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Synthesis, circular dichroism, and absolute stereochemistry of 1,1′:4′,1′-ternaphthalene compounds (1997)

Harada, Nobuyuki ; Hiyoshi, Norie ; Vassilev, Vassil P. ; [et al.]

New York, NY [u.a.] : Wiley-Blackwell

Chirality 9 (1997), S. 623-625

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ISSN: 0899-0042

Keywords: 1,1′:4′,1′-ternaphthalene ; enantioresolution ; chiral phthalic acid amide method ; circular dichroism ; absolute stereochemistry ; CD exciton chirality method ; Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Enantiopure 1,1′:4′,1′-ternaphthalene compounds were synthesized via enantioresolution of 1,1′:4′,1′-ternaphthalene-2,2′-dimethanol (2) by the chiral phthalic acid amide method. The CD spectra of chiral 1,1′:4′,1′-ternaphthalene compounds synthesized showed typical intense exciton split CD Cotton effects, from which the absolute stereochemistry of these 1,1′:4′,1′-ternaphthalene compounds was unambiguously determined by the CD exciton chirality method. Chirality 9:623-625, 1997. © 1997 Wiley-Liss, Inc.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

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