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  • Articles  (5)
  • 33.80.Wz  (1)
  • 42.50  (1)
  • 42.60.Da  (1)
  • 42.60.Fc  (1)
  • 82.50. − m  (1)
  • Chemistry  (1)
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  • Articles  (5)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 35 (1984), S. 123-126 
    ISSN: 1432-0649
    Keywords: 42.50 ; 42.60
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Spatial separation of wavelengths in a CO2-laser resonator helps to avoid competitions. We have achieved this by means of a nearly concentric resonator with a grating or prism in its center. Thus, we demonstrated independent multiline emission with a variety of output spectra. The temporal sequence of the lines was conveniently controlled by varying their losses.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 55 (1992), S. 65-70 
    ISSN: 1432-0649
    Keywords: 42.60.Da ; 42.60.Fc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A low-pressure (20 mbar) CO2 laser allows to extract pulses at several selected wavelengths simultaneously from the same active medium. We demonstrated this, using an industrial laser modified by a Q-switch and a resonator with two branches. In one branch the wavelengths are spatially separated, whereas in the other they oscillate in one common transverse mode. We designed a multi-wavelength resonator which requires a single additional reflector compared to usual laser cavities. It provided tunable oscillation at six wavelength simultaneously.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 62 (1996), S. 203-212 
    ISSN: 1432-0649
    Keywords: 33.80.Wz
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Searching for oxygen-isotope selectivity, we investigated the infrared multiphoton dissociation of the formaldehyde trimer around 10 µm, in a range where the molecule has a degenerate and a non-degenerate CO stretch vibration and a degenerate CH2 deformation vibration. In the region of the two latter, the wavelength dependence of the dissociation yield exhibits sharp structures. They were assigned ton-photon resonances (n = 2, 3, 5) by the help of the IR spectrum in the fundamental and overtone region. The O and C selectivities were very small (1.05) near the non-degenerate CO stretch band, but surprisingly large (2–4) in the CH2 deformation, which has no isotopic shift. The selectivity is not controlled by the first (n-photon) excitation step, but only by a later step. Its assignment is attempted. The pressure dependence of the dissociation is peculiar: Only after an initial decrease, the yield exhibits the usual rise with pressure. We attribute the decrease to a relaxation which perturbs the two-photon resonance.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 24 (1992), S. 47-56 
    ISSN: 1434-6079
    Keywords: 82.50. − m
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract 13C isotope separation by multiphoton dissociation of CHClF2 was studied by a continuous-discharge CO2 laserQ-switched at 8 kHz. This laser can easily emit two or more wavelengths with good spatial and temporal overlap. The best irradiation results were obtained by the line pair 9P16 + 9P28. After optimizing also the pressures of CHClF2 and of buffer gases (He and Ar), the energy density and the gas speed, the process is now much less nonlinear than in previous experiments with a single wavelength. Differences to the TEA laser induced process were observed, and generally the pressure influence on yield and selectivity showed a variety of phenomena. They were interpreted in terms of collisional changes of spectra during the laser pulse.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 19 (1840), S. 510-511 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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