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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 1415-1420 
    ISSN: 1434-1948
    Keywords: Combinatorial chemistry ; Molecular recognition ; Functionalized bipyridine metal complexes ; Janus molecules ; Hydrogen bonding ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The functionalized ligands 1 and 2 bearing hydrogen-bonding recognition groups have been synthesized. Their assembly by metal ions such as CuI and PdII having different coordination geometries generates different receptor architectures for the binding of suitable substrates. Addition of the complementary bis(imide) Janus molecules (4-7) to [1a, 2a, CuTf] or to [1b, 2b, Pd(BF4)2] mixtures leads to a moderate selective increase of the fraction of the [(1a)2Cu]+ or [(1b)2Pd]2+ complex depending on the Janus substrate used. Largest enhancements are observed for those Janus substrates that may be expected to display highest geometrical complementarity with the two complexes. These results represent a process directed by target binding based on dynamic combinatorial chemistry.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemistry - A European Journal 3 (1997), S. 99-104 
    ISSN: 0947-6539
    Keywords: bipyridines ; copper compounds ; selfassembly ; supramolecular chemistry ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The newly synthesised ligand 2 combines binding components known to undergo specific and distinct self-assembly processes with Cu1 ions. It complexes Cu1 to form, in almost quantitative yield, a large inorganic architecture 1 made up from four ligand molecules and twelve metal ions. The structure of 1 was ascertained by X-ray radiocrystallography as well as by NMR spectroscopy and electrospray mass spectrometry. It consists of a macrocycle of nanometric dimension with an external diameter of 28 Å; the central cavity has a diameter of 11 Å, which contains four PF-6 anions as well as solvent molecules. The spontaneous formation of 1 results from a self-assembly process based on a “program” combining two assembly subroutines, each specific to one of the ligand subunits. Self-assembly through double or, more generally, multiple subroutines can be used to generate a wide variety of highly complex inorganic supramolecular architectures by combination of two or more assembly processes.
    Additional Material: 5 Ill.
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  • 3
    ISSN: 0044-8249
    Keywords: Asymmetrische Synthesen ; Galliumverbindungen ; Helices ; Selbstorganisation ; Supramolekulare Chemie ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
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  • 4
    Publication Date: 2020-03-19
    Description: Ilopango caldera erupted episodically at least 13 tuff-forming eruptions with a minimum estimate volume of 1–5km3 DRE per eruption, reaching up to 150km3 DRE for the first caldera-forming eruption. All tuffs are of dacitic-rhyolitic composition. The complete pyroclastic sequence spans a range in time from 1.785 to 0.0015 Ma, and based on stratigraphy and geochronology constraints can be divided into three formations: the Comalapa, Altavista and Tierras Blancas formations. In this work, we focus on the members of the newly described Altavista Formation (middle part of Ilopango caldera volcanic sequence), which consist of six con- solidated pyroclastic deposits or tuffs. Each tuff corresponds to a specific eruption followed by a period of quiescence during which soil beds were developed on the deposits. The ages of the Altavista Formation ranges from 918 to 257ka, based on new 40Ar/39Ar, U/Pb-zircon, and U/Th-zircon analyses. The tuffs of this for- mation show similar characteristics in mineralogy and composition. They are calcalkaline, rhyodacitic tuffs, with plagioclase, clinopyroxene, and hornblende. From field mapping and descriptions of the deposits, we have inferred the eruptive styles that include pumice fallouts, pyroclastic density currents and also hydromag- matic explosions. The common vent in all tuffs was the Ilopango caldera and each member of the Altavista Formation could correspond to a caldera collapse event, except for one of the six eruptions. The volume of each member was estimated to be 〉30km3 DRE, which is the same order of magnitude than that estimated for the Tierra Blanca Joven (TBJ) eruption at about 1500 B. P, and smaller than those of the ignimbrites of the Comalapa Formation, the first three members of the Ilopango caldera reported previously. The tuffs of the Altavista Formation are visible up to 15–20 km away from the caldera's topographic margin. The recurrence interval of large explosive events at the Ilopango caldera was established by integrating the stratigraphic and geochronologic data of all 13 ignimbrites and pumice fallouts erupted from Ilopango caldera since the first one at 1.78 Ma to the last explosive event (TBJ).
    Description: Published
    Description: 100-119
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Keywords: Stratigraphy of volcanic deposits ; Ignimbrite ; Central America Volcanic Arc ; Pull-apart graben ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2019-02-25
    Description: The Ilopango caldera is located in the central part of El Salvador, within the right-lateral El Salvador Fault System (ESFZ) and adjacent to the capital city of San Salvador. The caldera has a polygonal shape of 17 × 13 km and hosts an intra-caldera lake. Ilopango caldera had multiple collapse eruptions that formed widespread and voluminous silicic ignimbrites. Volcanic activity of the caldera has been controlled by strike-slip faults of the ESFZ. In this work we present the geological characteristics of the first three ignimbrite-forming eruptions of Ilopango caldera, pro- viding an interpretation of the origin and initial stages of the volcanic evolution of this caldera complex. An initial extensional regime of the ESFZ possibly developed a graben at or near the actual Ilopango caldera, where the graben's master faults worked as fissure vents during the first caldera collapse. The Olocuilta Ignimbrite was emplaced at 1.785 ± 0.01 Ma BP, with a Dense Rock Equivalent (DRE) volume N 50 km3 (probably ~300 km3). The ESFZ stress gradually changed from extensive to transtensive, inducing the second collapse associated with a pull-apart caldera, producing the Colima Ignimbrite at 1.56 ± 0.01 Ma BP, with a DRE volume of N11 km3. The transtensive regime increased along the ESFZ, producing the third collapse in the pull-apart graben caldera apparently affected by the newly formed strike-slip San Vicente Fault. This phase corresponds to the ex- plosive eruption that formed the Apopa Ignimbrite at ~1.34 Ma BP, with N9 km3 DRE volume. The latter ignim- brite marks a change in the eruptive style producing hydromagmatic pyroclastic flows followed by a dense ignimbrite with coignimbrite lithic breccias. These features suggest the involvement of water that could come from a paleoIlopango lake within the caldera depression associated with the second caldera collapse at 1.56 Ma BP. Ilopango is thus a multistage caldera system associated with the largest explosive events registered in El Salvador so far.
    Description: Published
    Description: 1-19
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Keywords: Central America Volcanic Arc ; Tecton Fault ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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