ISSN:
0098-1273
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Composites with a matrix of poly(2-hydroxyethyl methacrylate) (PHEMA) and 10% by volume of various crosslinked PHEMA polymer fillers (prepared by copolymerization with 0.1, 0.4, 1.0, and 20.0% by weight of ethylenedimethacrylate) of particle size about 1 μm were prepared. Some polymer matrixes were prepared from soluble branched PHEMA (Hydron S), and others by copolymerization, in the presence of the filler with 0.4 and 1.0% of ethylenedimethacrylate as a crosslinking agent. In the case of the uncrosslinked matrix, a linear polymer-crosslinked polymer system, resulted; in the case of the crosslinked matrix, a composite heterogeneous network was formed (in the latter case, the particles of the filler were swollen with monomer during the crosslinking polymerization).Stress-strain, equilibrium, and ultimate characteristics were measured at 3, 10, 25, 40, 60, and 80°C on samples swollen to equilibrium in water (Tg ≈ -50°C) and at 80, 110, and 140°C on dry samples (Tg ≈ 100°C). Depending on experimental conditions, above all on the distance from the main transition region and on whether the polymer is dry or swollen, it was found that the measured hydrophilic composite systems behaves as a filled system (with the polymer filler acting mostly as solid particles, irrespective of the crosslink density) or as a system with crosslink density fluctuations (where both networks, the matrix and the filler, contribute roughly additively to the properties of the system), or finally as defect heterogeneous systems (where the properties depend primarily on the character of the polymer-filler interface).
Additional Material:
10 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1975.180130811
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