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  • 1
    ISSN: 1432-0819
    Keywords: Magma chambers ; Isotope geochemistry ; Fluid inclusions ; Geochemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The magmatic system feeding the last eruption of the volcano La Fossa, Vulcano Island, Italy was studied. The petrogenetic mechanisms controlling the differentiation of erupted rocks were investigated through petrography, mineral chemistry, major, trace and rare earth element and Sr, Nd and Pb isotopic geochemistry. In addition, melt inclusion and fluid inclusion data were collected on both juvenile material and xenolithic partially melted metamorphic clasts to quantify the P-T conditions of the magma chamber feeding the eruption. A regular and continuous chemical zoning has been highlighted: rhyolites are the first erupted products, followed by trachytes and latites, whereas rhyolitic compositions were also found in the upper part of the sequence. The chemical and isotopic composition of the rhyolites indicates that they originated by fractional crystallization from latitic magmas plus the assimilation of crustal material; the trachytes represent hybrid magmas resulting from the mixing of latites and rhyolites, contaminated in the shallow magmatic system. The erupted products, primarily compositionally zoned from latites to rhyolites, are heterogeneous due to syn-eruptive mingling. The occurrence of magmacrust interaction processes, evidenced by isotopic variations (87Sr/86Sr=0.70474±3 to 0.70511±3; 143Nd/144Nd=0.512550±6 to 0.512614±8; 206Pb/204Pb=19.318–19.489; 207Pb/204Pb=15.642–15.782; 208Pb/204Pb=39.175–39.613), is confirmed by the presence of partially melted metamorphic xenoliths, with 87Sr/86Sr=0.71633±6 to 0.72505±2 and 143Nd/144Nd=0.51229±7, in rhyolites and trachytes. AFC calculations indicate a few percentage contribution of crustal material to the differentiating magmas. Thermometric measurements on melt inclusions indicate that the crystallization temperatures of the latites and trachytes were in the range of 1050–1100° C, whereas the temperature of the rhyolites appears to have been around 1000°C at the time of the eruption. Compositional data on melt inclusions reveal that the magmas involved in the eruption contained about 1–1.5 wt.% dissolved H2O in pre-eruptive conditions. Secondary fluid inclusions found in metamorphic xenoliths give low equilibration pressure data (30–60 MPa), giving the location of the higher portions of the chamber at around 1500–2000 m of depth.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2021-06-03
    Description: This work presents the results of a mineralogical and isotopic (18O, 13C, 87Sr/86Sr) study on xenoliths ejected during the famous 79AD Plinian eruption of Vesuvius. They are considered to be representative of the upper parts of the crystallizing margins of the magma chamber and also of the associated skarn shell. The aim of this study is to describe the thermometamorphic and metasomatic processes which took place at the 79AD magma chamber/wall-rock interface. The results of our research indicate that metasomatism of carbonate wall rocks of the 79AD Vesuvius magma chamber took place due to the infiltration of magmatic fluids, which were exsolved from the peripheral parts of the magma chamber itself. These fluids drive Fe, K, Si, Al and trace elements such as REE, Nb, U, Th, Zr, W, Sb, Pb extracted from the magma into the carbonate host-rocks, thus producing exoskarn. No evidence of later re-equilibrium with low temperature external fluids of meteoric origin was observed. This indicates that only the prograde early stage of skarn formation is recorded in these xenoliths.
    Description: Published
    Description: 1-10
    Description: partially_open
    Keywords: cognate xenoliths ; skarn ; magma chamber ; O, C and Sr isotopes ; Vesuvius ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 461 bytes
    Format: 1045000 bytes
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    Format: application/pdf
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