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  • Atmospheric CO2; climate sensitivity; Eocene; GMT; surface seawater pH  (3)
  • Paleoclimate  (2)
  • 121-758B; 154-926A; 154-926B; 165-999A; AGE; Caribbean Sea; Cibicidoides mundulus, δ11B; Cibicidoides wuellerstorfi, δ11B; DRILL; Drilling/drill rig; Elevation of event; Event label; Globigerina praebulloides, Magnesium/Calcium ratio; Globigerina praebulloides, δ11B; Globigerinoides ruber, Magnesium/Calcium ratio; Globigerinoides ruber, δ11B; Globigerinoides trilobus, magnesium/calcium ratio; Globigerinoides trilobus, δ11B; Indian Ocean; Joides Resolution; Latitude of event; Leg121; Leg154; Leg165; Longitude of event; Ocean Drilling Program; ODP; Sample code/label; Size fraction; South Atlantic Ocean; δ11B, standard deviation  (1)
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  • 1
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 31 (2016): 626–638, doi:10.1002/2015PA002908.
    Description: Coral skeletons archive past climate variability with unrivaled temporal resolution. However, extraction of accurate temperature information from coral skeletons has been limited by “vital effects,” which confound, and sometimes override, the temperature dependence of geochemical proxies. We present a new approach to coral paleothermometry based on results of abiogenic precipitation experiments interpreted within a framework provided by a quantitative model of the coral biomineralization process. DeCarlo et al. (2015a) investigated temperature and carbonate chemistry controls on abiogenic partitioning of Sr/Ca and U/Ca between aragonite and seawater and modeled the sensitivity of skeletal composition to processes occurring at the site of calcification. The model predicts that temperature can be accurately reconstructed from coral skeleton by combining Sr/Ca and U/Ca ratios into a new proxy, which we refer to hereafter as the Sr-U thermometer. Here we test the model predictions with measured Sr/Ca and U/Ca ratios of 14 Porites sp. corals collected from the tropical Pacific Ocean and the Red Sea, with a subset also analyzed using the boron isotope (δ11B) pH proxy. Observed relationships among Sr/Ca, U/Ca, and δ11B agree with model predictions, indicating that the model accounts for the key features of the coral biomineralization process. By calibrating to instrumental temperature records, we show that Sr-U captures 93% of mean annual temperature variability (26–30°C) and has a standard deviation of prediction of 0.5°C, compared to 1°C using Sr/Ca alone. The Sr-U thermometer may offer significantly improved reliability for reconstructing past ocean temperatures from coral skeletons.
    Description: NSF Grant Numbers: OCE-1338320, OCE-1031971, OCE-1220529; NSF Graduate Research Fellowships
    Description: 2016-12-11
    Keywords: Coral ; Paleoclimate ; Sea surface temperature ; Geochemistry ; Biomineralization
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2022-05-26
    Description: © The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Proceedings of the National Academy of Sciences of the United States of America 114 (2017): 13114-13119, doi: 10.1073/pnas.1702143114.
    Description: During the Mid-Pleistocene Transition (MPT; 1,200–800 kya), Earth’s orbitally paced ice age cycles intensified, lengthened from ∼40,000 (∼40 ky) to ∼100 ky, and became distinctly asymmetrical. Testing hypotheses that implicate changing atmospheric CO2 levels as a driver of the MPT has proven difficult with available observations. Here, we use orbitally resolved, boron isotope CO2 data to show that the glacial to interglacial CO2 difference increased from ∼43 to ∼75 μatm across the MPT, mainly because of lower glacial CO2 levels. Through carbon cycle modeling, we attribute this decline primarily to the initiation of substantive dust-borne iron fertilization of the Southern Ocean during peak glacial stages. We also observe a twofold steepening of the relationship between sea level and CO2-related climate forcing that is suggestive of a change in the dynamics that govern ice sheet stability, such as that expected from the removal of subglacial regolith or interhemispheric ice sheet phase-locking. We argue that neither ice sheet dynamics nor CO2 change in isolation can explain the MPT. Instead, we infer that the MPT was initiated by a change in ice sheet dynamics and that longer and deeper post-MPT ice ages were sustained by carbon cycle feedbacks related to dust fertilization of the Southern Ocean as a consequence of larger ice sheets.
