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  • 1
    Publication Date: 2021-07-19
    Description: The Comoros archipelago is an active geodynamic region of intra-plate volcanism within which the youngest and oldest islands (Grande Comore and Mayotte respectively) are characterized by recent volcanic activity. The frequent eruptions of the large shield volcano Karthala on Grande Comore (last eruption 2007), and the recent birth of a large submarine volcano since 2018 at the submarine base of Mayotte are associated with permanent fumarolic emissions, bubbling gas seeps, and soil gas emissions, which are studied in detail here for the first time. CO2 fluxes and chemical and isotopic gas compositions acquired during two surveys in 2017 and 2020 are integrated with older datasets collected between 2005 and 2016, permitting the identification of a possible influence of the recent volcanic and magmatic activity at Mayotte. At Karthala, high gas fluxes with high temperature, and a marked magmatic signature are concentrated close to the summit crater area, while only weaker emissions with a stronger biogenic signature are found on the volcano flanks. At Mayotte, lower temperature and higher CH4 content are recorded in two main seep areas of CO2-rich fluid bubbling, while soil emissions on land record a higher proportion of magmatic fluids compared to Karthala. Our preliminary results reveal two quite separate gas emission patterns for each island that are distinct in composition and isotopic signatures, and well-correlated with the present state of volcanic activity. This work may potentially provide support for local observation infrastructures and contribute to the improvement in volcanic and environmental monitoring.
    Description: INGV (GECO project Fondi Ricerca libera 2019 INGV) and REVOSIMA Initiative (IPGP, CNRS, BRGM, IFREMER)
    Description: Submitted
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Keywords: •Geochemical characterisation of fumarolic and hydrothermal gases in terms of both primary component species and isotopic characteristics ; 04.08. Volcanology ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: report
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  • 2
    Publication Date: 2021-02-03
    Description: Gases present in the Earth crust are important in various branches of human activities. Hydrocarbons are a significant energy resource, helium is applied in many high-tech instruments, and studies of crustal gas dynamics provide insight in the geodynamic processes and help monitor seismic and volcanic hazards. Quantitative analysis of methane and CO2 migration is important for climate change studies. Some of them are toxic (H2S, CO2, CO); radon is responsible for the major part of human radiation dose. The development of analytical techniques in gas geochemistry creates opportunities of applying this science in numerous fields. Noble gases, hydrocarbons, CO2, N2, H2, CO, and Hg vapor are measured by advanced methods in various environments and matrices including fluid inclusions. Following the “Geochemical Applications of Noble Gases”(2009), “Frontiers in Gas Geochemistry” (2013), and “Progress in the Application of Gas Geochemistry to Geothermal, Tectonic and Magmatic Studies” (2017) published as special issues of Chemical Geology and “Gas geochemistry: From conventional to unconventional domains” (2018) published as a special issue of Marine and Petroleum Geology, this volume continues the tradition of publishing papers reflecting the diversity in scope and application of gas geochemistry.
    Description: Published
    Description: 976190
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: geochemistry ; Atmosphere ; 03. Hydrosphere ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2020-01-13
    Description: The understanding of the relationship between the geochemistry of fluids circulating during travertine deposition and the presence of active faults is crucial for evaluating the seismogenetic potential of an area. Here we investigate travertines from Pamukkale and Reşadiye (Turkey), sited in seismic regions and next to thermal springs. These travertines formed ~24,500–50,000 (Pamukkale) and ~240–14,600 years (Reşadiye) BP. We characterize fluid inclusions (FIs) and studied concentration of H2O, CO2, O2 + N2, and 3He, 4He, 20Ne, and 40Ar, and bulk composition (trace elements and δ13C‐δ18O). FIs from both localities are mainly primary with low salinity and homogenization temperature around 136–140 °C. H2O is the major component followed by CO2, with the highest gas content measured in Pamukkale travertines. Concentrations of Ne‐Ar together with O2 + N2 indicate that travertines from both areas precipitated from atmosphere‐derived fluids. The 3He/4He is 0.5–1.3 Ra in Pamukkale and 0.9–4.4 Ra in Reşadiye. Samples with R/Ra 〉 1 are modified by cosmogenic 3He addition during exposure to cosmic rays. Excluding these data, FIs of Reşadiye are mostly atmosphere‐derived. This implies a shallow formation where the circulation was dominated by meteoric waters, which is consistent with their young age. Instead, FIs of Pamukkale show mixing of mantle‐, crustal‐, and atmosphere‐derived He, indicating that these travertines formed in lithospheric fractures. Based on the δ13CCO2 and δ18O of bulk rocks, we infer that travertines formed involving crustal‐ (mechanochemical rather than organic) and mantle‐derived CO2. Trace elements of Pamukkale and Reşadiye show comparable rare earth element patterns. We conclude that travertines formed in response of seismogenetic activity.
