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  • Fe‐Mn oxyhydroxides  (1)
  • 2001-043-3; 2004-024-33; 2006-040-0003; 2006-040-0004; 2008-027-0011; 2008-027-15; 2009-061-0113; 2009-061-111; 2009-061-129; AMOC; BC; Biscaya; Box corer; calculated, 2 sigma; carbonate dissolution; DEPTH, sediment/rock; dolostone; Elevation of event; Event label; GC; Giant box corer; GIK17049-6; GIK17050-1; GIK17051-2; GIK17052-4; GIK17055-1; GIK23517-3; GIK23522-2; GIK23523-3; GIK23528-3; GKG; Gravity corer; Gravity corer (Kiel type); Greenland Sea; Heinrich Stadials; HU2001-043-3; HU2004-024-33; HU2006-040-0003; HU2006-040-0004; HU2006040-006; HU2006040-057; HU2008-027-0011; HU2008-027-15; HU2009-061-0113; HU2009-061-111; HU2009-061-129; Identification; KOL; Labrador Sea; Late Quaternary; Latitude of event; Longitude of event; M11/1; Meteor (1986); Neodymium isotopes; Optional event label; PC; Piston corer; Piston corer (Kiel type); POS210/2; Poseidon; SL; TC; Trigger corer; ε-Neodymium; ε-Neodymium, standard deviation
  • neodymium isotopes
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  • 1
    Publikationsdatum: 2023-07-19
    Beschreibung: Limited constraints on the variability of the deep‐water production in the Labrador Sea complicate reconstructions of the strength of the Atlantic Meridional Overturning Circulation (AMOC) during the Late Quaternary. Large volumes of detrital carbonates were repeatedly deposited in the Labrador Sea during the last 32 kyr, potentially affecting radiogenic Nd isotope signatures. To investigate this the Nd isotope compositions of deep and intermediate waters were extracted from the authigenic Fe‐Mn oxyhydroxide fraction, foraminiferal coatings, the residual silicates and leachates of dolostone grains. We provide a first order estimation of Nd release via dissolution of detrital carbonates and its contribution to the authigenic ԑNd signatures in the Labrador Sea. During the Last Glacial Maximum the Nd isotope signatures in the Labrador Sea would allow active water mass mixing with more radiogenic ɛNd values (−12.6 and −14) prevailing in its eastern part whereas less radiogenic values (ɛNd ∼ −18.4) were found on the western Labrador slope. The deposition of detrital carbonates during Heinrich stadials (2,1) was accompanied by negative detrital and authigenic Nd isotope excursions (ɛNd ∼ −31) that were likely controlled by dissolution of dolostone or dolostone associated mineral inclusions. This highly unradiogenic signal dominated the authigenic phases and individual water masses in the Labrador Sea, serving as potential source of highly unradiogenic Nd to the North Atlantic region, while exported southward. The Holocene authigenic ɛNd signatures of the coatings and leachates significantly differed from those of the detrital silicates, approaching modern bottom water mass signatures during the Late Holocene.
    Beschreibung: Plain Language Summary: The Labrador Sea is an important region for deep water formation and for the ocean circulation in the Atlantic region. Over the last 32 thousand years, numerous discharges from melting glaciers added freshwater to the Labrador Sea which could help understand the future effects of current melting glaciers. This information is necessary to better constrain climate predictions in order to gauge the effects on the Global Ocean Water Circulation. However, past deep water production in the Labrador is still poorly constrained, complicating reconstruction of the Atlantic Meridional Overturning Circulation on different timescales. In this study we investigated changes in deep and intermediate water mass circulation patterns over the last 32 kyr based on the radiogenic Nd isotope compositions that serve as a water mass circulation proxy. Analysis of four marine sediment cores show that the deposition of large volumes of detrital carbonates during studied period had a large effect on the recorded in the sediment column signals. New data suggest active water mass circulation during the maximum extent of glacial ice sheets. The modern day ocean circulation patterns have emerged during the Late Holocene (6 ka).
