruptions are extremely hazardous, producing pyroclastic fallout and flows extending many kilometres from the vent. The most commonly invoked eruption trigger for Plinian-type eruptions is the intrusion of fresh magma, generally associated with precursory ground deformation and seismicity days/weeks before eruption. Closed-system internal triggering has also been proposed, such as protracted crystallisation of magma, which can produce a build-up of exsolved volatiles and thus pressurise the system prior to eruption. On 22–23 April 2015 Calbuco volcano, Chile, produced a sub-Plinian eruption with 〈3 h seismic precursory activity and no clear deformation signals in the preceding months. Here, we show that petrological and geochemical evidence do not support a hypothesis of eruption triggering due to pre-eruptive intrusion of fresh magma, but instead are consistent with an internal trigger. We found that basaltic andesitic magma was stored at depths between 8 and 12 km (i.e. 230–320 MPa) beneath Calbuco volcano before the 2015 eruption. The stored magma had an initial temperature of 900–950 °C, was water-saturated (5.5–6.5 wt% H2O) and formed phenocrysts of titanomagnetite, orthopyroxene, clinopyroxene and plagioclase cores (An78–93). Gradual cooling of the magma chamber produced thermal gradients and magma convection, evidenced by plagioclase overgrowth rims (An58–77) and blocky microlites (25–250 μm). Our interpretation is that this continuing crystallisation induced second boiling and an over-pressurisation of the system, leading to the rapid onset of the 2015 eruption. Petrological and geochemical evidence therefore shows that a closed-system magma chamber can evolve into a highly explosive eruption with very little precursory warning, posing a challenge for current volcano monitoring paradigms. We propose that internal triggering should be carefully considered as a mechanism for unexpected sub-Plinian eruptions, prompting a potential revision of existing hazard management strategies.
    Description: Published
    Description: 35-50
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Calbuco ; Sub-Plinian eruption ; Internal trigger ; Crystallisation ; Volcanic hazard ; 04.08. Volcanology ; Petrology ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2021-03-29
    Description: Hydrothermal quartz crystals, which occur in the Rusey Fault Zone (Cornwall, UK), show feathery textures and network-like filamentous textures. Optical hotcathodoluminescence (CL) analysis and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) investigations on quartz samples revealed that positions exhibiting feathery textures (violet luminescence) contain higher amounts of Al and Li than quartz positions without feathery textures (blue luminescence), while concentrations of Al and Li are significantly lower in feathery textures. Both Al and Li correlate negatively with Si. Raman spectroscopy investigations revealed the presence of a weak peak at 507– 509 cm􀀀1 in quartz affected by feathery textures, which we attribute to the presence of 5% moganite, a microcrystalline silica polymorph, intergrown with chalcedony. The combined occurrence of feathery textures and network-like filamentous textures in quartz samples from the Rusey Fault Zone points to the presence of a metastable silica precursor (i.e., amorphous silica or silica gel) before or during the crystallization.
    Keywords: filamentous textures; re-crystallization; quartz; Rusey Fault Zone ; 551
    Language: English
    Type: article , publishedVersion
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