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  • UV Camera  (3)
  • 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics  (1)
  • Boat conformation
  • Collagen biosynthesis
  • 1
    ISSN: 0378-1119
    Keywords: Collagen biosynthesis ; fibrosis
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of computer aided molecular design 5 (1991), S. 357-370 
    ISSN: 1573-4951
    Keywords: MNDO ; Molecular modeling ; Superimposition ; Boat conformation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The active conformation of several histamine H1-antagonists is investigated. As a template molecule we used the antagonist cyproheptadine, which consists of a piperidylene ring connected to a tricyclic system. The piperidylene moiety is shown to be flexible. The global minimum is a chair conformation but, additionally, a second chair and various boat conformations have to be considered, as their energies are less than 5 kcal/mol above the energy of the global minimum. Two semi-rigid histamine H1-antagonists, phenindamine and triprolidine, were fitted onto the various conformations of cyproheptadine in order to derive the pharmacologically active conformation of cyproheptadine. At the same time, the active conformation of both phenindamine and triprolidine was derived. It is demonstrated that, within the receptor-bound conformation of cyproheptadine, the piperidylene ring most probably exists in a boat form.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2019-01-24
    Description: The advent of UV cameras has recently paved the way to volcanic SO2 flux observations of much improved temporal and spatial resolution, and has thus contributed to expanding use and utility of SO2 fluxes in volcano monitoring. Recently, the first examples of permanent UV camera systems have appeared that are now opening the way to routine fully automated monitoring of the volcanic SO2 flux at high-rate, and continuously (daily hours only). In 2014, using funding from the FP7-ERC project “Bridge” (http://www.bridge.unipa.it/), we deployed a network of 4 permanent UV cameras at Etna and Stromboli volcanoes (Sicily) that has been operating regularly since then. Using a suite of custom-built codes, data streamed by the UV camera are automatically processed and telemetered, allowing nearly real-time visualization and analysis of SO2 fluxes. Here, we summarise the key results obtained during the last 5 years of continuous observations (2014-2018) to demonstrate potentials and challenges in real-time continuous SO2 flux monitoring with UV cameras. We show that the spatially resolved SO2 flux time-series delivered by the UV camera allow effectively tracking migration in volcanic activity from the Central to New South-East Crater (Etna), and shifts in degassing activity along the crater terrace (Stromboli). At both volcanoes, the high temporal of UV cameras allows capturing the escalation in active (strombolian) SO2 degassing that typically precedes onset of paroxysmal (Etna in 2014-2016) or effusive (Stromboli in 2014) activity, and to quantify for the first time the syn- explosive SO2 budget for larger-scale explosions, including 2 paroxysmal lava fountains (Etna) and 1 major explosion (Stromboli). We finally demonstrate the ability of our automatic camera systems to capture temporal changes in SO2 flux regime, and thus to “live” monitoring degassing and eruptive behaviors at active volcanoes.
    Description: Published
    Description: Napoli
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Keywords: UV Camera ; SO2 Flux Monitoring ; Etna ; Stromboli
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 4
    Publication Date: 2022-08-25
    Description: We examine the tectonic evolution and structural characteristics of the Quaternary intermontane Mugello, Casentino, and Sansepolcro basins, in the Northern Apennines fold-andthrust belt. These basins have been classically interpreted to have developed under an extensional regime, and to mark the extension-compression transition. The results of our study have instead allowed framing the formation of these basins into a compressive setting tied to the activity of backthrust faults at their northeastern margin. Syndepositional activity of these structures is manifested by consistent architecture of sediments and outcrop-scale deformation. After this phase, the Mugello and Sansepolcro basins experienced a phase of normal faulting extending from the middle Pleistocene until Present. Basin evolution can be thus basically framed into a two-phase history, with extensional tectonics superposed onto compressional structures. Analysis of morphologic features has revealed the occurrence of fresh fault scarps and interaction of faulting with drainage systems, which have been interpreted as evidence for potential ongoing activity of normal faults. Extensional tectonics is also manifested by recent seismicity, and likely caused the strong historical earthquakes affecting the Mugello and Sansepolcro basins. Qualitative comparison of surface information with depth-converted seismic data suggests the basins to represent discrete subsiding areas within the seismic belt extending along the axial zone of the Apennines. The inferred chronology of deformation and the timing of activity of normal faults have an obvious impact on the elaboration of seismic hazard models.
    Description: Published
    Description: 336-356
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Description: open
    Keywords: Northern Apennines ; Basin evolution ; structural analysis ; active tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2022-05-06
    Description: We used a one-year long SO2 flux record, which was obtained using a novel algorithm for real-time automatic processing of ultraviolet (UV) camera data, to characterize changes in degassing dynamics at the Mt. Etna volcano in 2016. These SO2 flux records, when combined with independent thermal and seismic evidence, allowed for capturing switches in activity from paroxysmal explosive eruptions to quiescent degassing. We found SO2 fluxes 1.5–2 times higher than the 2016 average (1588 tons/day) during the Etna’s May 16–25 eruptive paroxysmal activity, and mild but detectable SO2 flux increases more than one month before its onset. The SO2 flux typically peaked during a lava fountain. Here, the average SO2 degassing rate was ~158 kg/s, the peak emission was ~260 kg/s, and the total released SO2 mass was ~1700 tons (in 3 hours on 18 May, 2016). Comparison between our data and prior (2014–2015) results revealed systematic SO2 emission patterns prior to, during, and after an Etna’s paroxysmal phases, which allows us to tentatively identify thresholds between pre-eruptive, syn-eruptive, and post-eruptive degassing regimes.
    Description: Published
    Description: id 1201
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: SO2 fluxes ; UV Camera ; Etna Volcano ; explosive basaltic volcanism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2024-01-25
    Description: The persistent open-vent degassing of Mt. Etna is often punctuated by monthslong paroxysmal sequences characterized by episodes of violent Strombolian to lava fountaining activity. Understanding these gas-fueled transitions from quiescence to eruption requires routine measurement of gas fluxes. Here, we report SO2 flux measurements, obtained from a permanent UV camera system, collected over a two-year-long period spanning two paroxysmal sequences of Etna’s New South East Crater (NSEC) in December 2020/April 2021 and May/ October 2021. In both cases, SO2 flux increased from ≤ 3250 Mg/day during “ordinary” activity to ≥ 4200 Mg/day. We interpret these distinct SO2 degassing regimes in light of seismic and thermal observations and drawing on numerical simulations of sulfur degassing constrained by parental melt sulfur contents in Etna’s hawaiites. We find that initiation of a paroxysmal sequence results from an approximate doubling of the time-averaged rate of magma supply (and degassing) above the sulfur exsolution level (~150 MPa pressure), to 〉4m3/s. This corroborates recent models that argue for the triggering of paroxysmal sequences by escalating supply of volatile-rich magma to a reservoir ~3–4 km below the summit region. The non-stationary nature of magma flow and volcanic degassing we identify highlights the need for sustained surveillance to characterize long-term atmospheric budgets of volcanic volatiles
    Description: Published
    Description: 1115111
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: Etna, ; volcanic gases ; SO2 flux ; paroxysms ; UV Camera ; basaltic explosive volcanism ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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