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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 347 (1993), S. 15-20 
    ISSN: 1434-601X
    Keywords: 21.10 ; 27.50
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A microscopic description of negative parity states in the nucleus68Ge is presented. The investigation is based on the EXCITED VAMPIR model in which via a chain of variational calculations first an optimal configuration space ofi symmetry-projected Hartree-Fock-Bogoliubov determinants for thei lowest states of a given symmetry is constructed and subsequently the residual interaction is diagonalised. Though some considerable quantitative discrepancies are obtained, qualitatively the theoretical results agree rather nicely with the complex pattern of negative parity states in this nucleus which has been recently found experimentally. Underlying structures and electromagnetic properties are discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of comparative physiology 178 (1996), S. 551-561 
    ISSN: 1432-1351
    Keywords: Chickens ; Emmetropization ; Breed ; Gender ; Form deprivation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract This study investigated the influences of breed and gender on the response to form deprivation and subsequent changes (recovery) when normal vision was restored. Two breeds of chickens, the White Leghorn and broiler cross, were compared, as well as male and female chicks for the White Leghorn breed. Normal eye growth was faster in the more rapidly growing broiler chicks; gender-differences were not as great as breed-differences although male White Leghorns ultimately became heavier and showed slightly greater normal eye growth than females. While both breeds showed high myopia and axial elongation in response to form deprivation, they differed significantly in the magnitude of their response, with White Leghorns showing more myopia and greater axial elongation and also recovering more slowly. Responses to form deprivation were similar for both genders, with respect to both the amount of myopia and axial elongation produced, although the female chicks recovered faster. Together these observations indicate that, although the overall pattern of response of form deprivation is consistent across both breed and gender, related quantitative differences in responses can be expected and need to be taken into account in experimental design and cross-study comparisons.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 36 (1953), S. 489-500 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei Studien der para-Claisen-Umlagerung mit Hilfe von 14C-markiertem Allyl-[2,6-dimethyl-phenyl]-äther liess sich durch Kreuzexperimente und durch Abbau des Allyläthers und seines Umlagerungsproduktes zeigen, dass die para-Umlagerung streng intramolekular und ohne Inversion des Allylrestes verläuft.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 35 (1952), S. 1879-1890 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Ausgehend von radioaktivem kaliumeyanid wurde der p-Kresyl-allyläther hergestellt, in dem das γ-C-Atom durch 14C markiert ist.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 36 (1953), S. 687-690 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Photolyse (25°) von 14C-Allyl-(2,6-dimethyl-phenyl)-äther mit 97,4% der Radioaktivität im γ-C-Atom des Allylrestes entstand neben 2,6-Dimethylphenol in 1,4-proz. Ausbeute 2,6-Dimethyl-4-allylphenol, in dem die Radioaktivität auf das α- und das γ-C-Atom ungefähr gleichmässig verteilt ist.
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  • 6
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: N-Methyltropiniumchlorid, in welchem eine der beiden unsymmetrisch angeordneten N-Methylgruppen durch 14C signiert war, gab bei der thermischen Zersetzung Tropin und Methylchlorid von ungefähr gleicher molarer Radioaktivität. Die Abspaltung verläuft somit stereounspezifisch. Aus einem Kreuzversuch folgte, dass die eigentliche Abspaltungsreaktion von gleichfalls nicht stereospezifisch verlaufenden Rekombinations- oder Ummethylierungsreaktionen begleitet ist.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 39 (1956), S. 555-563 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurde gezeigt, dass sich 2, 6-Dimethyl-4-allyl-[γ-14C]-phenylallylather beim Erhitzen auf 168° in ein mit dem Ausgangsmaterial chemisch identisches Produkt umlagert, in welchem die Radioaktivität zu gleichen Teilen in den γ-C-Atomen des O- und C-Allylrestes lokalisiert ist.
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  • 8
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der thermischen Umlagerung von [2-Propenyl-4,6-dimethyl-phenyl]-allyl-[γ-14C]-äther entst and ein 2-[P-Methyl-penta-α, δ-dienyl]-4,6-dimethyl-phenol, in welchem 84% der Radioaktivität im α- und 16% im γ-C-Atom der Pentadienyl-Seitenkette lokalisiert waren. Das Resultat eines Kreuzversuches spricht dagegen, dass diese Radioaktivitätsverteilung auf Radikalreaktionen zurückzuführen ist. Die möglichen unimolekularen Mechanismen dieser Seitenkettenumlagerung von Aryl-allyläthern aerden diskutiert.
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 44 (1961), S. 1622-1645 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of phosphamidon, a new systemic insecticide, is describcd. By use of the 14C-labeled compound it is shown that in the bean plant phosphamidon undergoes rapid degradation, during which traces of the metabolites desethylphosphamidon,α-chloroacetoaceto-diethylamide, and α-chloroacetoaceto-ethylamide only are detectable. In order to explain the mechanism of the degradation reactions, the behaviour of phosphamidon towards acids and bases has been studied.
    Additional Material: 7 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 37 (1954), S. 1080-1093 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Anhand von Experimenten mit radioaktiv markierten Stoffen liess sich zeigen, dass die thermische para-Claisen-Umlagerung von 2,6-Diallylphenyl-allyläther zu 2,4,6-Triallylphenol uber 2,2-Diallyl-6-allyl-cyclohexadienon-(l) als Zwischenprodukt verläuft. Dabei werden zwei cyclische Zwischenzustände durchschritten, die jedesmal eine Inversion der wandernden Allylgruppe bewirken.
    Additional Material: 1 Ill.
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