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  • 1
    ISSN: 1573-1561
    Keywords: aggregation pheromone ; α-cubebene ; 2,4-dimethyl-5-ethyl-6 ; 8-dioxabicyclo(3.2.1)octane ; Dutch elm disease ; elm bark beetle ; insect attractant ; 4-methyl-3-heptanol ; multilure ; multistriatin ; Scolytus multistriatus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract The secondary attractant for the smaller European elm bark beetleScolytus multistriatus is a mixture of three compounds: (-)4-methyl-3-heptanol(I); 2,4-dimethyl-5-ethyl-6,8-dioxabicyclo(3.2.1) octane (II); and (−)α-cubebene (III). The novel structure assigned to compound II was confirmed by synthesis. All three compounds were isolated from the volatile compounds collected on Porapak Q by aerating elm bolts infested with virgin female beetles. The GLC fractionations were monitored by two laboratory bioassays. Individually, each compound was inactive in the laboratory bioassays, but a mixture of all three showed activity nearly equivalent to that of the of the original Porapak extract. A mixture of synthetic I and II plus natural III (from cubeb oil) was highly attractive to beetles in preliminary field tests.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-1561
    Keywords: Scolytus multistriatus ; bioassay ; aggregating pheromone ; isomers ; enantiomers ; 4-methyl-3-heptanol ; α-multistriatin ; α-cubebene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Laboratory bioassays (two methods) and field tests demonstrated synergistic action of the three components [(−)-4-methyl-3-heptanol (I); (−)-2,4-dimethyl-5-ethyl-6,8-dioxabicylo[3.2.1]octane (α-multistriatin) (II); and (−)-α-cubebene (III)] of the pheromone bouquet ofScolytus multistriatus. Individually and in pairs the components were slightly attractive; I+II was clearly the most active doublet. Indirect evidence indicates that only one of the four enantiomers of I is active. Of the α, β, γ and δ isomers of II, only the α is active. With the addition of compound I, slightly attractive extract from mated females became nearly as active as extract from virgin females.
    Type of Medium: Electronic Resource
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