ALBERT

Description: We investigate the evolution of Cenozoic climate and ice volume as evidenced by the oxygen isotopic composition of seawater (delta18Osw) derived from benthic foraminiferal Mg/Ca ratios to constrain the temperature effect contained in foraminiferal delta18O values. We have constructed two benthic foraminiferal Mg/Ca records from intermediate water depth sites (Ocean Drilling Program sites 757 and 689 from the subtropical Indian Ocean and the Weddell Sea, respectively). Together with the previously published composite record of Lear et al. (2002, doi:10.1126/science.287.5451.269) and the Neogene record from the Southern Ocean of Billups and Schrag (2002, doi:10.1029/2000PA000567), we obtain three, almost complete representations of the delta18Osw for the past 52 Myr. We discuss the sensitivity of early Cenozoic Mg/Ca-derived paleotemperatures (and hence the delta18Osw) to assumptions about seawater Mg/Ca ratios. We find that during the middle Eocene (~ 49-40 Ma), modern seawater ratios yield Mg/Ca-derived temperatures that are in good agreement with the oxygen isotope paleothermometer assuming ice-free conditions. Intermediate waters cooled during the middle Eocene reaching minimum temperatures by 40 Ma. The corresponding delta18Osw reconstructions support ice growth on Antarctica beginning by at least 40 Ma. At the Eocene/Oligocene boundary, Mg/Ca ratios (and hence temperatures) from Weddell Sea site 689 display a well-defined maximum. We caution against a paleoclimatic significance of this result and put forth that the partitioning coefficient of Mg in benthic foraminifera may be sensitive to factors other than temperature. Throughout the remainder of the Cenozoic, the temporal variability among delta18Osw records is similar and similar to longer-term trends in the benthic foraminiferal delta18O record. An exception occurs during the Pliocene when delta18Osw minima in two of the three records suggest reductions in global ice volume that are not apparent in foraminiferal delta18O records, which provides a new perspective to the ongoing debate about the stability of the Antarctic ice sheet. Maximum delta18Osw values recorded during the Pleistocene at Southern Ocean site 747 agree well with values derived from the geochemistry of pore waters (Schrag et al., 1996, doi:10.1126/science.272.5270.1930) further highlighting the value of the new Mg/Ca calibrations of Martin et al. (2002, doi:10.1016/S0012-821X(02)00472-7) and Lear et al. (2002, doi:10.1016/S0016-7037(02)00941-9) applied in this study. We conclude that the application of foraminiferal Mg/Ca ratios allows a refined view of Cenozoic ice volume history despite uncertainties related to the geochemical cycling of Mg and Ca on long time scales.

Description: We present Globigerinoides ruber, G. sacculifer and Neogloboquadrina dutertrei oxygen isotope records from northwestern subtropical Atlantic Site 1058 spanning the mid Pleistocene (~600 to 400 ka). The high temporal resolution of these records (~800 yr) allows us to compare millennial-scale climate signals during one of the most extreme glacial periods of the Pleistocene (Marine Isotope Stage (MIS) 12) to an earlier, less extreme glacial (MIS 14), as well as to two full interglacial intervals (MIS 13 and MIS 15). We observe excellent agreement in the timing and amplitude of variations between the surface-most dwelling species G. ruber and Northern Hemisphere insolation during the two interglacial periods. There is some expression of Northern Hemisphere insolation during glacial MIS 14; however, during the more extreme glacial MIS 12 Northern Hemisphere insolation patterns are not apparent in any of the planktonic foraminiferal d18O records. Insolation remains relatively high, but d18O values increase toward the characteristic d18O maximum of MIS 12 in all three of the records. On the millennial-scale, all three species display their highest amplitude d18O variations (with a period between 4–6 kyr) during glacial MIS 12. Suborbital-scale variability is also statistically significant during glacial MIS 14, but the amplitude is smaller. These results support hypotheses linking millennial-scale climate fluctuations to the extent of continental glaciation. We propose that the relatively high degree of sea surface instability during one of the most extreme glacial periods of the Pleistocene arises from the competing effects of strong atmospheric winds related to the presence of a large ice sheet to the north and persistently high incident solar radiation during this interval of time.