ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The synthesis of sulfoxides and sulfones of 2-oxa-7-thia-isotwistane (24) and 2-oxa-7-thia-twistane (35) as well as of several of their derivatives is described. endo-2-Hydroxy-9-thiabicyclo[3.3.1]non-6-ene (5) was used as starting material.During the course of the reactions special attention was given to intramolecular hydroxy-mercuration and jododemercuration reactions, spectroscopic features, molecular rearrangements and stereospecificity of oxidations of sulfides to sulfoxides.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19720550809
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