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  • 1
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    Regional variations in the chemical and helium–carbon isotope composition of geothermal fluids across Tunisia (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2021-06-25
    Description: Tunisia has numerous thermo-mineral springs. Previous studies have shown that their chemical composition and occurrence are strongly influenced by the regional geology. However little work has been done so far to study the isotopic composition of volatiles associated with these geothermal manifestations. Here, we report on the results of an extensive survey of both natural hot springs and production wells across Tunisia, aimed at investigating the spatial distribution of thermal fluids' geochemical characteristics and He–C isotopic composition. The chemistry of the analyzed samples highlights the heterogeneity of the water mineralization processes in Tunisia, as a consequence of the complex geological and tectonic setting of the country. In terms of chemical composition, we are able to conclude, however, that dissolution of halite and gypsum plays a key control on groundwater chemistry. Helium and carbon isotope systematics confirm the prevalently crustal origin of the volatiles interacting with the aquifer systems, consistent with the absence of any recent magmatism. Most samples are characterized by crustal-type helium (3He/4He in the range 0.02 Ra–0.4 Ra) associated with a CO2 predominantly metamorphic in origin (with the exception of the Saharan platform where the carbon content is low and mostly organically-derived). In Eastern Tunisia, however, a few samples have He–C isotope compositions which suggest (at least partial) mantle derivation of the dissolved gas phase : the 3He/4He ratio reaches 2.4 Ra (corresponding to 30% of mantle-derived helium) at the Ain Garci site, a CO2 rich mineral spring located some 30 km south of the city of Zaghouan. This mantle signature is consistent with the fact that the Pelagian Block, to which Eastern Tunisia belongs, has been deeply affected by extensional and transtensional tectonics since the opening of the Tethys, a process which is still ongoing in the Sicily channel (Pantelleria Rift). As a whole however, our results show that the Italian mantle gas anomaly only marginally extends to Northwestern Africa.
    Description: Published
    Description: 67-85
    Description: JCR Journal
    Description: restricted
    Keywords: regional variation ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Environmental impact of Mt. Etna’s degassing: volcanogenic trace elements bioaccumulation in two endemic plant species (Senecio aethnensis and Rumex aethnensis) (2010)
    Copernicus
    Details
    Publication Date: 2017-04-04
    Description: A biomonitoring survey, above tree line level, using two endemic species (Senecio aethnensis and Rumex aethnensis) was performed on Mt. Etna, in order to evaluate the dispersion and the impact of volcanic atmospheric emissions. Samples of leaves were collected in summer 2008 from 30 sites in the upper part of the volcano (1500- 3000 m a.s.l). Acid digestion of samples was carried out with a microwave oven, and 44 elements were analyzed by using plasma spectrometry (ICP-MS and ICP-OES). The highest concentrations of all investigated elements were found in the samples collected closest to the degassing craters, and in the downwind sector, confirming that the eastern flank of Mt. Etna is the most impacted by volcanic emissions. Leaves collected along two radial transects from the active vents on the eastern flank, highlight that the levels of metals decrease one or two orders of magnitude with increasing distance from the source. This variability is higher for volatile elements (As, Bi, Cd, Cs, Pb, Sb, Tl) than for more refractory elements (Al, Ba, Sc, Si, Sr, Th, U). The two different species of plants do not show significant differences in the bioaccumulation of most of the analyzed elements, except for lanthanides, which are systematically enriched in Rumex leaves. The high concentrations of many toxic elements in the leaves allow us to consider these plants as highly tolerant species to the volcanic emissions, and suitable for biomonitoring researches in the Mt. Etna area.
    Description: Published
    Description: Vienna, Austria
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Mt. Etna ; biomonitoring ; Trace elements ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 3
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    Rainwater-induced leaching of selenium, arsenic and vanadium from Etnean volcanic soils (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Active volcanoes emit considerable amounts of contaminants such as As, Se and V. Mount Etna is the biggest volcano of Europe and an excellent geochemical site to study water-soil processes. Due to its volcanic activity, the rainwater has a strong compositional gradient, both in time and space. At present, the behaviour of trace elements in the soils around Mt Etna is poorly understood. To determine the influence of the rainwater pH on the potential mobilization of geogenic pollutants, batch experiments have been performed with synthetic rainwater for 25 soils collected along the flanks of the volcano. Our results show that: i) The maximum concentrations in the leaching solutions are higher for acid rain than for neutral rain (e.g. 7.7 vs 1.3 mg/L for Se). ii) With neutral rain conditions the soils upwind from the volcano have higher concentrations of Se than those downwind (up to 1.3 mg/L compared to ≤0.3 mg/L for the other samples). This trend is less clear for As and V. iii) For soils collected from 2 to 10 km downwind of the craters, Se concentrations in acid rain leachates decrease one order of magnitude with increasing distance. A similar pattern is also observed upwind from the volcano. For As and V no clear relationship between concentrations and location with respect to the volcanic craters is observed. Both i) and ii) result in a low pH dependence for samples upwind from the volcano. The biggest difference between acid and neutral leaching for As and V is observed for a sample 2 km downwind from the craters. The observed patterns are influenced by potential controlling factors, such as organic matter content, total concentrations, mineralogy, influence of the volcanic plume, etc. Our results have implications for the chemical composition of the Etnean aquifer, the only water resource to the one million inhabitants around Mt Etna, as well as for the bioavailability and potential toxicity through agricultural activities, essential to the local economy.
