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  • 1
    Electronic Resource
    Electronic Resource
    Cluster-model study of the interaction of halogen atoms with Ag clusters (1989)
    Springer
    The European physical journal 12 (1989), S. 543-546 
    Details
    ISSN: 1434-6079
    Keywords: 31.20 ; 36.40
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Analysis of ab initio wave functions shows that the interaction between halogen atoms (F, Cl, and Br) and Ag clusters is ionic, and that the halogen ionicity is essentially −1. The interaction and the bonding arise, almost entirely, from the Coulomb attraction between the charged halogen and the metal and from polarization of the two subunits. Large shifts in equilibrium bond distances and vibrational energies are caused by an external electric field. These changes arise from a dominant Stark effect.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01427014
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