ISSN:
0009-2940
Keywords:
1-Pyrrolecarbodithioate derivatives
;
Tin complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The 1-pyrrolecarbodithioate complexes of tin, PhSnCl(S2CNC4H4)2 (1) and Sn(S2CNC4H4)4 (2) have been synthesized and characterized by IR and NMR spectra (1H, 13C and 119Sn). δ119Sn suggests hexacoordination for 1 and an even higher coordination number for 2. X-ray structure determinations of these as well as of Me2Sn(S2CNC4H4)2 (3) have shown that 3 is one of the few known examples with a skew-trapezoidal bipyramidal configuration. 1 attains approximately a cis-octahedral geometry with two bidentate carbodithioate ligands with the Cl atom and the phenyl group in cis position. Complex 2 possesses two bidentate ligands while the other two are essentially anisobidentate leading to a structure between an octahedraon and a dodecahedron.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250702
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