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  • 1
    Publication Date: 2021-03-23
    Description: Detailed soil-gas surveys have been conducted at two mine districts to better comprehend gas migration mechanisms from deposits buried at different depths. The Tolfa (Lazio, Central Italy) and Neves-Corvo (Baixo Alentejo, Portugal) mine districts have different characteristics: the former is superficial (30-100 m) while the latter is located at a depth of 400-500 m and covered by low-permeability metamorphic rocks. The soil-gas results from these two different investigated areas provide interesting results related to the study of far- and near-field gas migration mechanisms. In particular, the anomalous concentrations of sulphur compounds (COS, CS2 e SO2), CO2, and Rn confirmed the presence of the two ore deposits. Furthermore, radon was found to be sensitive to soil permeability variations and to be associated with migration pathways (faults and/or fractures). Overall the results indicate the potential for using the studied gas species as indicators of deep seated ore deposits (i.e. in the Neves-Corvo mine district), even at locations where there is thick overburden and no surface evidence.
    Description: Submitted
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: open
    Keywords: soil-gas, mining exploration, gas migration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: manuscript
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  • 2
    Publication Date: 2021-05-12
    Description: Detailed soil gas surveyswere conducted at twomine districts to understand gas migrationmechanisms fromdeposits buried at different depths. The Tolfa (Lazio, Central Italy) and Neves-Corvo (Baixo Alentejo, Portugal) mine districts have different characteristics: the former is relatively shallow (30–100 m) whereas the latter is at a depth of 400–500 m and covered by low-permeability metamorphic rocks. The studied gases included major (N2, O2, CO2) and trace (4He, 222Rn) gases, hydrocarbons (CH4, C2H6 and C3H8) and S compounds (H2S, COS, SO2). The measured concentrations (some examples of max values at Tolfa: Rn 233 Bq/L, CO2 9.5%, CH4 12.3 ppm, COS 3.7 ppm; and at Neves-Corvo: Rn 130 Bq/L, CO2 24.3%, CH4 0.1%) indicate that gases migrate preferentially through zones of brittle deformation by advective processes, as suggested by the relatively high rate of migration needed to obtain anomalies of short-lived 222Rn in the soil pores. Considering the different depths of the two ore deposits, obtained results can be considered as features of near-field (Tolfa) and far-field (Neves- Corvo) gas migration.
    Description: Published
    Description: 37-53
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: JCR Journal
    Description: restricted
    Keywords: Soil gas migration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2021-06-09
    Description: The chemistry and isotope ratios of He, C (d13C) and H (dD) of free gases collected in the San Vittorino plain, an intramontane depression of tectonic origin, were determined to shed light on mantle degassing in central Italy. The C isotopic composition of CO2 (d13C–CO2 2.0‰to 3.8‰) and He isotope ratios (R/RA 0.12–0.27) were used to calculate the fraction of CO2 originating from mantle degassing vs. sedimentary sources. The results show that CO2 predominantly (average of 75%) derives from the thermo-metamorphic reaction of limestone. Between 6% and 22% of the CO2 in the samples derives from organic-rich sedimentary sources. The mantle source accounts for 0–6% of the total CO2; however, in two samples, located in proximity to the most important faults of the plain, the mantle accounts for 24% and 42%. The presence of faults and fractures allows upward gas migration from a deep source to the Earth’s surface, not only in the peri-Tyrrhenian sector, as generally reported by studies on natural gas emissions in central Italy, but also in the pre-Apennine and Apennine belts. Isotope ratios of CH4 (d13C–CH4 6.1‰ to 22.7‰; dD–CH4 9‰ to 129‰) show that CH4 does not appear to be related to mantle or magma degassing, but it is the product of thermal degradation of organic matter (i.e. thermogenic origin) and/or the reduction of CO2 (i.e. geothermal origin). Most of the samples appear to be affected by secondary microbial oxidation processes.
