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  • North Atlantic Ocean  (2)
  • 30-289; AGE; Deep Sea Drilling Project; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Glomar Challenger; Lanthanum/Cerium, standard deviation; Lanthanum/Cerium ratio; Leg30; Magnesium/Calcium ratio; Magnesium/Calcium ratio, standard deviation; Sample code/label; Sodium/Calcium ratio; Sodium/Calcium ratio, standard deviation; South Pacific/PLATEAU; Strontium/Calcium ratio; Strontium/Calcium ratio, standard deviation  (1)
  • ANTIPROD; APSARA4; Marion Dufresne (1972); MD80-304; MD88-769; PC; Piston corer; RC13; RC13-229; Robert Conrad; South Indian Ocean; South Pacific  (1)
  • Meltwater pulse
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Keywords
Years
  • 1
    Publication Date: 2023-06-27
    Keywords: 30-289; AGE; Deep Sea Drilling Project; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Glomar Challenger; Lanthanum/Cerium, standard deviation; Lanthanum/Cerium ratio; Leg30; Magnesium/Calcium ratio; Magnesium/Calcium ratio, standard deviation; Sample code/label; Sodium/Calcium ratio; Sodium/Calcium ratio, standard deviation; South Pacific/PLATEAU; Strontium/Calcium ratio; Strontium/Calcium ratio, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 265 data points
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  • 2
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    Unknown
    PANGAEA
    In:  Supplement to: Rosenthal, Yair; Boyle, Edward A; Labeyrie, Laurent D; Oppo, Delia W (1995): Glacial enrichments of authigenic Cd and U in Subantarctic sediments: A climatic control on the elements' oceanic budget? Paleoceanography, 10(3), 395-414, https://doi.org/10.1029/95PA00310
    Publication Date: 2023-06-27
    Description: We examine the possibility that glacial increase in the areal extent of reducing sediments might have changed the oceanic Cd inventory, thereby decoupling Cd from PO4. We suggest that the precipitation of Cd-sulfide in suboxic sediments is the single largest sink in the oceanic Cd budget and that the accumulation of authigenic Cd and U is tightly coupled to the organic carbon flux into the seafloor. Sediments from the Subantarctic Ocean and the Cape Basin (South Atlantic), where oxic conditions currently prevail, show high accumulation rates of authigenic Cd and U during glacial intervals associated with increased accumulation of organic carbon. These elemental enrichments attest to more reducing conditions in glacial sediments in response to an increased flux of organic carbon. A third core, overlain by Circumpolar Deep Water (CPDW) as are the other two cores but located south of the Antarctic Polar Front, shows an approximately inverse pattern to the Subantarctic record. The contrasting patterns to the north and south of the Antarctic Polar Front suggest that higher accumulation rates of Cd and U in Subantarctic sediments were driven primarily by increased productivity. This proposal is consistent with the hypothesis of glacial stage northward migration of the Antarctic Polar Front and its associated belt of high siliceous productivity. However, the increase in authigenic Cd and U glacial accumulation rates is higher than expected simply from a northward shift of the polar fronts, suggesting greater partitioning of organic carbon into the sediments during glacial intervals. Lower oxygen content of CPDW and higher organic carbon to biogenic silica rain rate ratio during glacial stages are possible causes. Higher glacial productivity in the Cape Basin record very likely reflects enhanced coastal up-welling in response to increased wind speeds. We suggest that higher productivity might have doubled the areal extent of suboxic sediments during the last glacial maximum. However, our calculations suggest low sensitivity of seawater Cd concentrations to glacial doubling of the extent of reducing sediments. The model suggests that during the last 250 kyr seawater Cd concentrations fluctuated only slightly, between high levels (about 0.66 nmol/kg) on glacial initiations and reaching lowest values (about 0.57 nmol/kg) during glacial maxima. The estimated 5% lower Cd content at the last glacial maximum relative to modern levels (0.60 nmol/kg) cannot explain the discordance between Cd and delta13C, such as observed in the Southern Ocean. This low sensitivity is consistent with foraminiferal data, suggesting minimal change in the glacial Cd mean oceanic content.
    Keywords: ANTIPROD; APSARA4; Marion Dufresne (1972); MD80-304; MD88-769; PC; Piston corer; RC13; RC13-229; Robert Conrad; South Indian Ocean; South Pacific
    Type: Dataset
    Format: application/zip, 8 datasets
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  • 3
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 20 (2005): PA2003, doi:10.1029/2004PA001074.
