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  • 21.10.HW  (1)
  • polyimides  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 331 (1988), S. 409-432 
    ISSN: 1434-601X
    Keywords: 27.30.+ t ; 21.10.HW ; 21.60.Cs
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Gamma decay modes and spin assignments of levels in27Al have been investigated by proton-γ-ray angular correlation measurements in the24Mg(α, pγ) reaction at 14.2, 15 and 15.6 MeV bombarding energy and byγ-ray angular distribution measurements on the Ep=1820, 2114, 2293 and 2574 keV resonances of the26Mg(p, γ) reaction. Unique spin assignments were obtained as follows: I=3/2 for the 5827 keV state, I=5/2 for the 6115, 6465, 6765, 7577, 7721, 8097, 8136, 8324 keV states, I=7/2 for the 5433, 6533, 7413, 8037, 8442, 8586 keV states, I=9/2 for the 5418, 6512, 6713, 7997 keV states, I=11/2 for the 5500, 6948, 7400, 8396 keV states. The level scheme and electromagnetic properties of levels are compared with the results of shell model calculations which use the complete configuration space of the 0d5/2-1s1/2-0d3/2 shell and the unifieds-d shell Hamiltonian. The agreement is good to excellent and extends into the region of high level density above 7 MeV excitation energy. The total B(M1↑) below 8.5 MeV excitation energy is evaluated, using published resonance fluorescence and (e, e′) data, and quenching relative to the free-nucleon predictions is reexamined. Evidence in favour of a prolate ground state deformation of27Al and implications of this work for the astrophysically interesting26Al(p, γ) reaction are discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 1855-1868 
    ISSN: 0887-6266
    Keywords: gas permeability ; permselectivity ; activation energies ; free volume ; polyimides ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Gas transport of helium, hydrogen, carbon dioxide, oxygen, argon, nitrogen, and methane in three soluble poly(phenylene sulfone imide)s based on 2,2-bis(3,4-decarboxyphenyl) hexafluoropropane dianhydride (6FDA) has been investigated. The effects of increasing length of well-defined oligo(phenylene sulfone) units on the gas permeabilities and diffusivities were determined and correlated with chain packing of the polymers. Activation energies of diffusion and permeation were calculated from temperature-dependent time-lag measurements. The influences of the central group in the diamine moiety of 6FDA-based polyimides on physical and gas transport properties are discussed. The incorporation of a long oligo(phenylene sulfone) segment in the polymer backbone decreases gas permeability and permselectivity simultaneously. The decreases in permeability coefficients can be mainly related to decreases in diffusion coefficients. Changing the central group of diamine moiety from —S— to —SO2— leads to a 45-50% decrease in CO2 and O2 permeabilities without appreciable increase in the selectivities. This is considered to be due to the formation of charge transfer complexes. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 1855-1868, 1997
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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