    Description: Published
    Description: 90.101
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: JCR Journal
    Description: restricted
    Keywords: stable isotope ; noble gases ; carbon dioxide ; methane ; San Vittorino Plain ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2017-04-04
    Description: Seven 222Rn soil gas surveys have been accomplished throughout the N-E area of Stromboli Island. The former survey has been performed in July 2001, in a quiescent period since 1985, throughout a grid of 50 sites. The same grid has been repeated, in January 2003, soon after December, 28, 2002 eruption onset. The other surveys have been carried out in March 2003, in June 2003 after the April, 5, 2003 paroxysm event, and in July 2004 and March 2005 (quiescent periods). Finally, CO2 fluxes and soil gas surveys (Rn, CO2, CH4, H2, O2, N2, He) have been performed in March 2007 after the slightly February 2007 eruption onset. Results have highlighted correlated and synchronous 222Rn soil gas changes throughout the grid, allowing to discriminate the sectors of maximum increased 222Rn emission at surface, with a volcano-tectonical significance, mostly in January and March 2003 surveys. The positive NE-SW anomalies have been found maximum up to 13.000 Bq/m3 in January 2003, while after the Rn values returned to pre-eruptive values. Plotting single point concentration versus monitoring time, it is well evident that, in proximity of a paroxysm event, always the same points undergo to a radon concentration increasing. Data set of the investigated area has been divided in eight zones (on the basis of geographic sectors of the island). In every zone maximum Rn values correspond to the paroxysmal phase of the Stromboli eruptions. In particular, highest radon values are found in the “Lampara – COA” and “Town Hall” zones located along the known N40° lineament. After the eruptive phase, concentrations start to decrease. The NW-SE extension could be linked to the ongoing volcano collapse toward the NW located Sciara del Fuoco slope. Also the SE sector could undergo to collapses, along weakness lines (faults and fractures) whose prolongation in the Mole-S14 zone could release anomalous CO2-fluxes and anomalous soil gas concentrations (up to 10-20 % in CO2) dangerous for human health. The importance of geochemical monitoring together with volcanic time series, is a valid tool for evaluating the volcanic hazard.
    Description: Unpublished
    Description: Reykjavík - ICELAND
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: soil gas surveys, radon, stromboli ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 5
    Publication Date: 2017-04-04
    Description: Geological sequestration of anthropogenic CO2 appears to be a promising method for reducing the amount of greenhouse gases released to the atmosphere. Geochemical modelling of the storage capacity for CO2 in saline aquifers, sandstones and/or carbonates should be based on natural analogues both in situ and in the laboratory. The main focus of this paper has been to study natural gas emissions representing extremely attractive surrogates for the study and prediction of the possible consequences of leakage from geological sequestration sites of anthropogenic CO2 (i.e., the return to surface, potentially causing localised environmental problems). These include a comparison among 3 different Italian case histories: i) the Solfatara crater (Phlegraean Fields caldera, southern Italy) is an ancient Roman spa. The area is characterized by intense and diffuse hydrothermal activity, testified by hot acidic mud pools, thermal springs and a large fumarolic field.. Soil gas flux measurements show that the entire area discharges between 1200 and 1500 tons of CO2 a day; ii) the Panarea island (Aeolian islands, southern Italy) where a huge submarine volcanic-hydrothermal gas burst occurred in November, 2002. The submarine gas emissions chemically modified seawater causing a strong modification of the marine ecosystem. All of the collected gases are CO2-dominant (maximum value: 98.43 vol. %); iii) the Tor Caldara area (Central Italy), located in a peripheral sector of the quiescent Alban Hills volcano, along the faults of the Ardea Basin transfer structure. The area is characterized by huge CO2 degassing both from water and soil. Although the above mentioned areas do not represent a storage scenario, these sites do provide many opportunities to study near-surface processes and to test monitoring methodologies.
    Description: Published
    Description: 1339-1346
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: gas emission ; natural analogue ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2017-04-04
    Description: Geochemical studies were conducted throughout soil gas and flux surveying for locating both permeable zones in buried reservoirs and the presence of possible gaseous haloes linked to active geothermal systems. In this work we focused our interest on the distribution of soil gas concentrations (Rn, Th, He, H2, O2, N2, CO2, CH4 and H2S) in the soil air of the Tetitlan area considered a potential thermal field and characterized by scarcity of surface manifestations. Radon is used as a tracer gas to provide a qualitative idea of gas transfer (velocity and flux), carbon dioxide and methane are believed to act as carriers for other gases (i.e., Rn and He), helium and hydrogen are used as shallow signals of crustal leaks along faults (Ciotoli et al., 2005). Methane is also considered both a characteristic biogenic indicator of organic matter deposits and a tracer of major crustal discontinuity. A total of 154 soil gas samples were collected in an area of about 80 square kilometres. The same area was investigated throughout a total of 346 of CO2 and CH4 flux measurements.