    Description: Stable isotope, trace metal, alkenone paleothermometry, and radiocarbon methods have been applied to sediment cores in the western subpolar North Atlantic between Hudson Strait and Cape Hatteras to reveal the history of climate in that region over the past ∼11 kyr. We focus on cores from the Laurentian Fan, which is known to have rapid and continuous accumulation of hemipelagic sediment. Although results among our various proxy data are not always in agreement, the weight of the evidence (alkenone sea surface temperature (SST), δ18O and abundance of Globigerinoides ruber) indicates a continual cooling of surface waters over Laurentian Fan, from about 18°C in the early Holocene to about 8°C today. Alternatively, Mg/Ca data on planktonic foraminifera indicate no systematic change in Holocene SST. The inferred long-term decrease in SST was probably driven by decreasing seasonality of Northern Hemisphere insolation. Two series of proxy data show the gradual cooling was interrupted by a two-step cold pulse that began 8500 years ago, and lasted about 700 years. Although this event is associated with the final deglaciation of Hudson Bay, there is no δ18O minimum anywhere in the Labrador Sea, yet there is some evidence for it as far south as Cape Hatteras. Finally, although the 8200 year B.P. event has been implicated in decreasing North Atlantic ventilation, and hence widespread temperature depression on land and at sea, we find inconsistent evidence for a change at that time in deep ocean nutrient content at ∼4 km water depth.
    Description: Funding for JPS was from the NOAA Climate and Global Change Program (NA 16GP2679), NSF-Earth System History (0116940), the Jeptha H. and Emily V. Wade Award for Research, and a Henry L. and Grace Doherty Professorship. LDK and YR were funded by NSF grant OCE-0117149.
    Keywords: Lake Agassiz ; 8200 year event ; Meltwater pulse
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 4
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    Unknown
    American Geophysical Union
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 23 (2008): PA1101, doi:10.1029/2007PA001500.
    Description: Models indicate that a complete shutdown of deep and intermediate water production is a possible consequence of extreme climate conditions in the northern North Atlantic, and the high ratio of 231Pa to 230Th on Bermuda Rise is evidence that this might have happened ∼17 ka during Heinrich event 1 (H1). However, new radiocarbon data from bivalves that lived at ∼4.6 km on the Bermuda Rise during H1 lead to a different conclusion. The bivalve data do indeed indicate ventilation of the deep western North Atlantic was suppressed during H1 but not as much as it was during the last glacial maximum. We propose that high diatom flux to the Bermuda Rise during H1 is at least in part responsible for increased 231Pa/230Th at that time. Although we cannot say for sure why opal production was so high in a gyre center location at that time, increased leakage of silica rich waters from the Southern Ocean to the North Atlantic is one possibility.
    Description: This work was funded by a grant from the Comer Foundation to WHOI’s Ocean and Climate Change Institute.
    Keywords: North Atlantic Ocean ; Meridional overturning ; Heinrich event
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 5
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2014. This is the author's version of the work. It is posted here by permission of Elsevier for personal use, not for redistribution. The definitive version was published in Marine Chemistry 173 (2015): 125-135, doi:10.1016/j.marchem.2014.09.002.
    Description: The size partitioning of dissolved iron and organic iron-binding ligands into soluble and colloidal phases was investigated in the upper 150 m of two stations along the GA03 U.S. GEOTRACES North Atlantic transect. The size fractionation was completed using cross-flow filtration methods, followed by analysis by isotope dilution inductively-coupled plasma mass spectrometry (ID-ICP-MS) for iron and competitive ligand exchange-adsorptive cathodic stripping voltammetry (CLE-ACSV) for iron-binding ligands. On average, 80% of the 0.1-0.65 nM dissolved iron (〈0.2 μm) was partitioned into the colloidal iron (cFe) size fraction (10 kDa 〈 cFe 〈 0.2 μm), as expected for areas of the ocean underlying a dust plume. The 1.3-2.0 nM strong organic iron-binding ligands, however, overwhelmingly (75-77%) fell into the soluble size fraction (〈10 kDa). As a result, modeling the dissolved iron size fractionation at equilibrium using the observed ligand partitioning did not accurately predict the iron partitioning into colloidal and soluble pools. This suggests that either a portion of colloidal ligands are missed by current electrochemical methods because they react with iron more slowly than the equilibration time of our CLE-ACSV method, or part of the observed colloidal iron is actually inorganic in composition and thus cannot be predicted by our model of unbound iron-binding ligands. This potentially contradicts the prevailing view that greater than 99% of dissolved iron in the ocean is organically complexed. Untangling the chemical form of iron in the upper ocean has important implications for surface ocean biogeochemistry and may affect iron uptake by phytoplankton.
    Description: J.N. Fitzsimmons was funded by a National Science Foundation Graduate Research Fellowship (NSF Award #0645960). Research funding was provided by the National Science Foundation (OCE #0926204 and OCE #0926197) and the Center for Microbial Oceanography: Research and Education (NSF-OIA Award #EF-0424599) to E.A. Boyle. R.M. Bundy was partially funded by NSF OCE-0550302 and NSF OCE-1233733 to K.A. Barbeau and an NSF-GK12 graduate fellowship.
    Keywords: Iron ; Iron ligands ; CLE-ACSV ; Colloids ; Ultrafiltration ; Trace metals ; GEOTRACES ; North Atlantic Ocean ; Chemical oceanography
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
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