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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 7 (1993), S. 789-794 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The 70 eV electron ionization mass spectrometric behaviour of some C6F13-compounds has been studied in detail by means of mass-analyzed ion kinetic energy spectroscopy and compared with that of the C6H13-analogs. As a general trend, the incorporation of fluorine leads to a strengthening of the alkyl chain; in fact the extensive primary fragmentation processes related to the chain cleavages observed for hydrocarbon derivatives are strongly suppressed in the case of the corresponding fluorocarbons. Moreover, the interaction of fluorine with functional groups leads to unexpected decomposition processes. The —CH2—CF2— bond, often considered in condensed-phase chemistry as a weak point in the molecule, never undergoes fragmentation.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 9 (1995), S. 57-60 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The mass spectrometric behaviour of 2-fluoro, 2-chloro, 2-bromo and 2-iodo ethanols has been studied in detail with the aid of metastable ion studies and deuterium labelling experiments. Clear differences are observed and rationalized in terms both of carbon-halogen bond strengths and electronegativity.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 8 (1994), S. 89-93 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The kinetics of the unimolecular dissociations of proton-bound dimers produced by fast-atom bombardment from nucleosides and reference amines enables the evaluation of the proton affinities (PA) of ribonucleosides. The PAs of cytosine, guanosine, adenosine, uridine and deoxyuridine have been thus determined. These values and those already available for the corresponding DNA homologues allow the evaluation of the effect of the hydroxyl group in position 2′ of the sugar moiety, which lowers the PAs of RNA nucleosides by 0.6-1 kcal/mol, and of the methyl group in position 5 of the thymine ring which enhances the basicity of deoxythymidine over deoxyuridine by 0.6 kcal/mol.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 7 (1993), S. 1012-1016 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Nine Semifluorinated alkanes, F(CF2)n(CH2)mH, were analysed by electron ionization and electron-capture mass spectrometry. Both techniques showed the presence of H…F bridges between the zigzag hydrocarbon chain and the twisted fluorocarbon one. In particular, this interaction can explain the extensive sequential HF losses detected in electron-capture mass spectrometry. The low abundance of fragments corresponding to cleavage of a CF2-CH2 bond indicate a relatively high bond strength.
    Additional Material: 3 Ill.
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  • 5
    ISSN: 1076-5174
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: N-Alkyl-N-tosyl amino acid esters were ionized by fast atom bombardment (FAB) in a nitrobenzyl alcohol matrix through oxidative processes leading to molecular radical cations (M+·). The addition to the matrix of Cu11 salts induces the ionization through proton attachment whereby [M + H]+ are exclusively displayed by the positive-ion FAB spectra. The formation of electron donor-acceptor complexes between the analytes and the matrix lowers the critical energy for the ionization by one-electron removal from the substrates.
    Additional Material: 2 Ill.
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  • 6
    Publication Date: 2020-11-26
    Description: The complexity of volcano-hosted hydrothermal systems is such that thorough characterization requires extensive and interdisciplinary work. We use here an integrated multidisciplinary approach, combining geological investigations with hydrogeochemical and soil degassing prospecting, and resistivity surveys, to provide a comprehensive characterization of the shallow structure of the southwestern Ischia's hydrothermal system. We show that the investigated area is characterized by a structural setting that, although very complex, can be schematized in three sectors, namely, the extra caldera sector (ECS), caldera floor sector (CFS), and resurgent caldera sector (RCS). This contrasted structural setting governs fluid circulation. Geochemical prospecting shows, in fact, that the caldera floor sector, a structural and topographic low, is the area where CO2-rich (〉40 cm3/l) hydrothermally mature (log Mg/Na ratios 〈 −3) waters, of prevalently meteoric origin (δ18O 〈 −5.5‰), preferentially flow and accumulate. This pervasive hydrothermal circulation within the caldera floor sector, being also the source of significant CO2 soil degassing (〉150 g m−2 d−1), is clearly captured by electrical resistivity tomography (ERT) and transient electromagnetic (TEM) surveys as a highly conductive (resistivity 〈 3 Ω·m) layer from depths of ~100 m, and therefore within the Mount Epomeo Green Tuff (MEGT) formation. Our observations indicate, instead, that less-thermalized fluids prevail in the extra caldera and resurgent caldera sectors, where highly conductive seawater-like (total dissolved solid, TDS 〉 10,000 mg/l) and poorly conductive meteoric-derived (TDS 〈 4,000 mg/l) waters are observed, respectively. We finally integrate our observations to build a general model for fluid circulation in the shallowest (〈0.5 km) part of Ischia's hydrothermal system.
