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  • Chemistry  (110)
  • Organic Chemistry  (13)
  • Campanian Ignimbrite  (2)
  • Heavy metals  (2)
  • (Promoter A1 of phage T7)  (1)
  • Brassicaceae
  • Ephedra distachya type
  • R/V Vereshchagin
  • pollen analytical standard techniques
  • 1
    Publication Date: 2021-06-16
    Description: The Campi Flegrei caldera collapsed 39 ka in the Neapolitan area (southern Italy) after the Campanian Ignimbrite eruption. This eruption, recognized as the largest and the most cataclysmic volcanic event in the Mediterranean area over the past 200 ka, extruded not less than 300 km3 of trachytic magma. Controversy exists over the timescales required to assemble a such large volume of silicic melt and thus whether large magmatic reservoirs can actually persist below active volcanic systems over prolonged periods of time. Uranium-series analyses have been performed on Campanian Ignimbrite whole-rocks, glass matrixes and separated minerals, and the obtained results have been interpreted in combination with data on Sr, Nd, Pb isotopes from literature. The compositionally most evolved sample which is most radiogenic with respect to Sr isotopes records a reference age of 71 ka. By contrast, U-Th internal isochrones of the three compositionally least evolved samples give identical initial Th isotope ratios and yield consistent ages predating the eruption by up to 6.4 ka. The highest Pb and Nd isotopic ratios and 230Th/232Th activity ratios together with the oldest reference age of the most evolved samples suggest the existence of a resident magma body possibly related to a magmatic system that is known to have fed earlier magmatic activity in the Campi Flegrei area. Conversely, the younger age of the least evolved and least radiogenic magma dates the crystallization/differentiation event of a chemically and isotopically new magma batch entering the reservoir of the resident magma some few thousand years before the cataclysmic eruption. Therefore, the time preceding this large caldera-forming eruption during which the large volume of Campanian Ignimbrite magma assembled and mixed is 6.4 ± 2.1 ka.
    Description: This study benefited from the financial support of the 5th Framework Programme of the European Union within the ERUPT project.
    Description: Published
    Description: 217-228
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: restricted
    Keywords: U-Th isotopes ; Campanian Ignimbrite ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: New Sr and Nd isotope data for whole rocks, glasses and minerals are combined to reconstruct the nature and origin of mixing end-members of the 200 km3 trachytic to phonolitic Campanian Ignimbrite (Campi Flegrei, Italy) magmatic system. The least-evolved magmatic end-member shows equilibrium between host glass and the majority of the phenocrysts and is less radiogenic in Sr and Nd than the most-evolved magma. On the contrary, only the Fe-rich pyroxene from the most-evolved erupted magma is in equilibrium with the matrix glass, while all other minerals are in isotopic disequilibrium. These magmas mixed prior to and during the Campanian Ignimbrite eruption and minerals were freely exchanged between the magma batches. Combining the results of the geochemical investigations on magma end-members with geophysical and geological data, we develop the following scenario. In stage 1, a parental, less differentiated magma rose into the middle crust, and evolved through combined crustal assimilation and crystal fractionation. In stage 2, the differentiated magma rose to shallower depth, fed the pre-Campanian Ignimbrite activity and evolved by further open-system processes into the most-evolved and most-radiogenic Campanian Ignimbrite end-member magma. In stage 3, new trachytic magma, isotopically distinct from the pre-Campanian Ignimbrite magmas, rose from ca. 6 km to shallower depth, recharged the most-evolved pre-Campanian Ignimbrite magma chamber, and formed the large and stratified Campanian Ignimbrite magmatic system. During the course of the Campanian Ignimbrite eruption, the two layers were tapped separately and/or simultaneously, and gave rise to the range of chemical and isotopic values displayed by the Campanian Ignimbrite pumices, glasses and minerals.
    Description: Published
    Description: 285-300
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Campanian Ignimbrite ; Radiogenic isotopes ; Mixing process ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Analytica Chimica Acta 283 (1993), S. 230-245 
    ISSN: 0003-2670
    Keywords: Biogenic halogenated methanes ; Gas chromatography ; Halogens ; Heavy metals ; Iodine cycle ; Ion chromatography ; Isotope dilution analysis ; Mass spectrometry ; Nitrate cycle ; Trace detection
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Biochimica et Biophysica Acta (BBA)/Gene Structure and Expression 909 (1987), S. 126-132 
    ISSN: 0167-4781
    Keywords: (Promoter A1 of phage T7) ; DNA fragment isolation ; DNA purification ; Phenol water partitioning ; Plasmid DNA
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Medicine , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Protoplasma 136 (1987), S. 37-48 
    ISSN: 1615-6102
    Keywords: Chara ; Fine structure ; Growth ; Heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary The toxicity of some heavy metals to the common macrophytic freshwater algaChara vulgaris was studied under laboratory conditions. For experiments, apical tips of algae containing two internodes were cultivated for fourteen days in the presence of various concentrations of cadmium, mercury or lead (as triethyl lead or lead nitrate). Fifty percent growth inhibition occurred with concentrations of 8.5×10−8 M (9.5 ppb) cadmium, 7.5×10−7M (150ppb) mercury, 1.6×10−6 M (330ppb) organic lead or 4× 10−5 M (8000 ppb) inorganic lead. Sublethal concentrations of these metals caused alterations in the fine structure of internodal cells which turned out to be at least partly metal-specific or in the case of lead, the effects depended on whether the lead was ionic or organically bound. Cadmium and inorganic lead induced disorders of cell wall microfibrils which resulted in local wall protuberances. Mercury affected the chloroplasts which mostly showed considerably increased grana stacks. In addition, mercury caused a dilation of the endoplasmic reticulum and of the mitochondrial tubuli. Organic lead damaged the membrane system of chloroplasts; sheet- or tubule-like thylakoids were disarranged and showed whorl-like structures. At higher concentrations of organic lead, tubular invaginations of the plasmalemma (“charasomes”) disappeared. The fine structure of nuclei was not altered by any of the metals.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 169 (1928), S. 140-150 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die für die Darstellung von gleichteiligen Silberhydrosolen besten Mengenverhältnisse werden zusammengestellt für das Arbeiten mit 0,001% iger Silberoxydlösung.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 209 (1932), S. 325-327 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Der beim Eintauchen von metallischem Cadmium in eine sehr verdünnte Lösung von Goldschlorid entstehende Niederschlag ist nicht nur in seiner Zusammensetzung, sondern auch in seiner röntgenographisch verglichenen Struktur identisch mit der intermetallischen, aus der Schmelze entstandenen Verbindung AuCd3.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 173 (1928), S. 27-44 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die bereits früher berichtete Beobachtung, daß die Reduktion von silberhaltigen Reduktionsgemischen ohne Verwendung von Gold-oder Silberkeimen durch Hydrazinhydrat je nach der Menge des dabei anwesenden Natriumcarbonats abgestufte Silbersole zu liefern vermag, wird erweitert.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 148 (1925), S. 382-390 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. An Goldhydrosolen, die durch Reduktion gewonnen waren, sind die Beweglichkeiten der Goldteilchen im elektrischen Potentialgefälle unabhängig von dem Zerteilungsgrad und der Art der Darstellung.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 181 (1929), S. 379-384 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Abhängigkeit des elektrokinetischen Potentials des Goldes von der Konzentration wird in sehr verdünnten Lösungen von Elektrolyten (10-8-10-5 n.) verfolgt.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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