    Description: Published
    Description: Davos, Switzerland
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: volcanic soils ; selenium ; arsenic ; vanadium ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 4
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    Geochemical comparison of natural and anthropogenic metal fluxes in extreme environments: Mt. Etna volcano (Italy) and Salek Valley (Slovenia) (2009)
    Geological Survey of Slovenia - Ljubljana
    Details
    Publication Date: 2017-04-04
    Description: Geochemical comparison between some metals (As, Cd, Cu, Pb, Se, V, Zn) emissions from an active volcano (Mt. Etna) and a highly industrialized area (Salek Valley) showed some interesting similarities: in general, most of the elements emitted into the atmosphere do not return to the Earth's surface and are therefore dispersed into the environment. Exceptions for Salek Valley are Cd, which probably derives in large part from rock leaching, and in part As and Pb, which fall mostly as ash. Also, Etna's emissions are richer in Cd and Cu, whereas industrial emissions at Salek Valley are richer in V and Zn. All other metals have similar fluxes in the two types of emissions.
    Description: Published
    Description: Ljubljana, Slovenia
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Trace metals ; Mt. Etna ; Salek Valley ; metals budget ; pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 5
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    Geogenic element behaviour in soil-rainwater interaction at Mt Etna, Sicily: preliminary results (2008)
    Details
    Publication Date: 2017-04-04
    Description: Active volcanoes emit considerable amounts of contaminants such as As, Se and V. Previous studies have shown that the volcanic activity at Mt Etna (Sicily) has a strong influence on local rainwater compositions. However to date, the behaviour of trace elements in the soils around Mt Etna is poorly understood. 4-hr batch experiments have been performed with 1:5 soil solutions of air-dried soil (fraction 〈2 mm) and synthetic (acid) rainwater (using either deionized water with a pH of ~6 or a ~500 ppm of sulphuric acid solution with a pH of ~2). In general trace element concentrations are more enriched in soil solutions with low pH (e.g. enrichment factor (EF) acid compared to neutral soil solution is up to 4.3x102 for V, 2.5x102 for As and 50 for Se). However, it seems that the EF especially for As and V has a correlation with the distance to the crater. Additional, some soils located downwind of the volcano have EFs smaller than 1 (i.e. the elements are more enriched in neutral rainwater), for several elements like V, As and Se. For As and V the EF seems to be vary with distance to the crater. Some possible explanations for these trends will be discussed. These results might have important implications for the chemical composition of the Etnean aquifer, the only water resource to the one million inhabitants around Mt Etna, as well as the bioavailability and therefore potential toxicity through agricultural activities, essential to the local economy.
    Description: Unpublished
    Description: Cluj-Napoca, Romania
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Mt. Etna ; soil chemistry ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 6
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    Volcanic signature of volatile trace elements on atmospheric deposition at Mt. Etna, Italy (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Volcanic volatiles and aerosol emitted into the atmosphere ultimately fall on the Earth’s surface as wet or dry deposition, and they can influence the environment and the ecosystems at local and regional scales. Therefore, atmospheric deposition plays a key-role in the geochemical cycles, redistributing volcanogenic elements to the ground. For this reason, estimating the volcanogenic trace element fluxes from the atmosphere to the surface is necessary for a better knowledge of the environmental impact of the volcanic emissions. Nevertheless, from a literature review, we have recognized the scarcity of investigation on trace element deposition in the surroundings of active volcanoes. Here, we present a chemical characterization of bulk deposition around Mt. Etna, Italy, including both major and many trace elements. Bulk depositions were collected approximately fortnightly, from April 2006 to December 2007, using a network of five rain gauges, located at various altitudes on the upper flanks around the summit craters of the volcano. For most elements highest concentrations have been found close to the emission vent, confirming the prevailing volcanic contribution to rainwater composition close to the summit craters. Comparison with contemporaneously collected plume emissions shows that deposition processes produce no evident element-to-element fractionation. By contrast, comparison with whole rock composition indicates a contrasting behaviour between volatile elements, which are highly-enriched in rainwater, and refractory elements, which have low rainwater/whole rock concentration ratios. Chemical concentrations in bulk deposition were used to estimate the deposition rates of a large suite of elements. Deposition rates for volatile trace elements like Se, As, and Cd range from 1.7, 1.2 and 0.9 µg m-2 day-1 nearby to the summit vents, to 0.5, 0.3, and 0.1 µg m-2 day-1 at the local background site on the upwind western sector.
