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  • 135-839B; Chromspinel; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Joides Resolution; Leg135; Ocean Drilling Program; ODP; Olivine; Percentage; Sample code/label; South Pacific Ocean; Sum  (1)
  • 135-839B; DRILL; Drilling/drill rig; Joides Resolution; Leg135; Ocean Drilling Program; ODP; South Pacific Ocean  (1)
  • Carbonate  (1)
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  • 1
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    PANGAEA
    In:  Supplement to: Gaetani, Glenn A; Grove, Timothy L; Bryan, Wilfred B (1994): Experimental phase relations of basaltic andesite from Hole 839B under hydrous and anhydrous conditions. In: Hawkins, J; Parson, L; Allan, J; et al. (eds.), Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX (Ocean Drilling Program), 135, 557-563, https://doi.org/10.2973/odp.proc.sr.135.133.1994
    Publication Date: 2024-01-09
    Description: Experimental phase relations were used to assess the role of volatiles and crustal level fractional crystallization in the petrogenesis of lavas from Hole 839B in the central Lau Basin. Melting experiments were performed on Sample 135-839B-15R-2, 63-67 cm, at 1 atm, anhydrous, and 2 kbar, H2O-saturated (~6 wt% H2O in the melt) to determine the influence of variable pressure and H2O content on phase appearances, mineral chemistry, and liquid line of descent followed during crystallization. The effects of H2O are to depress the liquidus by ~100°C, and to suppress crystallization of plagioclase and orthopyroxene relative to olivine and high-Ca clinopyroxene. At 1 atm, anhydrous, olivine and plagioclase coexist near the liquidus, whereas orthopyroxene and then clinopyroxene appear with decreasing temperature. Crystallization of 50 wt% produces a residual liquid that is rich in FeO* (10.8 wt%) and poor in Al2O3 (13.6 wt%). At 2 kbar, H2O-saturated, the liquidus phases are olivine and chromian spinel, with high-Ca clinopyroxene appearing after ~10% crystallization. Plagioclase saturation is suppressed until ~20% crystallization has occurred. The residual liquid from 35 wt% crystallization is rich in AI2O3 (17.4 wt%), and poor in MgO (4.82 wt%); it contains moderate FeO* (8.2 wt%), and resembles the low-MgO andesites recovered from Hole 839B. On the basis of these experiments we conclude that the primitive lavas recovered from Hole 839B have experienced crystallization along the Ol + Cpx saturation boundary, under hydrous conditions (an ankaramitic liquid line of descent), and variable amounts of olivine and chromian spinel accumulation. The low-MgO andesites from Hole 839B are the products of hydrous fractional crystallization, at crustal pressures, of a parent magma similar to basaltic andesite Sample 135-839B-15R-2, 63-67 cm.
    Keywords: 135-839B; DRILL; Drilling/drill rig; Joides Resolution; Leg135; Ocean Drilling Program; ODP; South Pacific Ocean
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 2
    Publication Date: 2024-01-09
    Keywords: 135-839B; Chromspinel; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Joides Resolution; Leg135; Ocean Drilling Program; ODP; Olivine; Percentage; Sample code/label; South Pacific Ocean; Sum
    Type: Dataset
    Format: text/tab-separated-values, 25 data points
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  • 3
    Publication Date: 2022-05-26
    Description: Author Posting. © The Author(s), 2015. This is the author's version of the work. It is posted here for personal use, not for redistribution. The definitive version was published in Chemical Geology 437 (2016): 67-76, doi:10.1016/j.chemgeo.2016.05.007.
    Description: Measurements of B/Ca ratios in marine carbonates have been suggested to record seawater carbonate chemistry, however experimental calibration of such proxies based on inorganic partitioning remains limited. Here we conducted a series of synthetic aragonite precipitation experiments to evaluate the factors influencing the partitioning of B/Ca between aragonite and seawater. Our results indicate that the B/Ca ratio of synthetic aragonites depends primarily on the relative concentrations of borate and carbonate ions in the solution from which the aragonite precipitates; not on bicarbonate concentration as has been previously suggested. The influence of temperature was not significant over the range investigated (20 – 40°C), however, partitioning may be influenced by saturation state (and/or growth rate). Based on our experimental results, we suggest that aragonite B/Ca ratios can be utilized as a proxy of [CO32-]. Boron isotopic composition (δ11B) is an established pH proxy, thus B/Ca and δ11B together allow the full carbonate chemistry of the solution from which the aragonite precipitated to be calculated. To the extent that aragonite precipitation by marine organisms is affected by seawater chemistry, B/Ca may also prove useful in reconstructing seawater chemistry. A simplified boron purification protocol based on amberlite resin and the organic buffer TRIS is also described.
    Description: This work was supported by the Australian Research Council (ARC) Centre of Excellence for Coral Reef Studies. Research conducted at WHOI was supported by NSF grant OCE-1338320. M.H. was supported by an ARC Super Science Fellowship and an NSF International Postdoctoral Fellowship. T.D. was supported by a NSF Graduate Research Fellowship. M.M. was supported by a Western Australian Premiers Fellowship and an ARC Laureate Fellowship.
    Keywords: Boron ; Aragonite ; Coral ; Proxy ; Carbonate
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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