    Description: Published
    Description: 5473-5498
    Description: 2T. Deformazione crostale attiva
    Description: 7T. Variazioni delle caratteristiche crostali e precursori sismici
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: travertine ; fluid inclusions ; noble gas ; Pamukkale ; Reşadiye ; seismogenetic activity ; geochemistry ; d13C and d18O ; Sold Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2019-03-26
    Description: Knowledge of the products originating from the subcontinental lithospheric mantle (SCLM) is crucial for constraining the geochemical features and evolution of the mantle. This study investigated the chemistry and isotope composition (noble gases and CO2) of fluid inclusions (FI) from selected mantle xenoliths originating from Wilcza Góra (Lower Silesia, southwest Poland), with the aim of integrating their petrography and mineral chemistry. Mantle xenoliths are mostly harzburgites and sometimes bear amphiboles, and are brought to the surface by intraplate alkaline basalts that erupted outside the north-easternmost part of the Eger (Ohˇre) Rift in Lower Silesia. Olivine (Ol) is classified into two groups based on its forsterite content: (1) Fo88.9−91.5, which accounts for a fertile-to-residual mantle, and (2) Fo85.5−88.1, which indicates large interactions with circulating (basic) melts. This dichotomy is also related to orthopyroxene (Opx) and clinopyroxene (Cpx), which show two ranges of Mg# values (87–90 and 91–93, respectively) and clear evidence of recrystallization. CO2 predominates within FI, followed by N2. The d13C of mantle CO2 varies between −4.7‰and −3.1‰, which mostly spans theMORB range (−8‰〈 d13C 〈 −4‰). The 3He/4He ratio is 6.7–6.9 Ra in Cpx, 6.3–6.8 Ra in Opx, and 5.9–6.2 Ra in Ol. These values are within the range proposed for European SCLM (6.3±0.3 Ra). The decrease in 3He/4He from Cpx to Ol is decoupled from the He concentration, and excludes any diffusive fractionation from FI. The chemistry of FI entrapped in Ol indicates that the mantle is depleted by variable extents of partial melting, while that of Opx and Cpx suggests the overprinting of at least one metasomatic event. According to Matusiak-Małek et al. (2017), Cpx, Opx, and amphiboles were added to the original harzburgite by carbonated hydrous silicate melt related to Cenozoic volcanism. This process resulted in entrapment of CO2-rich inclusions whose chemical and isotope composition resembles that of metasomatizing fluids. We argue that FI data reflect a mixing between two endmembers: (1) the residual mantle, resulting from partial melting of European SCLM, and (2) the metasomatic agent, which is strongly He-depleted and characterized by MORB-like features.
    Description: Published
    Description: Article 215
    Description: 1T. Struttura della Terra
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Keywords: European lithospheric mantle ; noble gases ; CO2 ; fluid inclusions ; metasomatism ; SCLM ; MORB ; mineral chemistry ; olivine ; orthopyroxene ; clinopyroxene ; Lower Silesia ; Eger Rift ; mantle xenoliths ; d13C ; partial melting
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2019-03-26
    Description: We investigated the geochemical features of the gases released from the Kizildag ophiolitic complex (Hatay, Turkey). Twenty-three samples both dissolved in hyperalkaline waters and free gases (bubbling gases and dry seeps) were collected. Samples were analysed for their chemical (He, H2, O2, N2, CH4 and CO2) and isotopic (He, d13C-CH4, d2H-CH4, d2H-H2) composition including the content and C-isotopic composition of C2 to C5 alkanes in free gases. Analytical results evidence H2 production through low temperature (〈80 C) serpentinization processes and subsequent abiogenic CH4 production through Fischer-Tropsch-type reactions. In some sample small additions of methane either of microbial or of thermogenic origin can be hypothesized. At one of the sites (Kisecik) a clear fractionation pattern due to microbial methane oxidation leading to strongly enriched isotopic values (d13C þ15‰ and d2H 68‰) and depletion in methane concentrations has been evidenced. At the dry gas seep of Kurtbagi methane flux measurements have been made and a preliminary output estimation of about 1000 kg per year has been obtained.
    Description: Published
    Description: 174-184
    Description: 7T. Variazioni delle caratteristiche crostali e precursori sismici
    Description: JCR Journal
    Keywords: Gas geochemistry ; Serpentinization ; Hydrogen ; Abiogenic methane ; Stable isotopes ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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