    Description: Published
    Description: Davos, Switzerland
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: trace metals ; atmospheric deposition ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 7
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    First application of active biomonitoring techniques (moss-bags) to map the dispersion of volcanic emissions (2011)
    Geoitalia - Federazione Italiana di Scienze della Terra
    Details
    Publication Date: 2017-04-04
    Description: Biomonitoring may be defined as the use of organisms and biomaterials (biomonitors) to obtain informations on certain characteristics of a particular medium (atmosphere, hydrosphere etc.). In particular, mosses accumulate large amounts of trace metals, making them good bioaccumulators to estimate atmospheric pollution. The moss-bags technique, introduced in the early 1970’, has become very popular. Such active biomonitoring technique is particularly useful in highly polluted areas and has been extensively used in industrial and/or urban areas to examine deposition patterns and to recognize point sources of pollution. The main objective of this study, which represents the first application of the moss-bags technique in an active volcanic area, was to test its efficacy in such environment. Complementary objectives were: to determine the different behavior and the geographic dispersion of volcanogenic elements emitted from Mt. Etna; to check the usefulness of a simpler analytical techniques (leaching instead of mineralization of the moss samples). A mixture of Sphagnum species was picked in a clean area, treated in laboratory (washed, dried and packed) and exposed in field for 1 month. Sites were chosen considering the prevailing wind at Mt. Etna’s summit. Milled samples were analyses for major and trace elements concentrations, after microwave digestion (HNO3 + H2O2), by ICP-MS and ICP-OES techniques. The same elements were also analyzed after simple leaching with deionized water (1/50 weight ratio for 4 hours). Leaching solutions were also analyzed by IC for F, Cl and SO4. Analyses clearly showed the efficacy of the moss-bags technique also in this peculiar environment. Several elements were strongly enriched in the mosses exposed to the volcanic emissions. The highest enrichment was measured close to the summit crater, but evidences of metals bioaccumulation were also found in down wind sites, at several km from the volcanic source. The accumulation factor (exposed/unexposed moss) allowed us to distinguish a group of elements (Tl, Bi, Se, Cu, As, Cd, S), which are highly mobile in the high temperature volcanic environment. Also alkali metals showed a significant increase in their concentrations, probably because of their affinity for the halide species carried by the volcanic plume. Also the simple and cheap leaching technique gave important indications on the plume dispersion pattern, especially for highly volatile elements (F, Cl, S, Tl).
    Description: Published
    Description: Torino, Italia
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: biomonitoring ; moss-bags ; trace elements ; Etna ; Volcanic emissions ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 8
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    Chemical and mineralogical characterization of Etnean volcanic emissions using active biomonitoring technique (moss-bags) (2011)
    Digilabs Pub., Bari, Italy
    Details
    Publication Date: 2017-04-04
    Description: Biomonitoring may be defined as the use of organisms and biomaterials (biomonitors) to obtain informations on certain characteristics of a particular medium (atmosphere, hydrosphere etc.). In particular, mosses accumulate large amounts of trace metals, making them good bioaccumulators to estimate atmospheric pollution. The moss-bags technique, introduced in the early 1970’, has become very popular. Such active biomonitoring technique is particularly useful in highly polluted areas and has been extensively used in industrial and/or urban areas to examine deposition patterns and to recognize point sources of pollution. The main objective of this study, which represents the first application of the moss-bags technique in an active volcanic area, was to test its efficacy in such environment. Complementary objectives were: to determine the different behaviour and the areal dispersion of volcanogenic elements emitted from Mt. Etna; to characterize the morphology and mineralogy of particles transported in the plume-system, basing on microscopy investigation. A mixture of Sphagnum species was picked in a clean area, treated in laboratory (rinsed, dried and packed) and exposed in field for 1 month. Sites were chosen considering the prevailing wind at Mt. Etna’s summit. Milled samples were analyses for major and trace elements concentrations, after microwave digestion (HNO3 + H2O2), by ICP-MS and ICP-OES techniques. Morphology and mineralogy of volcanic particulate were investigated by using a SEM with EDS. Analyses clearly showed the efficacy of the moss-bags technique also in this peculiar environment. Several elements were strongly enriched in the mosses exposed to the volcanic emissions. The highest enrichment was measured close to the summit crater, but evidences of metals bioaccumulation were also found in down wind sites, at several km from the volcanic source. The accumulation factor (exposed/unexposed moss) allowed us to distinguish a group of elements (Tl, Bi, Se, Cu, As, Cd, S), which are highly mobile in the high temperature volcanic environment. Also alkali metals showed a significant increase in their concentrations, probably because of their affinity for the halide species carried by the volcanic plume. Microscopic observations evidenced sulphate and halide crystals on particles trapped by the mosses. Mosses exposed at sites directly fumigated by the volcanic plume showed crystal growth also directly on the moss surface.
