ISSN:
0044-2313
Keywords:
Transition metal substituted phosphaalkenes
;
isophosphaalkyne complex
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Transition Metal Substituted Acylphosphanes and Phosphaalkenes. 17. Synthesis and Structure of the μ-Isophosphaalkyne Complexes [(η5-C5H5)2(CO)2Fe2(μ-CO)(μ-C=PC6H2R3)] (R = Me, iPr, tBu).Condensation of (η5-C5H5)2(CO)2Fe2(μ-CO)(μ-CSMe)}+SO3CF3- (6) with 2,4,6-R3C6H2PH(SiMe3) (7) (a: R = Me, b: R = iPr, c: R = tBu) affords the complexes (η5-C5H5)2(CO)2Fe2(μ-CO)(η-C=PC6H2R3-2,4,6) (9 a-c) with edge-bridging isophosphaalkyne ligands as confirmed by the x-ray structure analysis of 9 a.
Notes:
Die Kondensation des μ-Carbinkomplexes {(η5-C5H5)2(CO)2Fe2(μ-CO)(μ-CSMe)}+SO3CF3- (6) mit den Phosphanen 2,4,6-R3C6H2PH(SiMe3) (7) (a: R = Me, b: R = iPr, c: R = tBu) liefert die Komplexe (η5-C5H5)2(CO)2Fe2(μ-CO)(η-C=PC6H2R3-2,4,6) 9a-c, die die neuartigen Isophosphaalkine C≡P-Aryl als Brückenliganden tragen. Von 9 a wurde eine Röntgenstrukturanalyse durchgeführt.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19936191023
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