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  • 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics  (4)
  • 1
    Publication Date: 2017-04-04
    Description: Ischia volcano, in Central Italy, has long been known for its copious surface hydrothermal manifestations, signs of a pervasive circulation of hot fluids in the subsurface. Because of the significant chemical heterogeneity of fumarolic gas discharges and hot spring discharges, evidences of a complex hydrothermal setting, a definite model of fluid circulation at depth is currently unavailable, in spite of the several previous efforts. Here, we report on the chemical and isotopic composition of 120 groundwater samples, collected during several sampling surveys from 2002 to 2007. The acquired data suggest that the composition of surface manifestations reflect contributions from meteoric water, sea water, and thermal fluids rising from two distinct hydrothermal reservoir, with equilibrium temperatures of respectively ~150 °C and ~270 °C, and depths of 150–300 m and N300 m (but possibly N1000 m). We also make use of an isotopic characterization of the dissolved gas phase in thermal waters to demonstrate that the Ischia hydrothermal system is currently supplied by a deep-rising gas component (DGC), characterized by CO2 ~97.7±1.2 vol.% (on a water-free basis), δ13CCO2=−3.51±0.9‰, and helium isotopic ratio of about 3.5 Ra (3He/4He ratio normalized to the air ratio, Ra), likely magmatic in origin. An assessment of the thermal budget for Ischia hydrothermal system is also presented, in the attempt to derive a first estimate of the size and rate of degassing of the magmatic reservoir feeding the gas emissions. We calculate that a heat flow of about 153–222 MW presently drives hydrothermal circulation on the island, which we suggest is supplied in convective form (e.g., by the ascent of a high-T magmatic vapour phase) by complete degassing of 2.2–3.3 107 m3 yr−1 of trachytic magma (with ~2.1 wt.% dissolved H2O content). If extrapolated to entire period of quiescence lasting since the Arso eruption in 1302 A.D., this volume corresponds to 1.6–2.3 1010 m3 of magma degassed in about 700 years of quiescent activity.
    Description: Published
    Description: 133–159
    Description: JCR Journal
    Description: reserved
    Keywords: Ischia ; hydrothermal systems ; thermal groudwaters ; thermal and volatile budget ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Oxygen isotopes of both rainwater and groundwater samples from Mt Etna were used to obtain information on recharge areas, flow paths, and the origin of wet air masses. Oxygen isotope composition was determined in rainwater samples collected for a period of 3 years (October 1997–October 2000), in 11 rain-gauges distributed along the flanks of Mt Etna from sea level to 2900 m of altitude. Values ranged from 213.8 to þ 1.9‰, the lowest values being measured at higher altitudes and/or during cooler periods. For rain-gauges located from sea level up to 1000 m altitude, volume weighted values defined an isotopic gradient of 22.7‰/km, which is in the range observed in the Mediterranean area. Higher-altitude gauges yielded a much lower gradient (20.6‰/km), probably due to the fact that vapour condensing at higher altitudes was mixed with an 18O-rich volcanic component deriving from the huge vapour output of the summit craters. The oxygen isotope composition of about 210 groundwater samples collected all around the volcano ranged from 29.3 to 25.0‰. The higher values measured on the eastern flank indicated that recharge occurs at lower altitudes on this flank. The low variability (0.30–0.65‰) of the monthly values gathered from 14 groundwater sampling points over a period of 2 years indicates that the groundwater system is isotopically well mixed. Some long-term trends may be explained by variations in annual recharge, due to the prevalent isotope composition of wet air masses.
    Description: National Group for Volcanology (G.N.V.), Italy.
    Description: Published
    Description: 282–299
    Description: partially_open
    Keywords: Isotope hydrology ; d18O ; Groundwater ; Rainwater ; Mt Etna ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 751835 bytes
    Format: 539 bytes
    Format: application/pdf
    Format: text/html
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  • 3
    Publication Date: 2017-04-04
    Description: In this paper, in an attempt to reveal possible changes connected to natural or anthropogenic causes, the main results of hydrogeochemical monitoring carried out at Mount Etna are evaluated. We report on the salinity contents of the groundwaters that flow in fractured volcanics, which make up the flanks of the volcano. These waters, analyzed for major ion chemistry, were sampled regularly from 1994 to 2004. Basing on nonparametric Sen’s slope estimator, time series of groundwater composition reveal that the salinity of most of the Etnean aquifers increased by 0.5% to 3.5% each year during this period. This change in the water chemistry is clearly referable to the overexploitation of the aquifers. This increasing trend needs to be inverted urgently; otherwise, it will cause a shortage of water in the near future, because the maximum admissible concentration of salinity for drinking water will be exceeded.
    Description: Published
    Description: 431-446
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Hydrochemistry ; Salinization ; Over-abstraction ; Groundwater monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2017-04-04
    Description: Abstract The 87Sr/86Sr ratio was investigated in groundwater circulating in the volcanic edifice of Mt. Etna in order to estimate the possible contribution of deep brines circulating in the sedimentary basement. Samples from 14 sites were collected and analyzed for their chemical composition and Sr-isotope ratios. While the most common approach of coupling 87Sr/86Sr ratios with the concentration of dissolved Sr is not effective in distinguishing between the deep brine and seawater contributions, we suggest that the Sr/Cl ratio is a useful complementary parameter that needs to be considered when attempting to clearly identify the Sr sources. The obtained data indicate that the Sr-isotope signature of groundwater is determined by the volcanics hosting the aquifer. The volcanic isotopic signature is modified by very small amounts of brines (〈 1%), characterized by a high concentration of Sr and a 87Sr/86Sr ratio typical of sedimentary environments, but only at sites where the groundwater circulates almost in contact with the sedimentary basement. Conversely, the contribution of seawater is completely ruled out since this should produce a higher concentration of chloride. The proposed approach is potentially very effective for tracing the circulation of groundwater not only at Mt. Etna but also at volcanic edifices that overlie a bedrock with different 87Sr/86Sr ratios as well as at volcanic islands where freshwater overlies seawater.
    Description: Published
    Description: 102-107
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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