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  • 04.08. Volcanology  (2)
  • SO2  (2)
  • 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics  (1)
  • Boat conformation
  • Church of England, Sermons.
  • Collagen biosynthesis
  • 1
    ISSN: 0378-1119
    Keywords: Collagen biosynthesis ; fibrosis
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of computer aided molecular design 5 (1991), S. 357-370 
    ISSN: 1573-4951
    Keywords: MNDO ; Molecular modeling ; Superimposition ; Boat conformation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The active conformation of several histamine H1-antagonists is investigated. As a template molecule we used the antagonist cyproheptadine, which consists of a piperidylene ring connected to a tricyclic system. The piperidylene moiety is shown to be flexible. The global minimum is a chair conformation but, additionally, a second chair and various boat conformations have to be considered, as their energies are less than 5 kcal/mol above the energy of the global minimum. Two semi-rigid histamine H1-antagonists, phenindamine and triprolidine, were fitted onto the various conformations of cyproheptadine in order to derive the pharmacologically active conformation of cyproheptadine. At the same time, the active conformation of both phenindamine and triprolidine was derived. It is demonstrated that, within the receptor-bound conformation of cyproheptadine, the piperidylene ring most probably exists in a boat form.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2019-03-01
    Description: Understanding the trigger mechanisms of phreatic eruptions is key to mitigating the effects of these hazardous but poorly forecastable volcanic events. It has recently been established that high-rate volcanic gas observations are potentially very suitable to identifying the source processes driving phreatic eruptions, and to eventually detecting precursory changes prior to individual phreatic blasts. In February-May 2017, we deployed a Multi-GAS instrument to continuously monitor gas concentrations in the crater lake plume of Rincón de la Vieja, a remote and poorly monitored active volcano in Costa Rica, site of frequent phreatic/phreatomagmatic eruptions. Forty-two phreatic/phreatomagmatic eruptions were seismically recorded during our investigated period, 9 of which were also recorded for gas by the Multi-GAS. To the best of our knowledge, these represent the first instrumentally measured gas compositions during individual phreatic/phreatomagmatic explosions at an active volcano. Our results show that during background quiescent degassing the Rincón de la Vieja crater lake plume was characterized by high CO2/SO2 ratios of 64 ± 59 and H2S/SO2 ratios of 0.57 ± 0.20. This composition is interpreted as reflecting hydrothermal (re)processing of magma-sourced gas in the sub-limnic environment. Phreatic blasts were recorded by the Multi-GAS as brief (1–2 min long) pulses of elevated gas mixing ratios (up to ~52 ppmv SO2 and 〉3,000 ppmv CO2), or more than an order of magnitude higher than during background degassing (~1 ppmv SO2 and ~450 ppmv CO2). During the phreatic eruption(s), the H2S/SO2 ratio was systematically lower (〈0.18) than during background degassing, but the CO2/SO2 ratio remained high (and variable), ranging from 37 to 390. These S-poor compositions for the eruptive gas imply extensive processing of the source magmatic gas during pre-eruptive hydrothermal storage, likely by deposition of native S and/or sulfate. Our gas results are thus overall consistent with a mechanism of phreatic eruptions triggered by accumulation of magmatic-hydrothermal gases beneath a hydrothermal seal. We claim that real-time Multi-GAS monitoring is urgently needed at other crater lake-hosting volcanoes (e.g., Ruapehu, Aso), where phreatic eruptions may similarly be preceded by phases of reduced S degassing at the surface.
    Description: Published
    Description: Article 247
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: JCR Journal
    Keywords: volcanic gases ; crater lakes ; rincon de la vieja ; multi-GAS ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2021-12-23
    Description: At open-vent basaltic volcanoes, resolving the activity escalation that heralds larger, potentially harmful eruptions is challenged by the persistent mild ordinary activity, which often masks the precursory unrest signals related to heightened magma transport from depth. Gas (SO2 and CO2) fluxes at surface are controlled by rate of magma transport and degassing within the magma plumbing system, and thus constitute key parameters to infer deep magma budget and dynamics. Here, we use several year-long (2014-present) gas observations at Etna and Stromboli volcanoes, in Sicily, to provide new evidence for the utility of long-term instrumental gas monitoring in real-time detecting the early phase of unrest prior eruption, and for characterizing syn-eruptive dynamics. To this aim, we use information from a gas monitoring network of permanent ultraviolet (UV) cameras and automatic Multi-Gas instruments that, combined with geophysical observations, allow characterizing changes in degassing and eruptive dynamics at high temporal/spatial resolution. Our results show that the paroxysmal (lava fountaining) explosions that periodically interrupted persistent open-vent activity on Etna (during 2014-2020) were accompanied by systematic, repetitive SO2 emission patterns prior, during, and after eruptions. These allow us identifying the characteristic pre- syn- and post- eruptive degassing regimes, and to establish thresholds in the SO2 flux record that mark phases of unrest. On Stromboli, the much improved temporal/spatial resolution of UV cameras allows resolving the escalation of regular strombolian activity, and its concentration toward its North-east crater, that heralds onset of effusive eruptions. During effusive eruption, although magma level drops in the conduit and explosive summit activity ceases, UV camera observations can still detect explosive gas bursts deep in the conduit while no infrasonic activity is detected. Combining the UV camera-derived SO2 fluxes with CO2/SO2 ratio records measured by the Multi-Gas, the CO2 flux can be inferred. We find that such CO2 flux time-series can allow tracking degassing of deeply stored mafic magma months before Stromboli"s eruptions. We finally show that remotely sensed gas emission and thermal activity can be combined together to characterize the dynamics of shallow magmatic system prior to and during unrest, ultimately helping to define timing of magma re-charging events driving the eruptions.