    Description: Published
    Description: Q07017
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: ERT ; TEM ; Ischia ; fluid geochemistry ; hydrothermal systems ; resurgent caldera ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.05. Models and Forecasts ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2017-04-04
    Description: The intricate pathways of fluid–mineral reactions occurring underneath active hydrothermal systems are explored in this study by applying reaction path modelling to the Ischia case study. Ischia Island, in Southern Italy, hosts a well-developed and structurally complex hydrothermal system which, because of its heterogeneity in chemical and physical properties, is an ideal test sites for evaluating potentialities/limitations of quantitative geochemical models of hydrothermal reactions. We used the EQ3/6 software package, version 7.2b, to model reaction of infiltrating waters (mixtures of meteoric water and seawater in variable proportions) with Ischia’s reservoir rocks (the Mount Epomeo Green Tuff units; MEGT). The mineral assemblage and composition of such MEGT units were initially characterised by ad hoc designed optical microscopy and electron microprobe analysis, showing that phenocrysts (dominantly alkali–feldspars and plagioclase) are set in a pervasively altered (with abundant clay minerals and zeolites) groundmass. Reaction of infiltrating waters with MEGT minerals was simulated over a range of realistic (for Ischia) temperatures (95–260 C) and CO2 fugacities (10 0.2 to 100.5) bar. During the model runs, a set of secondary minerals (selected based on independent information from alteration minerals’ studies) was allowed to precipitate from model solutions, when saturation was achieved. The compositional evolution of model solutions obtained in the 95– 260 C runs were finally compared with compositions of Ischia’s thermal groundwaters, demonstrating an overall agreement. Our simulations, in particular, well reproduce the Mg-depleting maturation path of hydrothermal solutions, and have end-ofrun model solutions whose Na–K–Mg compositions well reflect attainment of full-equilibrium conditions at run temperature. High-temperature (180–260 C) model runs are those best matching the Na–K–Mg compositions of Ischia’s most chemically mature water samples, supporting quenching of deep-reservoir conditions for these surface manifestations; whilst Fe, SiO2 and, to a lesser extent, SO4 contents of natural samples are better reproduced in low-temperature (95 C) runs, suggesting that these species reflect conditions of water–rock interaction in the shallow hydrothermal environment. The ability of model runs to reproduce the compositional features of Ischia’s thermal manifestations, demonstrated here, adds supplementary confidence on reaction path modelling as a realistic and insightful representation of mineral–fluid hydrothermal reactions. Our results, in particular, demonstrate the significant impact of host rock minerals’ assemblage in governing the paths and trends of hydrothermal fluids’ maturation.
    Description: Published
    Description: 108-129
    Description: JCR Journal
    Description: restricted
    Keywords: Ischia ; Hydrothermal systems ; EQ3-6 ; Geochemical modelling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2017-04-04
    Description: The paper proposes a method to evaluate the potential for electric power production at any site of possible geothermal interest. Accounting for geological data of the reservoirs, the method allows the computation of the available electrical power of the investigated site. Electrical energy production from geothermal sources is realized through different techniques, such as single flash and double flash, dry steam, and binary ORC plants. The technique chosen to be the most productive is determined by analyzing a specific range of geofluid properties, mainly temperature and pressure. Moreover, each plant typology has a global efficiency that may be correlated to geofluid enthalpy by empiric relations available in literature. The proposed evaluation method brings together all these correlations, yielding the power availability from a geosource, once its temperature and pressure are known. The method takes as input the geofluid available flow rate, its pressure, temperature and non-condensable gas content. It defines the best plant option from these parameters, calculates its global efficiency and finally returns the actual available power. For sites of geothermic interest, such as the volcanic island of Ischia in Southern Italy, the results of the application of this new method clearly highlight the most suitable zones for power plants installations.
    Description: Published
    Description: 303-312
    Description: 4V. Vulcani e ambiente
    Description: 5A. Energia e georisorse
    Description: JCR Journal
    Description: restricted
    Keywords: Geothermal power plants Geothermal exergy Ischia volcanic island ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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