    Description: Research was supported by National Environmental Research Council (NERC) Studentship NE/I528626/1 (to T.B.C.); NERC Grant NE/P011381/1 (to T.B.C., M.P.H., G.L.F., E.J.R., and P.A.W.); NERC Fellowships NE/K00901X/1 (to M.P.H.), NE/I006346/1 (to G.L.F. and R.D.P), and NE/H006273/1 (to R.D.P.); Royal Society Wolfson Awards (to G.L.F. and P.A.W.); Australian Research Council Laureate Fellowship FL1201000050 (to E.J.R.); Swiss National Science Foundation Grant PP00P2-144811 (to S.L.J.); ETH Research Grant ETH-04 11-1 (to S.L.J.); European Research Council Consolidator Grant (ERC CoG) Grant 617462 (to H.P.); and NERC UK IODP Grant NE/F00141X/1 (to P.A.W.).
    Keywords: Boron isotopes ; MPT ; Geochemistry ; Carbon dioxide ; Paleoclimate
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Publication Date: 2024-01-09
    Keywords: 121-758B; 154-926A; 154-926B; 165-999A; AGE; Caribbean Sea; Cibicidoides mundulus, δ11B; Cibicidoides wuellerstorfi, δ11B; DRILL; Drilling/drill rig; Elevation of event; Event label; Globigerina praebulloides, Magnesium/Calcium ratio; Globigerina praebulloides, δ11B; Globigerinoides ruber, Magnesium/Calcium ratio; Globigerinoides ruber, δ11B; Globigerinoides trilobus, magnesium/calcium ratio; Globigerinoides trilobus, δ11B; Indian Ocean; Joides Resolution; Latitude of event; Leg121; Leg154; Leg165; Longitude of event; Ocean Drilling Program; ODP; Sample code/label; Size fraction; South Atlantic Ocean; δ11B, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 137 data points
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  • 4
    Publication Date: 2024-04-20
    Description: This dataset collection includes boron isotope, Mg/Ca, and Al/Ca data from planktonic foraminifera, reconstructed sea surface temperature, seawater pH and atmospheric CO2 concentrations, calculated Global Mean Temperature and Climate Sensitivity estimates, and recalculated seawater pH and atmospheric CO2 estimates from published planktonic foraminiferal boron isotope data.
    Keywords: Atmospheric CO2; climate sensitivity; Eocene; GMT; surface seawater pH
    Type: Dataset
    Format: application/zip, 3 datasets
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  • 5
    Publication Date: 2024-04-20
    Description: The dataset includes time series of global mean temperature for the Eocene, using a combination of sea surface temperature reconstructions and model derived estimates of global mean temperatures. These are coupled to the atmospheric CO2 reconstructions, translated into CO2 forcing relative to preindustrial, to calculate the evolving climate sensitivity for the Eocene. Both equilibrium climate sensitivity and earth system sensitivity are provided.
    Keywords: Atmospheric CO2; climate sensitivity; Eocene; GMT; surface seawater pH
    Type: Dataset
    Format: application/vnd.openxmlformats-officedocument.spreadsheetml.sheet, 377.2 kBytes
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  • 6
    Publication Date: 2024-04-20
    Description: In this dataset, we compile published records of seawater pH and atmospheric CO2 from foraminiferal δ11B are re-calculated using our current constrains and processing scenarios for the Eocene, for consistency to the new data. The re-calculation includes no vital effect treatment (for T. sac like species of planktonic foraminifera the offset in d11B at Eocene d11Bsw conditions is smaller than analytical uncertainty), no pH correction on Mg/Ca-temperature relationship (T. sac like species) and incorporating MyAMI for carbonate system calculations (https://github.com/MathisHain/MyAMI).
    Keywords: Atmospheric CO2; climate sensitivity; Eocene; GMT; surface seawater pH
    Type: Dataset
    Format: application/vnd.openxmlformats-officedocument.spreadsheetml.sheet, 209.6 kBytes
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