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  • 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy  (2)
  • Amino acid sequence  (1)
  • Antirrhinoside  (1)
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  • 1
    Publication Date: 2021-07-14
    Description: The 91.15 m thick St. Thomas section belongs to the Middle Globigerina Limestone, which is the intermediate member of the Globigerina Limestone Formation, and crops out along the eastern cliff of the Delimara Peninsula (the south-eastern part ofMalta Island). The sedimentary record is composed of alternating calcareous marls and marly limestones with subordinated prominent bioturbated indurated limestones that are deposited in a pelagic environment. For the first time paleomagnetic analyses of a Burdigalian succession have provided reliable data that allow the identification of five magnetozones that have been correlated to the Astronomically Tuned Neogene Time Scale, spanning the Early Miocene C6n–C5Dn interval. Calcareous plankton quantitative analyses integrated with paleomagnetic analyses, allowed us to identify and date several bioevents that have great potential for Mediterranean and extra-Mediterranean correlations in the interval between ~19.7 and ~17.2 Ma. In particular, the complete distributional range of the calcareous nannofossil Sphenolithus belemnos has been recorded as follows: the First Occurrence (FO) at 19.12 Ma, the First Common Occurrence (FCO) at 19.05 Ma, the Last Common Occurrence (LCO) at 18.44 Ma, and the Last Occurrence (LO) at 18.02 Ma. In addition, the FO and the FCO of Sphenolithus heteromorphus have been documented at 18.29 Ma and at 17.99 Ma, respectively. A new paracme interval in the lower part of the range of this species is described between 17.56 and 17.31 Ma. Concerning the planktonic Foraminifera, the main bioevents are the Common Interval top of Paragloborotalia siakensis at 19.55 Ma, a Common Interval of Globoquadrina dehiscens between 19.34 and 18.48 Ma, the Globigerinoides subquadratus FO at 18.43 Ma, and the onset of an acme interval of Paragloborotalia acrostoma that changes its coiling from random to prevalently sinistral at the same time, at 18.40 Ma. These new biostratigraphic data allowed us to place the succession in the standard Mediterranean calcareous plankton zonal schemes and to make some amendments to these schemes. The FCO of S. belemnos was revealed a more reliable marker than its FO for the base of the MNN3a Zone.With regard to the planktonic Foraminifera, the P. acrostoma AB-r/s has been used as a subzonal marker of the G. dehiscens/Catapsydrax dissimilis Zone, which now comprises three subzones instead of two. The deep marine paleoenvironmental setting, the excellent outcrops and the recognition of a continuous succession of bio-magnetostratigraphic events suggest that the St. Thomas section should be considered as a reference section for the lower Burdigalian of theMediterranean area and for future studies in the definition of the Burdigalian GSSP.
    Description: Published
    Description: 66-89
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Description: restricted
    Keywords: Mediterranean; Early Miocene; Calcareous nannofossils; Planktonic Foraminifera; Magnetostratigraphy ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-09-08
    Description: Results of high-resolution integrated stratigraphic studies (calcareous plankton and magnetostratigraphy) of three Mediterranean sections (La Vedova in Central Italy, Contrada Pesciarello in Sicily and St. Peter’s Pool in Malta) and one deep-sea core from the mid-latitude North Atlantic (DSDP Hole 608) are here synthesized. They are compared with those of previously studied deep marine sections in the Mediterranean including the historical stratotype, with the aim to select the most suitable section and criterion to define the Langhian GSSP (Global Stratotype Section and Point). This study significantly improves the existing magnetobiostratigraphic framework for the upper Burdigalian-lower Langhian and opens new perspectives for defining the Langhian GSSP. An extensive review of the first stages of the Globigerinoides-Praeorbulina evolutionary lineage pointed out that the Praeorbulina datum, historically used (and/or suggested) to approximate the base of the Langhian, coincides with the First Occurrence (FO) of P. glomerosa curva instead of P. sicana which is here included in the genus Globigerinoides. The FO of P. glomerosa curva occurs close to the C5Br/C5Bn.2n reversal boundary. As a consequence, the two recommended guiding criteria to recognize the base of the Langhian, i.e. the Praeorbulina datum and the top of Chron C5Cn.1n, can not be applied together, as these two events differ in age by ~740 kyr. The selection of either of these two criteria will imply a different duration for the Langhian: relatively short, in case the FO of P. glomerosa curva is selected, or longer and probably more acceptable, in case the top of Chron C5Cn.1n is selected. The primary calcareous plankton biohorizons which, according to our data, appoximate the top of Chron C5Cn.1n, are the Last Common Occurrence (LCO) of the calcareous nannofossil Helicosphaera ampliaperta and the LCO of the planktonic foraminifer Paragloborotalia bella. Other calcareous plankton events have been recorded close to the same magnetic reversal, such as a short influx of H. ampliaperta (Ia1) and the Paragloborotalia siakensis Acme0. The P. siakensis Acmea End (AaE) and the Sphenolithus heteromorphus Paracme End (PE) represent the primary plankton biohorizons associated with the P. glomerosa curva FO. Two of the three studied Mediterranean sections (La Vedova and St. Peter’s Pool), each from different point of view, are potentially suitable to be proposed as candidates for the definition of the Langhian GSSP. Yet, further studies on stable isotope stratigraphy and cyclostratigraphy, including astronomical tuning are necessary before the most suitable section and guiding criterion can be selected.
    Description: Published
    Description: xxx-xxx
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: calcareus plankton stratigraphy ; magnetostratigraphy ; Langhian GSSP ; Mediterranean ; mid-latitude North Atlantic Ocean ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Biochimica et Biophysica Acta (BBA)/Protein Structure and Molecular 869 (1986), S. 147-157 
    ISSN: 0167-4838
    Keywords: (Porcine pancreas) ; Amino acid sequence ; Disulfide bond ; α-Amylase
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Medicine
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2931-2935 
    ISSN: 1434-193X
    Keywords: Nucleosides ; Natural products ; Iridoids ; Catalpol ; Antirrhinoside ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two iridoid glucosides, antirrhinoside (1) and catalpol (2), were converted into selectively protected polysubstituted cyclopentylmethanols, which were subsequently used to prepare carbocyclic homo-N-nucleosides (5, 6 and 14). A purine moiety was introduced either by the Mitsunobu reaction or by substitution of a primary triflate with the tetrabutylammonium salt of 6-iodopurine. The latter method was superior with regard to both ease of purification and yield. The N-9 vs. N-7 regioselectivity of the salts of different 6-substituted purine derivatives was briefly investigated.
    Type of Medium: Electronic Resource
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