    Beschreibung: Key Points: Estimation of Nd release via dissolution of detrital carbonates and its contribution to the authigenic ԑNd signatures in the Labrador Sea. Dissolution of detrital dolostones in the water column during Heinrich stadials at least partially controlled ɛNd signatures. During the LGM generally more radiogenic signatures possibly indicate active water mass advection and mixing in the Labrador Sea.
    Beschreibung: GEOMAR Helmholtz‐Zentrum für Ozeanforschung Kiel http://dx.doi.org/10.13039/501100003153
    Beschreibung: Kiel University
    Beschreibung: https://doi.org/10.1594/PANGAEA.952659
    Schlagwort(e): ddc:551.9 ; Labrador Sea ; Late Quaternary ; Paleoceanography ; neodymium isotopes ; dolostone ; AMOC ; carbonate dissolution ; Heinrich stadials
    Sprache: Englisch
    Materialart: doc-type:article
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2021-07-21
    Beschreibung: Radiogenic lead (Pb) and neodymium (Nd) isotope compositions extracted from authigenic phases in marine sediments are sensitive tracers to reconstruct past ocean circulation and water mass mixing. Chemical reductive leaching of hydrogenetic ferromanganese oxyhydroxides from bulk sediments is the most practical way to recover past seawater Pb and Nd isotope signatures in the Southern Ocean, due to the scarcity of alternative archives. However, the leached signal could be compromised if substantial quantities of Pb and Nd were released from non‐hydrogenetic sediment fractions during chemical extraction. Here we developed a very short 10‐s leaching method to extract reliable seawater Pb and Nd isotope signals from sediments in the Atlantic sector of Southern Ocean. The effect of a previously recommended MgCl2 pre‐wash, the role of chelate ligands in the leaching solution and length of leaching time were investigated. The results show that 10‐s exposure time of sediments to reductive leaching extracted sufficient and more reliable hydrogenetic Pb and Nd compared with the commonly used 30‐min leaching approaches. The robustness of our improved leaching method was validated via direct comparison of Pb and Nd isotope signatures with actual seawater, porewater, and corresponding sediment leachates from three stations in front of the Antarctic Filchner‐Rønne Ice Shelf. Our findings also indicate that in contrast previously studied sites on the West Antarctic continental shelf, the bottom seawater Nd concentration is less elevated through benthic fluxes in the area of the southern Weddell Sea shelf.
    Beschreibung: Plain Language Summary: Individual modern ocean water masses can often be identified by the isotopic signature of dissolved trace metals lead (Pb) and neodymium (Nd) supplied from surrounding continents. By analyzing past seawater Pb and Nd isotope ratios preserved in the sedimentary archives, we can understand how the ocean circulation changed. In the Southern Ocean, archives preserving past seawater Pb and Nd isotope compositions are very scarce. Thus, the chemical extraction of Pb and Nd from seawater‐derived ferromanganese oxyhydroxides within deep marine sediments becomes the most practical way to recover past seawater signal. However, Southern Ocean sediments commonly contain substantial quantities of Antarctic continental fine‐grained sediment, which easily partially dissolve during extraction, thereby releasing Pb and Nd, which did not originate from past ambient seawater. Here we established a gentle and efficient extraction method to obtain reliable past Southern Ocean seawater signatures. In addition, via analysis of regional seawater‐derived Pb and Nd signatures in the Atlantic sector of Southern Ocean, we found that the sediments further away from Antarctica and volcanically active regions are better suited to preserve unaltered seawater Pb and Nd isotope signals, which strongly supports the unique possibility of tracing past water mass sourcing in the Southern Ocean with our analytical approach.
    Beschreibung: Key Points: 10‐s reductive leaching is capable of reliably extracting seawater Pb and Nd isotope signals from Southern Ocean sediments. Natural porewater Pb isotopic compositions are analyzed for the first time in front of the Antarctic Filchner‐Rønne Ice Shelf. Identify potential sites for extracting seawater Pb and Nd isotopic signatures from bulk sediments in the Atlantic sector of Southern Ocean.
    Beschreibung: China Scholarship Council (CSC)
    Schlagwort(e): 551.9 ; Fe‐Mn oxyhydroxides ; Nd isotopes ; Pb isotopes ; reductive leaching ; sediment ; Southern Ocean
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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