    Description: Published
    Description: Virtual
    Description: 4V. Processi pre-eruttivi
    Description: 5V. Processi eruttivi e post-eruttivi
    Keywords: Open vent volcanism ; SO2 ; UV cameras
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 5
    Publication Date: 2022-08-25
    Description: We examine the tectonic evolution and structural characteristics of the Quaternary intermontane Mugello, Casentino, and Sansepolcro basins, in the Northern Apennines fold-andthrust belt. These basins have been classically interpreted to have developed under an extensional regime, and to mark the extension-compression transition. The results of our study have instead allowed framing the formation of these basins into a compressive setting tied to the activity of backthrust faults at their northeastern margin. Syndepositional activity of these structures is manifested by consistent architecture of sediments and outcrop-scale deformation. After this phase, the Mugello and Sansepolcro basins experienced a phase of normal faulting extending from the middle Pleistocene until Present. Basin evolution can be thus basically framed into a two-phase history, with extensional tectonics superposed onto compressional structures. Analysis of morphologic features has revealed the occurrence of fresh fault scarps and interaction of faulting with drainage systems, which have been interpreted as evidence for potential ongoing activity of normal faults. Extensional tectonics is also manifested by recent seismicity, and likely caused the strong historical earthquakes affecting the Mugello and Sansepolcro basins. Qualitative comparison of surface information with depth-converted seismic data suggests the basins to represent discrete subsiding areas within the seismic belt extending along the axial zone of the Apennines. The inferred chronology of deformation and the timing of activity of normal faults have an obvious impact on the elaboration of seismic hazard models.
    Description: Published
    Description: 336-356
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Description: open
    Keywords: Northern Apennines ; Basin evolution ; structural analysis ; active tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2024-01-26
    Description: We used two and a half years long SO2 flux record, obtained using permanent ultraviolet cameras, to characterize changes in degassing dynamics at Mt. Etna volcano from summer 2014 to the end of 2016. Volcanic activity at Mt. Etna was characterized by persistent open-vent degassing periodically interrupted by intense paroxysmal lava fountaining events (in August 2014, December 2015, and May 2016). Results revealed systematic SO2 emission patterns prior, during, and after Etna’s paroxysmal phases, allowing us to identify thresholds between pre-syn-and post-eruptive degassing regimes. The SO2 flux typically peaked during a lava fountain: in the 18 May 2016 example, the averaged SO2 degassing rate was ~158 kg/s, the peak emission was ~260 kg/s, and the total released SO2 mass was ~1700 tons (in 3h). Paroxysmal explosive activity at NSE crater on 11-15 August 2014 was also associated with intense syneruptive SO2 degassing (at 30-40 kg/s levels on a daily average), and was preceded by onset in degassing activity at the same crater 4 days before. During paroxysmal activity on 3-5 December 2015, the SO2 fluxes peaked at 54-103 kg/s from VOR crater, and was preceded by a sizable increase from 10 kg/s (end of November) up to 45.5 kg/s, two days before. The May 16-25 2016 paroxysmal activity was characterized by intense degassing ~2 times higher than the 2016 average (~18 kg/s) and preceded by mild but detectable SO2 flux increases more than one month before its onset. Taken together, our observations, when combined with independent geophysical (thermal and seismic) evidence, allow us to fully characterize the Etna’s degassing dynamics and contribute to our understanding of its shallow plumbing system.
    Description: Published
    Description: Catania
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Keywords: SO2 ; Mt. Etna volcano ; permanent ultraviolet cameras
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Abstract
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  • 7
    Publication Date: 2024-01-25
    Description: The persistent open-vent degassing of Mt. Etna is often punctuated by monthslong paroxysmal sequences characterized by episodes of violent Strombolian to lava fountaining activity. Understanding these gas-fueled transitions from quiescence to eruption requires routine measurement of gas fluxes. Here, we report SO2 flux measurements, obtained from a permanent UV camera system, collected over a two-year-long period spanning two paroxysmal sequences of Etna’s New South East Crater (NSEC) in December 2020/April 2021 and May/ October 2021. In both cases, SO2 flux increased from ≤ 3250 Mg/day during “ordinary” activity to ≥ 4200 Mg/day. We interpret these distinct SO2 degassing regimes in light of seismic and thermal observations and drawing on numerical simulations of sulfur degassing constrained by parental melt sulfur contents in Etna’s hawaiites. We find that initiation of a paroxysmal sequence results from an approximate doubling of the time-averaged rate of magma supply (and degassing) above the sulfur exsolution level (~150 MPa pressure), to 〉4m3/s. This corroborates recent models that argue for the triggering of paroxysmal sequences by escalating supply of volatile-rich magma to a reservoir ~3–4 km below the summit region. The non-stationary nature of magma flow and volcanic degassing we identify highlights the need for sustained surveillance to characterize long-term atmospheric budgets of volcanic volatiles
    Description: Published
    Description: 1115111
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: Etna, ; volcanic gases ; SO2 flux ; paroxysms ; UV Camera ; basaltic explosive volcanism ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Unknown
    Grand Rapids, Mich : Christian Classics Ethereal Library
    Keywords: Church of England, Sermons. ; Sermons, English.
    ISBN: 0-585-07463-1
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