ISSN:
0009-2940
Schlagwort(e):
Macrocyclic thioethers
;
Adamantane as a building block
;
Chemistry
;
Inorganic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
4,6:12,14-Di(1,3-adamantano)-1,9-dithiacyclohexadecane (1), 4,6:12,14:20,22-tri(1,3-adamantano)-1,9,17-trithiacyclotetracosane (2), and 5,7:14,16-di(1,3-adamantano)-1,2,10,11-tetrathiacyclooctadecane (3) have been obtained by intermolecular cyclization of 1,3-bis(2-bromoethyl)adamantane (4) with thioacetamide using a high-dilution technique. The reaction is concentration-dependent. The crystal structures of 1, 2, and 3 have been determined by single-crystal X-ray diffraction.
Zusätzliches Material:
3 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/cber.19941270724
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