    Description: Published
    Description: Bari, Italy
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: biomonitoring ; moss-bags ; trace elements ; Etna ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 9
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    Selenium mobilization in soils due to volcanic derived acid rain: An example from Mt Etna volcano, Sicily (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The significant amounts of selenium(Se)emitted by volcanoesmay have important impact on human health due to the narrow range between nutrition requirement and toxic effects for living organisms upon Se exposure. Although soils play a key role in determining the level in food and water and thereby human health, little is known about the behaviour of Se in volcanic soils. In this work we evaluated the Se release during rainwater–soil interaction under controlled conditions using soils collected on the flanks of Etna volcano and synthetic rain. Seleniumconcentrations in soil leachate solutions displayed a spatial distribution, which cannot be explained by plume deposition, total Se soil concentrations or the presence of Fe oxides. Instead, Al compounds and to a minor extent SOM were identified as the active phases controlling the selenate mobilization during interaction with sulphate-containing rainwater. This shows the importance of soils as reactive interfaces. Selenium is mobilized when volcanic-derived acid rain interacts with poorly developed soils close to the crater. This geogenic process might influence the chemical composition of groundwater and as a result, human health.
    Description: Published
    Description: 235–244
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: reserved
    Keywords: Selenium ; Volcanic soils ; Geogenic ; Volcanoes ; Contamination ; Groundwater ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
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    Atmospheric sources and sinks of volcanogenic elements in a basaltic volcano (Etna, Italy) (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This study reports on the first quantitative assessment of the geochemical cycling of volcanogenic elements, from their atmospheric release to their deposition back to the ground. Etna’s emissions and atmospheric depositions were characterised for more than 2 years, providing data on major and trace element abundance in both volcanic aerosols and bulk depositions. Volcanic aerosols were collected from 2004 to 2007, at the summit vents by conventional filtration techniques. Precipitation was collected, from 2006 to 2007, in five rain gauges, at various altitudes around the summit craters. Analytical results for volcanic aerosols showed that the dominant anions were S, Cl, and F, and that the most abundant metals were K, Ca, Mg, Al, Fe, and Ti (1.5–50 lg m 3). Minor and trace element concentrations ranged from about 0.001 to 1 lg m 3. From such analysis, we derived an aerosol mass flux ranging from 3000 to 8000 t a 1. Most analysed elements had higher concentrations close to the emission vent, confirming the prevailing volcanic contribution to bulk deposition. Calculated deposition rates were integrated over the whole Etna area, to provide a first estimate of the total deposition fluxes for several major and trace elements. These calculated deposition fluxes ranged from 20 to 80 t a 1 (Al, Fe, Si) to 0.01–0.1 t a 1 (Bi, Cs, Sc, Th, Tl, and U). Comparison between volcanic emissions and atmospheric deposition showed that the amount of trace elements scavenged from the plume in the surrounding of the volcano ranged from 0.1% to 1% for volatile elements such as As, Bi, Cd, Cs, Cu, Tl, and from 1% to 5% for refractory elements such as Al, Ba, Co, Fe, Ti, Th, U, and V. Consequently, more than 90% of volcanogenic trace elements were dispersed further away, and may cause a regional scale impact. Such a large difference between deposition and emission fluxes at Mt. Etna pointed to relatively high stability and long residence time of aerosols in the plume.
    Description: Published
    Description: 7401-7425
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: trace elements ; volcanic plume chemistry ; bulk deposition ; Etna ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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