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Mass spectra of synthesized mixed bromochloroacetic acids (1992)

Xie, Yuefeng ; Rajan, R. V. ; Reckhow, David A.

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 27 (1992), S. 807-810

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Mass spectra of methyl esters of three common drinking water chlorination by-products, bromodichloroacetic acid, dibromochloroacetic acid and tribromoacetic acid, are presented. The spectra are obtained in electron impact and chemical ionization modes, using a quadrupole mass spectrometer. Proposed fragment ion assignments are presented in detail. Fragment clusters were identified from their m/z values and confirmed with their relative isotope ratios. The detailed mass spectra presented are especially useful because standards for these drinking water contaminants are not yet commercially available.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210270708

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