    Description: UNAM
    Description: Unpublished
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: soil-gas ; geothermal field ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: report
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  • 7
    Publication Date: 2017-04-04
    Description: The physical properties of clay allow to consider argillaceous formations as geological barriers to radionuclide migration in high-level radioactive-waste isolation systems. As laboratory simulations are short term and numerical models always involve assumptions and simplifications of the natural system, natural analogues are extremely attractive surrogates for the study of long-term isolation. The thermally altered clays of the Orciatico area (Tuscany, Central Italy) represent an interesting natural model of a heat source which acted on argillaceous materials. The study of this natural analogue was performed through detailed geoelectrical and soil-gas surveys in order to define both the geometry of the intrusive body and the gas permeability of a clay unit characterized by different thermal alteration degrees. In particular, soil-gas radon and carbon dioxide distributions highlighted that the clay sequences, in spite of their thickness and plasticity, if fractured and metamorphosed, form a lesser impermeable barrier for naturally migrating gas.
    Description: European Commission
    Description: Unpublished
    Description: Luxembourg
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: radionuclide migration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 8
    Publication Date: 2017-04-03
    Description: Geochemical studies were conducted using soil-gas and flux surveyings for locating both permeable zones in buried reservoirs and the presence of possible gaseous haloes linked to active geothermal systems. In this work we focused our interest on the distribution of soil-gas concentrations (Rn, Th, He, H2, O2, N2, CO2, CH4 and H2S) in the soil air of the Tetitlan area (Nayarit, Mexico) considered a potential thermal field and characterized by scarcity of surface manifestations. A total of 154 soil-gas samples and 346 CO2 and CH4 flux measurements were collected in an area of about 80 square kilometres. The performed soil-gas and flux geochemical surveys highlighted a general rising patterns linked to local fault system, with the important implication that the highest CO2 and CH4 fluxes, as well as Rn concentrations, could be used in undeveloped geothermal systems to identify main upflow regions and areas of increased and deep permeability.
    Description: Unpublished
    Description: Bali, Indonesia
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: geothermal exploration ; soil-gas ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Extended abstract
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  • 9
    Publication Date: 2017-04-04
    Description: The physical properties of clay allow to consider argillaceous formations as geological barriers to radionuclide migration in high-level radioactive-waste isolation systems. As laboratory simulations are short term and numerical models always involve assumptions and simplifications of the natural system, natural analogues are extremely attractive surrogates for the study of long-term isolation. The thermally altered clays of the Orciatico area (Tuscany, Central Italy) represent an interesting natural model of a heat source which acted on argillaceous materials. The study of this natural analogue was performed through detailed geoelectrical and soil-gas surveys in order to define both the geometry of the intrusive body and the gas permeability of a clay unit characterized by different thermal alteration degrees. In particular, soil-gas radon and carbon dioxide distributions highlighted that the clay sequences, in spite of their thickness and plasticity, if fractured and metamorphosed, form a lesser impermeable barrier for naturally migrating gas.
    Description: Submitted
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: open
    Keywords: gas migration ; gas permeability ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: manuscript
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  • 10
    Publication Date: 2017-04-04
    Description: Two Italian areas, characterized by different seismological histories, were investigated in order to enhance the basic knowledge of gas migration mechanisms along fracture and fault surfaces during earthquakes. Sharp variations occur in the movement and concentration of some gaseous species due to the evolution of the local stress regime. The first area (named Colpasquale) is located in the central Italian region of Marche and provided a good location to study gas migration in a seismically active region. The area was devastated by a sequence of shallow earthquakes over a three month-long period (September-December, 1997). The occurrence of this catastrophic event as well as the long duration of the "seismic sequence", presented a unique opportunity to apply a study of gas migration to a zone undergoing active displacement. Soil-gas surveys were performed one day, one week, one year and two years after the main shock (Ms 5.6) in the Colpasquale area. In particular, results highlighted a change of the radon distribution during the three monitoring years indicating a variation of gas migration that may be linked to the evolution of the stress regime. The second study area is located in the Campidano Graben (southern part of Sardinia Island). This area is characterized by seismic quiescence, displaying an almost complete lack of historical earthquakes and instrumentally recorded seismicity. The consistently low values observed for all analysed gases suggest that the studied area is characterised by self-sealing probably non-active faults that prevent significant gas channelling. The comparison of data from both studied areas indicate that soil-gas geochemistry is useful to locate tectonic discontinuities even when they intersect non-cohesive clastic rocks (unconsolidated sediments) near the surface and thus are not visible (e.g. “blind faults”).
    Description: Submitted
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: open
    Keywords: seismotectonic investigations ; soil-gas migration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: manuscript
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